Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Evidence of ameliorated Middle Weichselian climate and sub‐arctic environment in the western Baltic region: coring lake sediments at Klintholm,Møn,Denmark

Coring through glaciotectonically stacked Quaternary sediments situated below sea level on the island of Møn, Denmark, recovered a succession of interstadial sediments of Middle Weichselian age. Plant and animal remains including insects found in laminated sand and mud indicate deposition in a lake surrounded by dwarf shrubs, herbs, mosses and rare trees. The insect fauna indicates a mean July temperature of 8–12 °C, suggesting an arctic to sub‐arctic environment, while winter temperatures around ?8 to ?22 °C suggest periglacial conditions with permafrost. Luminescence dating of sediment samples gave ages from 48–29 ka, and radiocarbon dating indicates deposition of plant fragments between 45 and 36 ka BP. The fossil assemblage from Møn shows close resemblance to those from other sites with similar ages found in the vicinity of the western Baltic Basin.     

Assessing the effects of land cover and future climate conditions on the provision of hydrological services in a medium‐sized watershed of Portugal

The separated and combined effects of land‐cover scenarios and future climate on the provision of hydrological services were evaluated in Vez watershed, northern Portugal. Soil and Water Assessment Tool was calibrated against daily discharge, sediments and nitrates, with good agreements between model predictions and field observations. Four hypothetical land‐cover scenarios were applied under current climate conditions (eucalyptus/pine, oak, agriculture/vine and low vegetation). A statistical downscaling of four General Circulation Models, bias‐corrected with ground observations, was carried out for 2021–2040 and 2041–2060, using representative concentration pathway 4.5 scenario. Also, the combined effects of future climate conditions were evaluated under eucalyptus/pine and agriculture/vine scenario. Results for land cover revealed that eucalyptus/pine scenario reduced by 7% the annual water quantity and up to 17% in the summer period. Although climate change has only a modest effect on the reduction of the total annual discharge (?7%), the effect on the water levels during summer was more pronounced, between ?15% and ?38%. This study shows that climate change can affect the provision of hydrological services by reducing dry season flows and by increasing flood risks during the wet months. Regarding the combined effects, future climate may reduce the low flows, which can be aggravated with eucalyptus/pine scenario. In turn, peak flows and soil erosion can be offset. Future climate may increase soil erosion and nitrate concentration, which can be aggravated with agriculture scenario. Results moreover emphasize the need to consider both climate and land‐cover impacts in adaptation and land management options at the watershed scale. Copyright © 2015 John Wiley & Sons, Ltd.     

Coastal lagoons and beach ridges as complementary sedimentary archives for the reconstruction of Holocene relative sea‐level changes

Coastal lagoons and beach ridges are genetically independent, though non‐continuous, sedimentary archives. We here combine the results from two recently published studies in order to produce an 8000‐year‐long record of Holocene relative sea‐level changes on the island of Samsø, southern Kattegat, Denmark. The reconstruction of the initial mid‐Holocene sea‐level rise is based on the sedimentary infill from topography‐confined coastal lagoons (Sander et al., Boreas, 2015b). Sea‐level index points over the mid‐ to late Holocene period of sea‐level stability and fall are retrieved from the internal structures of a wide beach‐ridge system (Hede et al., The Holocene, 2015). Data from sediment coring, georadar and absolute dating are thus combined in an inter‐disciplinary approach that is highly reproducible in micro‐tidal environments characterised by high sediment supply. We show here that the commonly proximate occurrence of coastal lagoons and beach ridges allows us to produce seamless time series of relative sea‐level changes from field sites in SW Scandinavia and in similar coastal environments.     

Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.