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41.
Larry W. Finger Robert M. Hazen Anne M. Hofmeister 《Physics and Chemistry of Minerals》1986,13(4):215-220
High-pressure crystal structures and compressibilities have been determined by x-ray methods for MgAl2O4 spinel and its isomorph magnetite, Fe3O4. The measured bulk moduli, K, of spinel and magnetite (assuming K′=4) are 1.94±0.06 and 1.86±0.05 Mbar, respectively, in accord with previous ultrasonic determinations. The oxygen u parameter, the only variable atomic position coordinate in the spinel structure (Fd3m, Z=8), decreases with pressure in MgAl2O4, thus indicating that the magnesium tetrahedron is more compressible than the aluminum octahedron. In magnetite the u parameter is unchanged, and both tetrahedron and octahedron display the 1.9 Mbar bulk modulus characteristic of the entire crystal. This behavior contrasts with that of nickel silicate spinel (γ-Ni2SiO4), in which the u parameter increases with pressure because the silicon tetrahedron is relatively incompressible compared to the nickel octahedron. 相似文献
42.
Larry V. Benson Joseph P. Smoot Michaele Kashgarian Andrei Sarna-Wojcicki James W. Burdett 《Quaternary Research》1997,47(3):251-260
Uncalibrated radiocarbon data from core PLC92B taken from Wizards Cove in the Pyramid Lake subbasin indicate that the Trego Hot Springs and Wono tephra layers were deposited 23,200 ± 300 and 27,300 ± 30014C yr B.P. (uncorrected for reservoir effect). Sedimentological data from sites in the Pyramid Lake and Smoke Creek–Black Rock Desert subbasins indicate that the Trego Hot Springs tephra layer was deposited during a relatively dry period when Pyramid Lake was at or below its spill point (1177 m) to the Winnemucca Lake subbasin. The Wono tephra layer was deposited when lake depth was controlled by spill across Emerson Pass sill (1207 m) to the Smoke Creek–Black Rock Desert subbasin.18O data from core PLC92B also support the concept that the Trego Hot Springs tephra fell into a relatively shallow Pyramid Lake and that the Wono tephra fell into a deeper spilling lake. 相似文献
43.
应用等效纬度-海拔模型进行地温及多年冻土制图 总被引:2,自引:2,他引:2
KenjiYoshikawa PrasadGogineni 《冰川冻土》2002,24(5):526-531
This research presents a method for permafrost mapping in discontinuous permafrost regions based on equivalent latitude/elevation concept in interior Alaska. In winter months, study site has a strong temperature inversion in air up to 700 m elevation. Air temperature data and the effects of slope, aspect and elevation were used to create an equivalent latitude/elevation model. This model was well correlated with mean annual surface temperature (0.79). In this watershed, the thawing index (It≈1 400 ℃*days) at the ground surface and snow depth do not vary greatly from south facing to north facing slopes. The primary controlled factor that determines the mean annual surface temperature was the winter surface temperature. The permafrost stability is effectively controlled by the freezing index. We determined 37.5% of Caribou-Poker Creeks Research Watershed has unstable or thawing permafrost. At least 2.1% of the permafrost in this watershed may have disappeared in the last 90 years due to climate warming. This method makes it possible to evaluate the permafrost stability in the present, past and future. 相似文献
44.
A method to characterize reservoirs, based on matching temporal fluctuations in injection and production rates, has recently
been developed. The method produces two coefficients for each injector–producer pair; one parameter, λ, quantifies the connectivity and the other, τ, quantifies the fluid storage in the vicinity of the pair. Previous analyses used λ and τ separately to infer the presence of transmissibility barriers and conduits in the reservoir, but several common conditions
could not be easily distinguished. This paper describes how λ and τ can be jointly interpreted to enhance inference about preferential transmissibility trends and barriers. Two different combinations
are useful: one is a plot of log (λ) versus log (τ) for a producer and nearby injectors, and the second is a Lorenz-style flow capacity (F) versus storativity (C) plot. These techniques were tested against the results of a numerical simulator and applied to data from the North Buck
Draw field. Using the simulated data, we find that the F–C plots and the λ–τ plots are capable of identifying whether the connectivity of an injector–producer well pair is through fractures, a high-permeability
layer, multiple-layers or through partially completed wells. Analysis of data from the North Buck Draw field shows a reasonable
correspondence between τ and the tracer breakthrough times. Of two possible geological models for Buck Draw, the F–C and λ–τ plots support the model that has less connectivity in the field. The wells in fluvial deposits show better communication
than those wells in more estuarine-dominated regions. 相似文献
45.
46.
Ryan A. Zeigler Randy L. Korotev Bradley L. Jolliff Larry A. Haskin Christine Floss 《Geochimica et cosmochimica acta》2006,70(24):6050-6067
The regolith of the Apollo 16 lunar landing site is composed mainly of feldspathic lithologies but mafic lithologies are also present. A large proportion of the mafic material occurs as glass. We determined the major element composition of 280 mafic glasses (>10 wt% FeO) from six different Apollo 16 soil samples. A small proportion (5%) of the glasses are of volcanic origin with picritic compositions. Most, however, are of impact origin. Approximately half of the mafic impact glasses are of basaltic composition and half are of noritic composition with high concentrations of incompatible elements. A small fraction have compositions consistent with impact mixtures of mare material and material of the feldspathic highlands. On the basis of major-element chemistry, we identified six mafic glass groups: VLT picritic glass, low-Ti basaltic glass, high-Ti basaltic glass, high-Al basaltic glass, KREEPy glass, and basaltic-andesite glass. These glass groups encompass 60% of the total mafic glasses studied. Trace-element analyses by secondary ion mass spectroscopy for representative examples of each glass group (31 total analyses) support the major-element classifications and groupings. The lack of basaltic glass in Apollo 16 ancient regolith breccias, which provide snapshots of the Apollo 16 soil just after the infall of Imbrium ejecta, leads us to infer that most (if not all) of the basaltic glass was emplaced as ejecta from small- or moderate-sized impacts into the maria surrounding the Apollo 16 site after the Imbrium impact. The high-Ti basaltic glasses likely represent a new type of basalt from Mare Tranquillitatis, whereas the low-Ti and high-Al basaltic glasses possibly represent the composition of the basalts in Mare Nectaris. Both the low-Ti and high-Al basaltic glasses are enriched in light-REEs, which hints at the presence of a KREEP-bearing source region beneath Mare Nectaris. The basaltic andesite glasses have compositions that are siliceous, ferroan, alkali-rich, and moderately titaniferous; they are unlike any previously recognized lunar lithology or glass group. Their likely provenance is within the Procellarum KREEP Terrane, but they are not found within the Apollo 16 ancient regolith breccias and therefore were likely deposited at the Apollo 16 site post-Imbrium. The basaltic-andesite glasses are the most ferroan variety of KREEP yet discovered. 相似文献
47.
The temporal and spatial distributions of salinity, dissolved oxygen, suspended particulate material (SPM), and dissolved nutrients were determined during 1983 in the Choptank River, an estuarine tributary of Chesapeake Bay. During winter and spring freshets, the middle estuary was strongly stratified with changes in salinity of up to 5‰ occurring over 1 m depth intervals. Periodically, the lower estuary was stratified due to the intrusion of higher salinity water from the main channel of Chesapeake Bay. During summer this intrusion caused minimum oxygen and maximum NH4 + concentrations at the mouth of the Choptank River estuary. Highest concentrations of SPM, particulate carbon (PC), particulate nitrogen (PN), total nitrogen (TN), total phosphorous (TP) and dissolved inorganic nitrogen (DIN) occurred in the upper estuary during the early spring freshet. In contrast, minimum soluble reactive phosphate (SRP) concentrations were highest in the upper estuary in summer when freshwater discharge was low. In spring, PC:PN ratios were >13, indicating a strong influence by allochthonous plant detritus on PC and PN concentrations. However, high concentrations of PC and PN in fall coincided with maximum chlorophyll a concentrations and PC:PN ratios were <8, indicating in situ productivity controlled PC and PN levels. During late spring and summer, DIN concentrations decreased from >100 to <10 μg-at l?1, resulting mainly from the nonconservative behavior of NO3 ?, which dominated the DIN pool. Atomic ratios of both the inorganic and total forms of N and P exceeded 100 in spring, but by summer, ratios decreased to <5 and <15, respectively. The seasonal and spatial changes in both absolute concentrations and ratios of N and P reflect the strong influence of allochthonous inputs on nutrient distributions in spring, followed by the effects of internal processes in summer and fall. 相似文献
48.
Paul Duuring Stephen M. Rowins Bradley S. M. McKinley Jenni M. Dickinson Larry J. Diakow Young-Seog Kim Robert A. Creaser 《Mineralium Deposita》2009,44(4):463-496
The Toodoggone district comprises Upper Triassic to Lower Jurassic Hazelton Group Toodoggone Formation volcanic and sedimentary
rocks, which unconformably overlie submarine island-arc volcanic and sedimentary rocks of the Lower Permian Asitka Group and
Middle Triassic Takla Group, some of which are intruded by Upper Triassic to Lower Jurassic plutons and dikes of the Black
Lake suite. Although plutonism occurred episodically from ca. 218 to 191 Ma, the largest porphyry Cu–Au ± Mo systems formed
from ca. 202 to 197 Ma, with minor mineralization occurring from ca. 197 to 194 Ma. Porphyry-style mineralization is hosted
by small-volume (<1 km3), single-phase, porphyritic igneous stocks or dikes that have high-K calc-alkaline compositions and are comparable with volcanic-arc
granites. The Fin porphyry Cu–Au–Mo deposit is anomalous in that it is 16 m.y. older than any other porphyry Cu–Au ± Mo occurrence
in the district and has lower REEs. All porphyry systems are spatially restricted to exposed Asitka and Takla Group basement
rocks, and rarely, the lowest member of the Hazelton Group (i.e., the ca. 201 Ma Duncan Member). The basement rocks to intrusions
are best exposed in the southern half of the district, where high rates of erosion and uplift have resulted in their preferential
exposure. In contrast, low- and high-sulfidation epithermal systems are more numerous in the northern half of the district,
where the overlying Hazelton Group rocks dominate exposures. Cogenetic porphyry systems might also exist in the northern areas;
however, if they are present, they are likely to be buried deeply beneath Hazelton Group rocks. High-sulfidation epithermal
systems formed at ca. 201 to 182 Ma, whereas low-sulfidation systems were active at ca. 192 to 162 Ma. Amongst the studied
epithermal systems, the Baker low-sulfidation epithermal deposit displays the strongest demonstrable genetic link with magmatic
fluids; fluid inclusion studies demonstrate that its ore fluids were hot (>468°C), saline, and deposited metals at deep crustal
depths (>2 km). Sulfur, C, O, and Pb isotope data confirm the involvement of a magmatic fluid, but also suggest that the ore
fluid interacted with Asitka and Takla Group country rocks prior to metal deposition. In contrast, in the Shasta, Lawyers,
and Griz-Sickle low-sulfidation epithermal systems, there is no clear association with magmatic fluids. Instead, their fluid
inclusion data indicate the involvement of low-temperature (175 to 335°C), low-salinity (1 to 11 equiv. wt.% NaCl) fluids
that deposited metals at shallow depths (<850 m). Their isotope (i.e., O, H, Pb) data suggest interaction between meteoric
and/or metamorphic ore fluids with basement country rocks. 相似文献
49.
50.
Regional-scale hydrothermal alteration in the Central Blake River Group,western Abitibi subprovince,Canada: implications for VMS prospectivity 总被引:1,自引:0,他引:1
Mark?D.?HanningtonEmail author Frank?Santaguida Ingrid?M.?Kjarsgaard Larry?M.?Cathles 《Mineralium Deposita》2003,38(4):393-422
The Late Archean Blake River Group is a thick succession of predominantly mafic volcanic rocks within the southern zone of the Abitibi greenstone belt. It contains a number of silicic volcanic centers of different size, including the large Noranda volcanic complex, which is host to 17 past-producing volcanogenic massive sulfide deposits. The Noranda complex consists of a 7- to 9-km-thick succession of bimodal mafic and felsic volcanic rocks erupted during five major cycles of volcanism. Massive sulfide formation coincided with a period of intense magmatic activity (cycle III) and the formation of the Noranda cauldron. Hydrothermal alteration in these rocks is interpreted to reflect large-scale hydrothermal fluid flow associated with rapid crustal extension and rifting of the volcanic complex. The alteration includes abundant albite, chlorite, epidote and quartz (silicification), which exhibit broad stratigraphic and structural control and correlate with previously mapped whole-rock oxygen isotope zonation. The Mine Sequence volcanic rocks are characterized by abundant iron-rich chlorite (Fe/Fe+Mg >0.5), hydrothermal amphibole (ferroactinolite) and coarse-grained epidote of clinozoisite composition (<10 wt% Fe 2O 3). Volcanic rocks of the pre-cauldron sequences, which contain only subeconomic stringer mineralization, are characterized by less abundant chlorite and mainly fine-grained epidote (>10 wt% Fe 2O 3) lacking the clinozoisite solid solution. Alteration in the Mine Sequence volcanic rocks persists along strike well beyond the limits of the main ore deposits (as far as several tens of kilometers) and can be readily distinguished from greenschist facies metamorphic assemblages at a regional scale. The lack of similar alteration in the pre-cauldron sequences is consistent with limited 18O-depletion and suggests that the early history of the volcanic complex did not support large-scale, high-temperature fluid flow in these rocks. Comparisons with a much smaller, barren volcanic complex in nearby Ben Nevis township reveal important differences in the alteration mineralogy between volcanoes of different size, with implications for area selection during regional-scale mineral exploration. The Ben Nevis Complex consists of a 3- to 4-km-thick succession of mafic, intermediate and felsic volcanic rocks centered on a small subvolcanic intrusion. Alteration of the volcanic rocks comprises mainly low-temperature assemblages of prehnite, pumpellyite, magnesium-rich chlorite (Fe/Fe+Mg <0.5), iron-rich epidote (>10 wt% Fe 2O 3) and calcite. Actinolite ± magnetite alteration occurs proximal to the intrusive core of the complex, but the limited extent of this alteration indicates only local high-temperature fluid circulation adjacent to the intrusion. A distal zone of carbonate alteration is located 4–6 km from the center of the volcano. Although iron-bearing carbonates are present locally within this zone, the absence of siderite argues against a high-temperature origin for this alteration. These observations do not offer positive encouragement for the existence of a fossil geothermal system of sufficient size or intensity to have produced a large massive sulfide deposit. 相似文献