Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.     

A note on climate change adaptation for seaports: a challenge for global ports, a challenge for global society

With 80 % of world trade carried by sea, seaports provide crucial linkages in global supply-chains and are essential for the ability of all countries to access global markets. Seaports are likely to be affected directly and indirectly by climatic changes, with broader implications for international trade and development. Due to their coastal location, seaports are particularly vulnerable to extreme weather events associated with increasing sea levels and tropical storm activity, as illustrated by hurricane “Sandy”. In view of their strategic role as part of the globalized trading system, adapting ports in different parts of the world to the impacts of climate change is of considerable importance. Reflecting the views of a diverse group of stakeholders with expertise in climate science, engineering, economics, policy, and port management, this essay highlights the climate change challenge for ports and suggests a way forward through the adoption of some initial measures. These include both “soft” and “hard” adaptations that may be spearheaded by individual port entities, but will require collaboration and support from a broad range of public and private sector stakeholders and from society at large. In particular, the essay highlights a need to shift to more holistic planning, investment and operation.     

Assessing the influence of climate model uncertainty on EU-wide climate change impact indicators

Despite an increasing understanding of potential climate change impacts in Europe, the associated uncertainties remain a key challenge. In many impact studies, the assessment of uncertainties is underemphasised, or is not performed quantitatively. A key source of uncertainty is the variability of climate change projections across different regional climate models (RCMs) forced by different global circulation models (GCMs). This study builds upon an indicator-based NUTS-2 level assessment that quantified potential changes for three climate-related hazards: heat stress, river flood risk, and forest fire risk, based on five GCM/RCM combinations, and non-climatic factors. First, a sensitivity analysis is performed to determine the fractional contribution of each single input factor to the spatial variance of the hazard indicators, followed by an evaluation of uncertainties in terms of spread in hazard indicator values due to inter-model climate variability, with respect to (changes in) impacts for the period 2041–70. The results show that different GCM/RCM combinations lead to substantially varying impact indicators across all three hazards. Furthermore, a strong influence of inter-model variability on the spatial patterns of uncertainties is revealed. For instance, for river flood risk, uncertainties appear to be particularly high in the Mediterranean, whereas model agreement is higher for central Europe. The findings allow for a hazard-specific identification of areas with low vs. high model agreement (and thus confidence of projected impacts) within Europe, which is of key importance for decision makers when prioritising adaptation options.     

Sutter's Mill dicarboxylic acids as possible tracers of parent‐body alteration processes

Dicarboxylic acids were searched for in three Sutter's Mill (SM) fragments (SM2 collected prerain, SM12, and SM41) and found to occur almost exclusively as linear species of 3‐ to 14‐carbon long. Between these, concentrations were low, with measured quantities typically less than 10 nmole g^?1 of meteorite and a maximum of 6.8 nmole g^?1 of meteorite for suberic acid in SM12. The SM acids' molecular distribution is consistent with a nonbiological origin and differs from those of CMs, such as Murchison or Murray, and of some stones of the C2‐ungrouped Tagish Lake meteorite, where they are abundant and varied. Powder X‐ray diffraction of SM12 and SM41 show them to be dominated by clays/amorphous material, with lesser amounts of Fe‐sulfides, magnetite, and calcite. Thermal gravimetric (TG) analysis shows mass losses up to 1000 °C of 11.4% (SM12) and 9.4% (SM41). These losses are low compared with other clay‐rich carbonaceous chondrites, such as Murchison (14.5%) and Orgueil (21.1%). The TG data are indicative of partially dehydrated clays, in accordance with published work on SM2, for which mineralogical studies suggest asteroidal heating to around 500 °C. In view of these compositional traits and mineralogical features, it is suggested that the dicarboxylic acids observed in the SM fragments we analyzed likely represent a combination of molecular species original to the meteorite as well as secondary products formed during parent‐body alteration processes, such as asteroidal heating.     

The Meteoritical Bulletin,No. 100, 2014 June

Meteoritical Bulletin 100 contains 1943 meteorites including 8 falls (Boumdeid [2011], Huaxi, Ko?ice, Silistra, So?tmany, Sutter's Mill, Thika, Tissint), with 1575 ordinary chondrites, 139 carbonaceous chondrites, 96 HED achondrites, 25 ureilites, 18 primitive achondrites, 17 iron meteorites, 15 enstatite chondrites, 11 lunar meteorites, 10 mesosiderites, 10 ungrouped achondrites, 8 pallasites, 8 Martian meteorites, 6 Rumuruti chondrites, 3 enstatite achondrites, and 2 angrites, and with 937 from Antarctica, 592 from Africa, 230 from Asia, 95 from South America, 44 from North America, 36 from Oceania, 6 from Europe, and 1 from an unknown location. This will be the last Bulletin published in the current format. Information about approved meteorites can be obtained from the Meteoritical Bulletin Database (MBD) available online at http://www.lpi.usra.edu/meteor/     

On the Multiplicity of the O-Star Cyg OB2 #8a and its Contribution to the γ-ray Source 3EG J2033+4118

We present the results of an intensive spectroscopic campaign in the optical waveband revealing that Cyg OB2 #8A is an O6+O5.5 binary system with a period of about 21.9 days. Cyg OB2 #8A is a bright X-ray source, as well as a non-thermal radio emitter. We discuss the binarity of this star in the framework of a campaign devoted to the study of non-thermal emitters, from the radio waveband to γ-rays. In this context, we attribute the non-thermal radio emission from this star to a population of relativistic electrons, accelerated by the shock of the wind-wind collision. These relativistic electrons could also be responsible for a putative γ-ray emission through inverse Compton scattering of photospheric UV photons, thus contributing to the yet unidentified EGRET source 3EG J2033+4118. Based partly on data Obtained at the Observatoire de Haute-Provence, France.     

Dissociative excitation of SO2 by controlled electron impact

The fragmentation of SO₂ following dissociative electron impact excitation has been studied under single collision conditions for incident electron energies up to 500 eV. The emission spectrum in the far v.u.v. spectral range (450–1100Å) shows many features arising from excited neutral oxygen and ionized oxygen and sulphur fragments. Absolute emission cross sections have been measured for the most intense lines and the maximum values were found to range from 1–12 × 10^?19 cm² with an uncertainty of approx. ± 35%. Dissociation mechanisms are discussed and in some cases the dissociation path could be uniquely identified. The striking differences between the v.u.v. emission spectrum produced by single step dissociation of SO₂ and the spectra emitted by the plasma torus around Jupiter are discussed.