Nutrient flux into an intense deep chlorophyll layer in a mode-water eddy

An intense deep chlorophyll layer in the Sargasso Sea was reported near the center of an anticyclonic mode-water eddy by McGillicuddy et al. [2007. Eddy–wind interactions stimulate extraordinary mid-ocean plankton blooms, Science, accepted]. The high chlorophyll was associated with anomalously high concentrations of diatoms and with a maximum in the vertical profile of ¹⁴C primary productivity. Here we report tracer measurements of the vertical advection and turbulent diffusion of deep-water nutrients into this chlorophyll layer. Tracer released in the chlorophyll layer revealed upward motion relative to isopycnal surfaces of about 0.4 m/d, due to solar heating and mixing. The density surfaces themselves shoaled by about 0.1 m/d. The upward flux of dissolved inorganic nitrogen, averaged over 36 days, was approximately 0.6 mmol/m²/d due to both upwelling and mixing. This flux is about 40% of the basin wide, annually averaged, nitrogen flux required to drive the annual new production in the Sargasso Sea, estimated from the oxygen cycle in the euphotic zone, the oxygen demand below the euphotic zone, and from the ³He excess in the mixed layer. The observed upwelling of the fluid was consistent with theoretical models [Dewar, W.K., Flierl, G.R., 1987. Some effects of wind on rings. Journal of Physical Oceanography 17, 1653–1667; Martin, A.P., Richards, K.J., 2001. Mechanisms for vertical nutrient transport within a North Atlantic mesoscale eddy. Deep-Sea Research II 48, 757–773] in which eddy surface currents cause spatial variations in surface stress. The diapycnal diffusivity at the base of the euphotic zone was 3.5±0.5×10⁻⁵ m²/s. Diapycnal mixing was probably enhanced over more typical values by the series of storms passing over the eddy during the experiment and may have been enhanced further by the trapping of near-inertial waves generated within the eddy.     

New variable stars from the photographic archive: semi-automated discoveries,attempts at automatic classification and the new field 104 Her

Using 172 plates taken with the 40-cm astrograph of the Sternberg Astronomical Institute(Lomonosov Moscow University) in 1976–1994 and digitized with a resolution of 2400 dpi, we discovered and studied 275 new variable stars. We present the list of our new variables with all necessary information concerning their brightness variations. As in our earlier studies, the new discoveries show a rather large number of high-amplitude Delta Scuti variables, predicting that many stars of this type remain not detected in the whole sky. We also performed automated classification of the newly discovered variable stars based on the Random Forest algorithm. The results of the automated classification were compared to traditional classification and showed that automated classification was possible even with noisy photographic data. However, further improvement of automated techniques is needed, which is especially important when considering the very large numbers of new discoveries expected from all-sky surveys.     

Inversion for Range-Dependent Sediment Compressional-Wave-Speed Profiles From Modal Dispersion Data

A perturbative inversion method for estimating sediment compressional-wave-speed profiles from modal travel-time data is extended to include range-dependent environments. The procedure entails dividing a region into range-independent sections and obtaining estimates of the sediment properties for each region. Inversion results obtained using synthetic data show that range-dependent properties can be obtained if an experiment is designed to include multiple source/receiver combinations. This approach is applied to field data collected during the 2006 Shallow Water Experiment (SW06). The sediment compressional-wave-speed profiles resulting from analysis of the field data are evaluated by comparing acoustic fields predicted based on the inversion to acoustic fields measured during a different experiment conducted in the same region. The model is also compared to seismic reflection survey data collected during SW06. Resolution and variance estimated for the inversion results are also presented.      

Phytoplankton production and seasonal biomass variation of seagrass,Ruppia maritima L., in a tropical Mexican lagoon with an ephemeral inlet

Plankton metabolism andRuppia maritima biomass were measured seasonally during 1982–83 in El Verde Lagoon, a small coastal lagoon with an ephemeral inlet on the Pacific Coast of Mexico. Total net aquatic primary production was 521 g C m^?2 y^?1. The water column was slightly heterotrophic, with an annual P/R ratio of 0.89. Our analysis indicates that tropical and subtropical coastal lagoons with restricted or seasonal inlets have generally higher net aquatic primary productivity levels than lagoons with permanently open inlets. We hypothesize that this is due to retention of nutrients and plankton stocks during the dry season. The seasonal pattern of water column metabolism was related to rainfall and riverflow, with higher values generally occurring during the wet season. Net production and respiration were about three times lower during the 1982 dry season as compared to the 1983 dry season which received considerable rains due to abnormal climatic conditions. The biomass ofR. maritima ranged from zero to 620 g dry wt m^?2. Growth occurred only during the dry season and there were two distinct biomass peaks representing two separate crops. The second crop was heavily epiphytized with nitrogen-fixing algae. There was an apparent succession in dominance of water column productivity over the year, withRuppia dominating during the dry season and phytoplankton more important during the wet season.     

Gas phase reactions of alkyl nitrates with hydroxyl radicals under tropospheric conditions in comparison with photolysis

Rate constants for the reaction of OH radicals with some branched alkyl nitrates have been measured applying a competitive technique. Methyl nitrite photolysis in synthetic air was used as OH radical source at 295±2 K and 1000 mbar total pressure. Using a rate constant of 2.53×10^-12 cm³ s^-1 for the reaction of OH radicals with n-butane as reference, the following rate constants were obtained (units: 10^-12 cm³ s^-1): isopropyl nitrate, 0.59±0.22; isobutyl nitrate, 1.63±0.20; 3-methyl-2-butyl nitrate, 1.95±0.15; 2-methyl-1-butyl nitrate, 2.50±0.15; 3-methyl-1-butyl nitrate, 2.55±0.35. These values have been combined with the literature data to recalculate the substituent factors F(X) for the different nitrate groups which can be used to predict OH rate constants for organic nitrates for which experimental data are not available.Preliminary measurements of the photolysis frequency of isopropyl nitrate have shown that for this nitrate as a model substance, OH reactions and direct photolysis are of equal importance under tropospheric conditions.     

Within-storm variations in runoff and sediment export from a rapidly eroding coal-refuse deposit

Measurements of rainfall, runoff and sediment export from a barren deposit of coal mine refuse in south-western Indiana were collected during three storms in the summer and autumn of 1990. Interfluve sheetwash, sediment mass flux, sediment concentration and, to a lesser extent, trunk gully discharge all responded quickly to changes in rainfall intensity. Grain-size distributions varied considerably during storms, containing exclusively fine-grained sediment at low sediment discharges but very large quantities of coarse (> 2mm) sediment at peak sediment discharges. Although data from a fairly long, multipulsed storm indicate that sediment production is limited by supply, the imbricated layer of flat chips that exists at the surface of the deposit is apparently mobilized during most high-intensity pulses of rainfall, thereby producing large volumes of coarse sediment during summer thunderstorms.     

Significance of the remotely sensed thermal infrared measurements obtained over a citrus orchard

In this work we have developed a theoretical model that helps the interpretation of the remotely sensed thermal infrared measurements carried out over citrus orchards. A detailed analysis of the different factors which take part in the definition of the effective emissivity and temperature (observation height, viewing angle, type of soil, dimensions and separation between orange trees) is made. The model was validated under vertical observation in a citrus orchard during seven nights. In this situation we have determined that the model performs to an accuracy of about 1%.     

Geochemical Indicators of Intrinsic Bioremediation

A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO₂ relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes.     

Carbon,hydrogen and nitrogen isotopes in solvent-extractable organic matter from carbonaceous chondrites

Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl₄ and CH₃OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH₃OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH₃OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH₃OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ¹³C values of about +5 to + 10%. and δ¹⁵N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH₃OH-extract also has a δ¹⁵N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH₃OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH₃OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl₄ has essentially no nitrogen, and δ³C and δD values are lower than for CH₃OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin.