Indigenous soil knowledge among the Fulani of northern Burkina Faso: linking soil science and anthropology in analysis of natural resource management

The indigenous soil knowledge among the Fulani subsistence farmers in two villages of northern Burkina Faso is examined, analysed and assessed with the aim of evaluating its adequacy for sustaining soil fertility and for the appropriateness of tapping indigenous knowledge in development programmes. The analytical framework is a multidisciplinary approach combining soil science and anthropology. The results show a high degree of consistency between the science-based western soil classification and the Fulani soil classification although the routes of generation are different. The farmers are aware of and active in management of soil fertility based on their experience, but express no thorough understanding of the mechanisms of plant growth. The soil knowledge is applied in the farming strategies which, as a primary aim, seek to minimize the risk of harvest failure. However, the analysis also suggests that the knowledge is no part of a free-standing knowledge body which can be separated from the actual agricultural performance. The farmers express a general concern about the present state of the environment and degradation processes; however, there is no motivation to take active control of and manage the bush area. This is in contrast with the way millet cultivators actively manage their fields. An explanation of this is suggested by the division between the two Fulani ethnic subgroups, the FulBe who are the former masters and the RimayBe, the former slaves.     

Assessing the effects of land cover and future climate conditions on the provision of hydrological services in a medium‐sized watershed of Portugal

The separated and combined effects of land‐cover scenarios and future climate on the provision of hydrological services were evaluated in Vez watershed, northern Portugal. Soil and Water Assessment Tool was calibrated against daily discharge, sediments and nitrates, with good agreements between model predictions and field observations. Four hypothetical land‐cover scenarios were applied under current climate conditions (eucalyptus/pine, oak, agriculture/vine and low vegetation). A statistical downscaling of four General Circulation Models, bias‐corrected with ground observations, was carried out for 2021–2040 and 2041–2060, using representative concentration pathway 4.5 scenario. Also, the combined effects of future climate conditions were evaluated under eucalyptus/pine and agriculture/vine scenario. Results for land cover revealed that eucalyptus/pine scenario reduced by 7% the annual water quantity and up to 17% in the summer period. Although climate change has only a modest effect on the reduction of the total annual discharge (?7%), the effect on the water levels during summer was more pronounced, between ?15% and ?38%. This study shows that climate change can affect the provision of hydrological services by reducing dry season flows and by increasing flood risks during the wet months. Regarding the combined effects, future climate may reduce the low flows, which can be aggravated with eucalyptus/pine scenario. In turn, peak flows and soil erosion can be offset. Future climate may increase soil erosion and nitrate concentration, which can be aggravated with agriculture scenario. Results moreover emphasize the need to consider both climate and land‐cover impacts in adaptation and land management options at the watershed scale. Copyright © 2015 John Wiley & Sons, Ltd.     

Spalling Experiments on Large Hard Rock Specimens

Specimens of coarse-grained Äspö diorite were axially compressed to observe stress-induced spalling. The specimens had a novel design characterized by two manufactured large radius notches on opposite sides. The tangential stress occurring in the notches aimed to represent the tangential loading around a circular opening. Fracture stages were monitored by acoustic emission measurements. Rock chips were formed similar to those found in situ, which indicates a similar fracture process. Slabs were cut out from the specimens and impregnated using a fluorescent material to visualize the cracks. The cracks were subsequently examined by the naked eye and by means of microscopy images, from which fracture paths could be identified and related to different minerals and their crystallographic orientations. The microscopy analyses showed how the stress field and the microstructure interact. Parallel cracks were formed 2–4 mm below the surface, sub-parallel to the direction of the maximum principal stress. The crack initiation, the roles of minerals such as feldspar, biotite and quartz and their grain boundaries and crystallographic directions are thoroughly studied and discussed in this paper. Scale effects, which relate to the stress gradient and microstructure, are discussed.     

The Barents Sea Ice Sheet — A model of its growth and decay during the last ice maximum

On the basis of geomorphological and sedimentological data, we believe that the entire Barents Sea was covered by grounded ice during the last glacial maximum. ¹⁴C dates on shells embedded in tills suggest marine conditions in the Barents Sea as late as 22 ka BP; and models of the deglaciation history based on uplift data from the northern Norwegian coast suggest that significant parts of the Barents Sea Ice Sheet calved off as early as 15 ka BP. The growth of the ice sheet is related to glacioeustatic fall and the exposure of shallow banks in the central Barents Sea, where ice caps may develop and expand to finally coalesce with the expanding ice masses from Svalbard and Fennoscandia.The outlined model for growth and decay of the Barents Sea Ice Sheet suggests a system which developed and existed under periods of maximum climatic deterioration, and where its growth and decay were strongly related to the fall and rise of sea level.     

EPR investigation of the methyl radical,the hydrogen atom and carbon oxide radicals in Maxixe-type beryl

The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH₃ radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g _// = 2.00263, g _⊥ = 2.00249 and A_// = 2.288 mT, A_⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A ₀ = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g _// = 2.00265, g _⊥ = 2.00625 and A_// = 0.895 mT, A_⊥ = 0.885 mT, could come from a HCO₃ radical. One narrow and easily saturated signal with g _// = 2.00227 and g _⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g _// = 2.0017 and g _⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.     

Crystal chemistry of tremolite–tschermakite solid solutions

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.     

The use of spectral analysis-based exact solutions to characterize topography-controlled groundwater flow

Spectral analysis enhances the ability to analyze groundwater flow at a steady state by separating the top boundary condition into its periodic forms. Specifically, spectral analysis enables comparisons of the impact of individual spatial scales on the total flow field. New exact spectral solutions are presented for analyzing 3D groundwater flow with an arbitrarily shaped top boundary. These solutions account for depth-decaying, anisotropic and layered permeability while utilizing groundwater flux or the phreatic surface as a top boundary condition. Under certain conditions, groundwater flow is controlled by topography. In areas where the groundwater flow is controlled by the topography, the unknown water table is often approximated by the topography. This approximation induces a systematic error. Here, the optimal resolution of digital elevation models (DEMs) is assessed for use as a top boundary in groundwater flow models. According to the analysis, the water-table undulation is smoother than the topography; therefore, there is an upper limit to the resolution of DEMs that should be used to represent the groundwater surface. The ability to represent DEMs of various spectral solutions was compared and the results indicate that the fit is strongly dependent on the number of harmonics in the spectral solution.     

Microbial mineralization and assimilation of black carbon: Dependency on degree of thermal alteration

Black carbon is degraded slowly in the environment and its formation can therefore be an effective sink for atmospheric CO₂. This study examined whether charcoal is assimilated by microorganisms or not and estimated the rate of mineralization depending on the degree of thermal alteration of the black carbon. Charcoals were produced at three different temperatures from homogeneously ¹⁴C labelled plant material and incubated in soil, and ¹⁴C in the evolved CO₂ and the microbial biomass was measured. Unlike parallel plant samples, CO₂ evolution from the charcoals showed no lag phase, but a period of faster CO₂ evolution for the first 5–8 days followed by a period of slow evolution. The mineralization of charcoal appeared to decrease with increasing temperature at which it was produced. This was also the case after the initial period of fast CO₂ evolution. With the techniques used, it was not possible to observe any microbial assimilation of charcoal, either because it did not occur, or because the methods used were not sufficiently sensitive. However, the lack of a lag phase in the CO₂ evolution from the charcoals is in line with earlier evidence that charcoal is initially oxidized at the surfaces by abiotic processes.     

Lumbering operations,lake humification and consequences for the structure of the lake foodweb: A case study using the LakeWeb-model for Lake Stora Kröntjärn,Sweden

This work presents a scenario to demonstrate how a given lake (Lake Stora Kröntjärn, Sweden) would respond to changes in colour related to lumbering operations in its watershed. The questions posed are: How would lake colour values increase, for how long would such increases last and how would this influence the production and biomasses of key functional organisms in the lake? The work is based on a comprehensive lake ecosystem model, LakeWeb, which accounts for production, biomasses, predation, abiotic/biotic interactions of nine key functional groups of organisms, phytoplankton, bacterioplankton, two types of zooplankton (herbivorous and predatory), two types of fish (prey and predatory), as well as zoobenthos, macrophytes and benthic algae. The LakeWeb-model has been calibrated and critically tested using empirical data and regressions for many lakes and it can capture typical functional and structural patterns in lakes. To obtain results like these by traditional field-work in one or more lakes would be very demanding (in terms of money, persons and time). It has been shown that single tributary peaks in colour concentrations are often "drowned" in weekly mean lake values. The lumbering operations must be extensive and continue for a long time to cause significant increases in tributary colour values in order to significantly influence fundamental lake foodweb structures. This means that it is often realistic to assume that lumbering activities do not strongly influence lake foodweb structures. The LakeWeb-model with the given mass-balance model for lake colour can be a useful tool to assess situations when this might not be valid.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.