Surface water–groundwater interaction at restored streams and associated reference reaches

Stream restoration goals include improving habitat and water quality through reconstruction of morphological features found at analogous, pristine stream reaches. Enhancing hyporheic exchange may facilitate achieving these goals. Although hyporheic exchange at restoration sites has been explored in a few previous studies, comparative studies of restored versus reference or control streams are largely absent. We hypothesized that restoration cross‐vanes enhance hyporheic exchange, resulting in biogeochemical alteration of stream water chemistry in the streambed. Two streams restored using cross‐vanes to control erosion and improve habitat were compared with their associated reference reaches, which provided the basis for the restoration design. Thirteen temperature profile rods with vertically stacked sensors were installed at each site for 2 weeks. Heat tracing was used to quantify vertical flux in the streambed from the diurnal temperature fluctuations in the subsurface. Stream water and bed pore waters from mini‐piezometers were analysed for ion and nutrient chemistry. In general, mean vertical flux rates through the streambed were small throughout reference sites (?0.3 to 0.3 m/day) and at most locations at restored sites. Immediately adjacent to cross‐vanes, vertical flux rates were larger (up to 3.5 m/day). Geochemistry of pore waters shows distinct differences in the sources for the reference and restored sites. Strong downwelling zones adjacent to cross‐vanes showed high dissolved oxygen (10.75 mg/l) and geochemistry in the streambed similar to surface water. Reference sites had lower dissolved oxygen in the streambed (0.66–5.14 mg/l), and geochemical patterns suggest a mixture of discharging groundwater and surface water in the hyporheic zone. Restored sites also clearly show sulfate and nitrate reduction occurring in the streambed, which is not observed at the reference sites. The stream restoration sites studied here enhance rapid hyporheic exchange, but upwelling of groundwater has a stronger influence on streambed geochemistry at reference sites. Copyright © 2012 John Wiley & Sons, Ltd.     

Tracking suitable habitat for tree populations under climate change in western North America

An important criticism of bioclimate envelope models is that many wide-ranging species consist of locally adapted populations that may all lag behind their optimal climate habitat under climate change, and thus should be modeled separately. Here, we apply a bioclimate envelope model that tracks habitat of individual populations to estimate adaptational lags for 15 wide-ranging forest tree species in western North America. An ensemble classifier modeling approach (RandomForest) was used to spatially project the climate space of tree populations under observed climate trends (1970s to 2000s) and multi-model projections for the 2020s, 2050s and 2080s. We find that, on average, populations already lag behind their optimal climate niche by approximately 130 km in latitude, or 60 m in elevation. For the 2020s we expect an average lag of approximately 310 km in latitude or 140 m in elevation, with the most pronounced geographic lags in the Rocky Mountains and the boreal forest. We show that our results could in principle be applied to guide assisted migration of planting stock in reforestation programs using a general formula where 100 km north shift is equivalent to approximately 44 m upward shift in elevation. However, additional non-climatic factors should be considered when matching reforestation stock to suitable planting environments.     

The molecular mechanism of Mo isotope fractionation during adsorption to birnessite

Fractionation of Mo isotopes during adsorption to manganese oxides is a primary control on the global ocean Mo isotope budget. Previous attempts to explain what drives the surprisingly large isotope effect δ^97/95Mo_dissolved-δ^97/95Mo_adsorbed=1.8‰ have not successfully resolved the fractionation mechanism. New evidence from extended X-ray absorption fine structure analysis and density functional theory suggests that Mo forms a polymolybdate complex on the surfaces of experimental and natural samples. Mo in this polynuclear structure is in distorted octahedral coordination, while Mo remaining in solution is predominantly in tetrahedral coordination as . Our results indicate that the difference in coordination environment between dissolved Mo and adsorbed Mo is the cause of isotope fractionation. The molecular mechanism of metal isotope fractionation in this system should enable us to explain and possibly predict metal isotope effects in other systems where transition metals adsorb to mineral surfaces.     

The Dorn gold deposit in northern Victoria Land,Antarctica: Structure,hydrothermal alteration,and implications for the Gondwana Pacific margin

The Dorn gold deposit in northern Victoria Land, Antarctica is a fault related gold-only deposit and it represents the first described occurrence of gold mineralization in Paleozoic terranes of the Antarctic continent. The deposit is hosted in lower greenschist facies Middle Cambrian metavolcanic and metasedimentary rocks of the Bowers terrane. Gold-bearing veins are located in a brittle–ductile reverse high-strain zone, which was produced by transpressional deformation that overprints the structures of the Cambrian–Ordovician Ross Orogeny. The vein system is surrounded by a hydrothermal alteration zone that is as much as 300-m-wide, where the host rocks are partially to completely transformed into Fe–Mg carbonate-rich rocks with different degrees of replacement of the original mineralogy and texture.The type of host rock, the temperature estimates for mineralization from 290–320 °C, the quartz dominant vein system with sulfides and Fe-rich carbonates, and the controlling structures linked to a convergent margin tectonic setting together suggest that this mineralized vein system can be classified as an orogenic gold deposit. Close analogies are found with deposits of the Stawell zone in western Victoria, which is consistent with the correlation between units and hydrothermal events in northern Victoria Land and southeastern Australia.     

Glaciers and rock glaciers’ distribution at 28° SL,Dry Andes of Argentina,and some considerations about their hydrological significance

The area studied includes a little-known portion on the Dry Andes of the San Juan Frontal Cordillera, Argentina, where the hydrological significance of glaciers and rock glaciers was earlier never studied. The surveyed sector includes Cerro El Potro (5,870 m ASL) and nearby mountain chains (28°S). The predominant landforms in these areas were shaped in a periglacial environment superimposed on an earlier glacial landscape. These regions comprise abundant rock glaciers, a noteworthy rock glacier zone in the world, of which little is known in South America. This work employs geomorphological mapping to analyze the distribution of active rock glaciers in relation to altitude, aspect and slope using optical remote sensing techniques with GIS. Statistical estimation techniques were used based on a Digital Elevation Model (DEM) and aerial photos and Spot images interpretation. The specific density of rock glaciers’ estimation in the surveyed area (Argentine border) is 1.56% with corresponds to 38 rock glaciers with an area of 5.86 km² and 0.12 km³ of water equivalent. Furthermore, the analytical results show that elevations >4,270 m ASL, a southeast-facing aspect, and slope between 2° and 40° favor the existence of rock glaciers, Finally, a comparison with glacier water equivalent, which covers an area of ~16 km² and 0.9 km³ of water equivalent, shows that glaciers are the main stores of water at 28°S (Cerro El Potro Glacier). However, the importance of rock glaciers as water reserves in this portion of Argentina should not be underestimated.     

Oscarella balibaloi,a new sponge species (Homoscleromorpha: Plakinidae) from the Western Mediterranean Sea: cytological description,reproductive cycle and ecology

A new homoscleromorph sponge species was observed for the first time in 2002 along the coast of Provence (France) and since then, several investigations have been implemented. The new homoscleromorph species is devoid of skeleton and it is thus related to the Oscarella genus. Oscarella balibaloi sp. nov. has been found in several littoral submarine caves of the Western Mediterranean Sea (France and Spain). After several years of monitoring, we show that this sponge is becoming abundant in several locations. The species has a peculiar habit, often overgrowing massive sponges, gorgonians or some erected bryozoans. Oscarella balibaloi sp. nov. is thinly encrusting, with an irregular morphology, lobate surface, and soft and very slimy consistency. Its color is white to orange. At the cytological level, this new species is characterized by three distinct types of cells with inclusions in its mesohyl: one with vacuoles and the others with paracrystalline inclusions. The reproduction pattern is very similar to other Oscarella species. We also present a specific metabolic fingerprint and compare it to that of other Mediterranean Oscarella species.     

Seasonal variations of zinc in a eutrophic lake

Depth profiles of dissolved zinc were measured monthly over one year in Lake Greifen, a eutrophic lake. The concentrations are in the range 10–40 nM and show systematic variations over time and depth. Due to the increased binding to particles and subsequent settling, concentrations of zinc in the epilimnion decrease during summer stagnation. Clear correlations between Zn and major nutrients (P, Si) are, however, not observed in the water column. No accumulation of Zn occurs in the anoxic hypolimnion. The Zn sedimentation is related to the sedimentation of algae and of manganese oxide. A mass-balance calculation shows that 87% of the Zn input is retained in the sediments of Lake Greifen.     

Mixing behavior of dissolved organic carbon and its potential biological significance in the Pawcatuck River Estuary

The distributions of dissolved organic carbon (DOC), phytoplankton biomass (as measured by in vivo fluorescence), total nitrogen and phosphorus, and light extinction were observed on 10 cruises during 1989 and 1990 in the Pawcatuck River estuary located in southern Rhode Island. In the lower estuary, the distance of peak phytoplankton biomass from the head of the estuary was positively correlated with river discharge while the magnitude of the peak increased with decreasing discharge. High light-extinction appeared to limit the accumulation of biomass in the upper estuary. Variability in light extinction was largely (50%) explained by variation in the concentration of DOC. Salinity versus constituent plots suggested that DOC behaved nonconservatively in the estuary. These observational data indicate that the mixing behavior of DOC in the estuary influences light extinction and thus may limit accumulation of phytoplankton biomass in the upper estuary. This interpretation of observational data was supported by experimental work that demonstrated the significant contribution of DOC to light extinction, and by measurements, of phytoplankton productivity that showed greater light limitation in the upper estuary.