The epoch of helium reionization

We study the reionization of He  ii by quasars using a numerical approach that combines 3D radiative transfer calculations with cosmological hydrodynamical simulations. Sources producing the ionizing radiation are selected according to an empirical quasar luminosity function, and are assigned luminosities according to their intrinsic masses. The free parameters associated with this procedure are (1) a universal source lifetime, (2) a minimum mass cut-off, (3) a minimum luminosity cut-off, (4) a solid angle specifying the extent to which radiation is beamed, and (5) a tail-end spectral index for the radiative energy distribution of the sources. We present models in which these parameters are varied, and examine characteristics of the resultant reionization process that distinguish the various cases. In addition, we extract artificial spectra from the simulations and quantify statistical properties of the spectral features in each model.
We find that the most important factor affecting the evolution of He  ii reionization is the cumulative number of ionizing photons that are produced by the sources. Comparisons between He  ii opacities measured observationally and those obtained by our analysis reveal that the available ranges in plausible values for the parameters provide enough leeway to provide a satisfactory match. However, one property common to all our calculations is that the epoch of He  ii reionization must have occurred at a redshift in the range  3≲ z ≲4  . If so, future observational programmes will be able to directly trace the details of the ionization history of helium and to probe the low-density phase of the intergalactic medium during this phase of the evolution of the Universe.     

Eelpout (Zoarces viviparus) in marine environmental monitoring

The implementation of the EU Marine Strategy Framework Directive necessitates the development of common criteria and methodological standards for marine environmental monitoring and assessment across Europe. Eelpout (Zoarces viviparus) is proposed as a key indicator organism in the Baltic and North Sea regions. This benthic fish species is widely used in ecotoxicological studies and as a bioindicator of local pollution due to its stationary behavior. Eelpout is included in the environmental monitoring program of several Baltic States, covering both chemical and biological effects measurements, and samples have been archived in environmental specimen banks for >15 years. A method for evaluating the frequency of larval aberrations has been suggested as a standardized assessment tool. The large scientific knowledge-base and considerable experience of long-term chemical and biological effects monitoring and specimen banking, make eelpout a suitable species for the assessment of Good Environmental Status in the Baltic and North Seas.     

Geoid determination by spectral combination of an Earth gravitational model with airborne and terrestrial gravimetry — a theoretical study

Today air-gravimetry is a versatile technique to quickly collect gravity data over large regions, where terrestrial gravity data are sparse and/or of poor quality. The method requires the data to be downward continued to sea level for use in geoid determination, an inverse problem operation that calls for smoothing of the data and/or the kernel function involved (in either spectral or space domain). In this purely theoretical study we avoid this separate computational step by performing direct geoid estimation by so-called spectral combination/filtering of the data, which includes terrestrial gravimetry, airgravimetry, an Earth Gravitational Model (EGM) as well as their signal and error degree variances. Each derived geoid estimator is presented as the sum of one or two integral formulas and the harmonic series of the EGM together with the expected mean square error of the estimator. The article is limited to a theoretical study, leaving its practical tests for future investigation.     

A method of estimating the Moho density contrast with a tentative application of EGM08 and CRUST2.0

Based on Vening Meinez-Moritz global inverse isostatic problem, the Moho density contrast is formulated as that of finding a solution of a Fredholm integral equation of the first kind. We present solutions to this equation by combining global models of gravity (EGM08), topography (DTM2006) and seismic crust (CRUST2.0) to a resolution of 2°×2°. The test computations yielded Moho density contrasts ranging from 81.5 kg/m3 (in Pacific) to 988 kg/m³ (Tibet), with averages of 678 ± 78 and 334 ± 108 kg/m³ for continental and oceanic regions, respectively, and a global average of 448 ± 187 kg/m³. Estimated Moho depths range from 8 to 75 km with continental and oceanic averages of 36.6 ± 5.3 km and 12.9 ± 5.8 km, respectively, and a global average of 21 ± 12.5 km.     

A cryptic sulfur cycle driven by iron in the methane zone of marine sediment (Aarhus Bay, Denmark)

Sulfate reduction and sulfur-iron geochemistry were studied in 5-6 m deep gravity cores of Holocene mud from Aarhus Bay (Denmark). A goal was to understand whether sulfate is generated by re-oxidation of sulfide throughout the sulfate and methane zones, which might explain the abundance of active sulfate reducers deep below the main sulfate zone. Sulfate penetrated down to 130 cm where methane started to build up and where the concentration of free sulfide peaked at 5.5 mM. Below this sulfate-methane transition, sulfide diffused downwards to a sulfidization front at 520 cm depth, below which dissolved iron, Fe²⁺, accumulated in the pore water. Sulfate reduction rates measured by ³⁵S-tracer incubations in the sulfate zone were high due to high concentrations of reactive organic matter. Within the sulfate-methane transition, sulfate reduction was distinctly stimulated by the anaerobic oxidation of methane. In the methane zone below, sulfate remained at positive “background” concentrations of <0.5 mM down to the sulfidization front. Sulfate reduction decreased steeply to rates which at 300-500 cm depth were 0.2-1 pmol SO₄²⁻ cm⁻³ d⁻¹, i.e., 4-5 orders of magnitude lower than rates measured near the sediment surface. The turn-over time of sulfate increased from 3 years at 12 cm depth to 100-1000 years down in the methane zone. Sulfate reduction in the methane zone accounted for only 0.1% of sulfate reduction in the entire sediment column and was apparently limited by the low pore water concentration of sulfate and the low availability of organic substrates. Amendment of the sediment with both sulfate and organic substrates immediately caused a 10- to 40-fold higher, “potential sulfate reduction” which showed that a physiologically intact community of sulfate reducing bacteria was present. The “background” sulfate concentration appears to be generated from the reaction of downwards diffusing sulfide with deeply buried Fe(III) species, such as poorly-reactive iron oxides or iron bound in reactive silicates. The oxidation of sulfide to sulfate in the sulfidic sediment may involve the formation of elemental sulfur and thiosulfate and their further disproportionation to sulfide and sulfate. The net reaction of sulfide and Fe(III) to form pyrite requires an additional oxidant, irrespective of the formation of sulfate. This could be CO₂ which is reduced with H₂ to methane. The methane subsequently diffuses upwards to become re-oxidized at the sulfate-methane transition and thereby removes excess reducing power and enables the formation of excess sulfate. We show here how the combination of these well-established sulfur-iron-carbon reactions may lead to the deep formation of sulfate and drive a cryptic sulfur cycle. The iron-rich post-glacial sediments underlying Holocene marine mud stimulate the strong sub-surface sulfide reoxidation observed in Aarhus Bay and are a result of the glacial to interglacial history of the Baltic Sea area. Yet, processes similar to the ones described here probably occur widespread in marine sediments, in particular along the ocean margins.     

Composition and solubility of precipitated copper(II) arsenates

Equilibrium reactions involving Cu(II) and As(V) have been studied with respect to formation of complexes in aqueous solutions as well as formation of solid phases. Potentiometric titrations performed at 25 °C (I = 0.1 M Na(Cl)) and at different Cu to As ratios gave no evidence for the existence of Cu(II) arsenate complexes in solution below the pH of the precipitation boundaries (pH ≈ 4), irrespective of the Cu to As ratio and pH. Mixing of solutions of Cu(II) and As(V) at different proportions and adjusting pH to values ranging from 4 to 9 resulted in precipitation of five different solid phases. The elemental composition of the solids was determined using X-ray Photoelectron Spectroscopy, and Environmental Scanning Microscopy-Field Emission Gun equipped with an energy dispersive spectroscopy detector. The average Cu/As ratio was determined by dissolving the solids. Total soluble concentrations of the components Cu(II) and As(V), as well as the basicity of the solid phases were determined by analysis of aqueous solutions. Based upon these experimental data the stoichiometric composition of the solid phases and their stability were determined. The resulting equilibrium model includes the solid phases Cu₃(AsO₄)₂, Cu₃(AsO₄)(OH)₃, Cu₂(AsO₄)(OH), Cu₅Na(HAsO₄)(AsO₄)₃ and Cu₅Na₂AsO₄)₄, where Cu₅Na(HAsO₄)(AsO₄)₃ and Cu₅Na₂(AsO₄)₄ have not been reported previously. In 0.1 M Na(Cl), Na⁺ was found to be a significant component in two of the solid phases. The Cu₅Na₂(AsO₄)₄ was formed in weakly alkaline conditions with pNa < 2.5. Stability constants for all solid phases have been determined. Distribution diagrams as well as predominance area (pNa-pH) diagrams are presented to illustrate stability fields of the different solid phases.     

A poly morphological landform approach for hydrogeological applications in heterogeneous glacial sediments

The ‘poly morphological (PM) concept’ is used to assess geological heterogeneity in glacial sediments and to evaluate groundwater recharge to aquifers, especially those underlying clay till. The novelty of the PM concept is that it enhances the knowledge of, especially, heterogeneity of till units in geological models by using superimposed geomorphological units with typical sediment types related to the individual landforms. The PM concept is demonstrated through the construction of a poly morphological map for Zealand in Denmark and an aggregated map comparing clay-till-thickness distribution within individual PM types. The hydrogeological applicability of the PM concept was tested with a physical-based distributed 3D hydrological model. The aggregated PM map was compared with fracture and redox conditions at 21 field sites to evaluate the PM-type correlation to: (1) till thickness, (2) thickness of the reduced-till zone, and (3) depth to the zone with fracture spacing >1 m The results show that the till thickness is a critical parameter for the formation of fracture networks in clay till, and that fracture density decreases in till thicker than 8–10 m. However, the amount of data is still inadequate for statistically proving the PM concept.     

Matching authority and VGI road networks using an extended node-based matching algorithm

The amount of volunteered geographic information (VGI) has increased over the past decade, and several studies have been conducted to evaluate the quality of VGI data. In this study, we evaluate the completeness of the road network in the VGI data set OpenStreetMap (OSM). The evaluation is based on an accurate and efficient network-matching algorithm. The study begins with a comparison of the two main strategies for network matching: segment-based and node-based matching. The comparison shows that the result quality is comparable for the two strategies, but the node-based result is considerably more computationally efficient. Therefore, we improve the accuracy of node-based algorithm by handling topological relationships and detecting patterns of complicated network components. Finally, we conduct a case study on the extended node-based algorithm in which we match OSM to the Swedish National Road Database (NVDB) in Scania, Sweden. The case study reveals that OSM has a completeness of 87% in the urban areas and 69% in the rural areas of Scania. The accuracy of the matching process is approximately 95%. The conclusion is that the extended node-based algorithm is sufficiently accurate and efficient for conducting surveys of the quality of OSM and other VGI road data sets in large geographic regions.