Effect of intertidal compared to subtidal exposure on the uptake,loss and oxidative toxicity of water-born benzo[a]pyrene in the mantle and whole tissues of the mussel,Mytilus edulis L

Blue mussels (Mytilus edulis, L.) were exposed to a single dose of 1 ppb benzo[a]pyrene (BaP) under subtidal (SC) or tidal conditions (TC; 6 h immersion, 6 h emersion) in order to follow its bioaccumulation in whole mussel and mantle tissue, and to compare BaP-mediated toxicity on lipids (malonaldehyde formation, MDA) in the mantle. Rapid uptake of BaP (70-80% of BaP initially introduced in tanks) was observed in both conditions after 12 h, but subsequent depuration in clean water was slower in TC mussels. BaP levels decreased in whole tissue in both conditions between 12 and 24 h, but increased in mantle. The mantle BaP levels were similar during the first 4 days in SC and TC, but whereas they decreased in SC after 7 days. BaP was retained at high levels in mantle in TC until the end of the study (14 days). In both conditions, significant increases (P < 0.05) in lipid peroxidation were observed after 4 days, but MDA levels were approximately 3 times higher in the mantle of TC than SC mussels, although BaP tissue concentrations were similar. These observations suggested that increased BaP-mediated toxicity in mantle lipid was due to the interactive effect of the tidal cycle of immersion/emersion on BaP-mediated oxidative damage.     

Volcanic stratigraphy of DSDP/ODP Hole 395A: An interpretation using well-logging data

Deep Sea Drilling Project/Ocean Drilling Program Hole 395A was drilled approximately 500 m deep into young oceanic crust west of the Mid-Atlantic Ridge. Core recovery is very poor in this hole and therefore continuous downhole measurements are important to understand the drilled lithology. Geophysical downhole measurements were carried out during several cruises. A new set of logs was recorded during Leg 174B in summer 1997. The new logging data show a significant improvement in data quality compared to older measurements from Leg 109. The lithostratigraphy established from cores gives only limited information because of the poor core recovery in this hole. The gaps in the core lithostratigraphy are filled by reconstructing a synthetic lithological profile using the standard well-logging data. Three types of lava morphologies, massive basalts, altered lava flows, and pillow basalts, may be distinguished using the logs because the lava morphologies show differences in their physical properties due to differences in fracturing and alteration. The synthetic lithological profile gives a more detailed and precise vertical definition of single layers than the core profile. The integration of further logging and core data enables a detailed reconstruction of the accretion history at the drill site. Cyclic, upward decreasing trends in the resistivity logs were already observed during earlier cruises and were referred to magmatic cycles. Similar trends occur in the density log and, inversely, in the total gamma ray log. The trends reflect gradual changes in fracturing, porosity, permeability, and alteration and cover depth intervals of several tens of meters. Boundaries between cycles are interpreted to correspond to periods of volcanic quiescence. Two types of boundaries may be identified. Boundaries correlating with reversals in the magnetic field and/or changes in the geochemical composition of the basalts are interpreted as long pauses. Basalts separated by these boundaries were probably fed by separate magma reservoirs. Boundaries identified only by changes in alteration but not in geochemistry are interpreted to represent shorter pauses. They separate basalts that were probably fed by the same magma chamber. This revised version was published online in November 2006 with corrections to the Cover Date.     

The contact binary AE phoenicis — An analysis from deconvoluted spectra

A method is described for an analysis of deconvoluted stellar spectra, and applied to new spectroscopic observations of the close eclipsing system AE Phuenicis, obtained with the 1.52 m telescope of the Southern European Observatory at La Silla, Chile, Results are presented for the rotational velocities of this variable, together with a proposed model of the system.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia, 3–7 June, 1983.     

Prebiotic carbon in clays from Orgueil and Ivuna (CI), and Tagish Lake (C2 ungrouped) meteorites

Abstract— Transmission electron microscopic (TEM) and electron energy‐loss spectroscopic (EELS) study of the Ivuna and Orgueil (CI), and Tagish Lake (C2 ungrouped) carbonaceous chondrite meteorites shows two types of C‐clay assemblages. The first is coarser‐grained (to 1 μm) clay flakes that show an intense O K edge from the silicate together with a prominent C K edge, but without discrete C particles. Nitrogen is common in some clay flakes. Individual Orgueil and Tagish Lake meteorite clay flakes contain up to 6 and 8 at% C, respectively. The C K‐edge spectra from the clays show fine structure revealing aromatic, aliphatic, carboxylic, and carbonate C. The EELS data shows that this C is intercalated with the clay flakes. The second C‐clay association occurs as poorly crystalline to amorphous material occurring as nanometer aggregates of C, clay, and Fe‐O‐rich material. Some aggregates are dominated by carbonaceous particles that are structurally and chemically similar to the acid insoluble organic matter. The C K‐edge shape from this C resembles that of amorphous C, but lacking the distinct peaks corresponding to aliphatic, carboxylic, and carbonate C groups. Nanodiamonds are locally abundant in some carbonaceous particles. The abundance of C in the clays suggest that molecular speciation in the carbonaceous chondrites is partly determined by the effects of aqueous processing on the meteorite parent bodies, and that clays played an important role. This intricate C‐clay association lends credence to the proposal that minerals were important in the prebiotic chemical evolution of the early solar system.     

Glacial/interglacial sea surface temperature changes in the Southwest Pacific ocean over the past 360 ka

The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ¹⁸O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ¹⁸O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ¹⁸O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO₂ rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of ¹⁴C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.     

Crowdsourcing The National Map

Using crowdsourcing techniques, the US Geological Survey’s (USGS) Volunteered Geographic Information (VGI) project known as “The National Map Corps (TNMCorps)” encourages citizen scientists to collect and edit data about man-made structures in an effort to provide accurate and authoritative map data for the USGS National Geospatial Program’s web-based The National Map. VGI is not new to the USGS, but past efforts have been hampered by available technologies. Building on lessons learned, TNMCorps volunteers are successfully editing 10 different structure types in all 50 states as well as Puerto Rico and the US Virgin Islands.     

The geology of Hotei Regio, Titan: Correlation of Cassini VIMS and RADAR

Joint Cassini VIMS and RADAR SAR data of ∼700-km-wide Hotei Regio reveal a rich collection of geological features that correlate between the two sets of images. The degree of correlation is greater than anywhere else seen on Titan. Central to Hotei Regio is a basin filled with cryovolcanic flows that are anomalously bright in VIMS data (in particular at 5 μm) and quite variable in roughness in SAR. The edges of the flows are dark in SAR data and appear to overrun a VIMS-bright substrate. SAR-stereo topography shows the flows to be viscous, 100-200 m thick. On its southern edge the basin is ringed by higher (∼1 km) mountainous terrain. The mountains show mixed texture in SAR data: some regions are extremely rough, exhibit low and spectrally neutral albedo in VIMS data and may be partly coated with darker hydrocarbons. Around the southern margin of Hotei Regio, the SAR image shows several large, dendritic, radar-bright channels that flow down from the mountainous terrain and terminate in dark blue patches, seen in VIMS images, whose infrared color is consistent with enrichment in water ice. The patches are in depressions that we interpret to be filled with fluvial deposits eroded and transported by liquid methane in the channels. In the VIMS images the dark blue patches are encased in a latticework of lighter bands that we suggest to demark a set of circumferential and radial fault systems bounding structural depressions. Conceivably the circular features are tectonic structures that are remnant from an ancient impact structure. We suggest that impact-generated structures may have simply served as zones of weakness; no direct causal connection, such as impact-induced volcanism, is implied. We also speculate that two large dark features lying on the northern margin of Hotei Regio could be calderas. In summary the preservation of such a broad suite of VIMS infrared color variations and the detailed correlation with features in the SAR image and SAR topography evidence a complex set of geological processes (pluvial, fluvial, tectonic, cryovolcanic, impact) that have likely remained active up to very recent geological time (<10⁴ year). That the cryovolcanic flows are excessively bright in the infrared, particularly at 5 μm, might signal ongoing geological activity. One study [Nelson, R.M., and 28 colleagues, 2009. Icarus 199, 429-441] reported significant 2-μm albedo changes in VIMS data for Hotei Arcus acquired between 2004 and 2006, that were interpreted as evidence for such activity. However in our review of that work, we do not agree that such evidence has yet been found.     

The time scales of magma mixing and mingling involving primitive melts and melt–mush interaction at mid-ocean ridges

We have studied the chemical zoning of plagioclase phenocrysts from the slow-spreading Mid-Atlantic Ridge and the intermediate-spreading rate Costa Rica Rift to obtain the time scales of magmatic processes beneath these ridges. The anorthite content, Mg, and Sr in plagioclase phenocrysts from the Mid-Atlantic Ridge can be interpreted as recording initial crystallisation from a primitive magma (~11 wt% MgO) in an open system. This was followed by crystal accumulation in a mush zone and later entrainment of crystals into the erupted magma. The initial magma crystallised plagioclase more anorthitic than those in equilibrium with any erupted basalt. Evidence that the crystals accumulated in a mush zone comes from both: (1) plagioclase rims that were in equilibrium with a Sr-poor melt requiring extreme differentiation; and (2) different crystals found in the same thin section having different histories. Diffusion modelling shows that crystal residence times in the mush were <140 years, whereas the interval between mush disaggregation and eruption was ≤1.5 years. Zoning of anorthite content and Mg in plagioclase phenocrysts from the Costa Rica Rift show that they partially or completely equilibrated with a MgO-rich melt (>11 wt%). Partial equilibration in some crystals can be modelled as starting <1 year prior to eruption but for others longer times are required for complete equilibration. This variety of times is most readily explained if the mixing occurred in a mush zone. None of the plagioclase phenocrysts from the Costa Rica Rift that we studied have Mg contents in equilibrium with their host basalt even at their rims, requiring mixing into a much more evolved magma within days of eruption. In combination these observations suggest that at both intermediate- and slow-spreading ridges: (1) the chemical environment to which crystals are exposed changes on annual to decadal time scales; (2) plagioclase crystals record the existence of melts unlike those erupted; and (3) disaggregation of crystal mush zones appears to precede eruption, providing an efficient mechanism by which evolved interstitial melt can be mixed into erupted basalts.