Noble gas and carbon abundances of the Haverö, Dingo Pup Donga,and North Haig ureilites

Total carbon determinations on the Haverö, Dingo Pup Donga, and North Haig ureilites yield values of 2.07, 3.17, and 5.58 wt.%, respectively. Haverö and Dingo Pup Donga contain relatively large amounts of trapped Ar, Kr and Xe, which like the carbon content varies with grain size for Haverö. These two meteorites also contain dominant cosmic rayproduced He and Ne, and show ³He exposure ages of ~23 m.y. and ~7 m.y., respectively. North Haig contains much smaller amounts of trapped gases and spallogenic gases, which may result from loss due to terrestrial weathering. The isotopic composition of Xe in five grain size analyses of Haverö and a whole rock analysis of Dingo Pup Donga shows the presence of a major solar-like Xe component. The presence of this solar component adds an additional complication to the concept of forming ureilites from carbonaceous chondrites.     

Inducing mineral precipitation in groundwater by addition of phosphate

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 10⁵ and 10⁷ mL^-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.     

Pre- and post-dispersal seed loss and soil seed dynamics of the dominant Bulnesia retama (Zygophyllaceae) shrub in a sandy Monte desert of western Argentina

In deserts and semi-deserts dominant plants seldom rely on a persistent seed bank to ensure their recruitment from sexual reproduction, which is generally based on the seeds produced in the last reproductive event. We studied pre- and post-dispersal seed loss of Bulnesia retama, a dominant shrub of the sandy Monte deserts (western Argentina). We hypothesised that pre- and post-dispersal seed depletion in B. retama regulate soil seed density and in turn decrease soil seed reserves. We also hypothesised that spatial patches induced by standing vegetation and other microsites additionally affect post-dispersal seed loss and soil seed density.We observed that as much as half the total seed production was lost due to pre-dispersal seed predation. Seed dispersal plus predation showed a negative exponential function with 61% of seeds falling during the first 28 days, and 99% after 90 days, when 34% of the seeds remained inside excluded branches. A significant patch effect was observed on soil seed density and seed dynamics, with a greater number of seeds and increased seed depletion rates below B. retama shrubs. However, spatial patches did not affect seed germination although they increased with burial time, from 22% to 70% after 75 and 276 days, respectively. Likewise, a similar trend was found in potential seed germination; seeds collected directly from mother plants had a low germination rate (less than 25%), which increased to 75% after 276 days of soil burial. About 15% of the dispersed seeds should persist to the next rainy season, thus contributing to a low-density but persistent seed bank.The delay in seed germination and temporal decrease in soil seed density that we observed for B. retama suggest that a set of mechanisms have been developed promoting germination events whenever soil water is available, at any moment of the year.     

Seasonal and spatial variability of particulate matter of a muddy intertidal flood front

The concentration and composition of suspended particulate matter (SPM) were measured weekly for a period of one year in the flood front waters traversing a muddy tidal flat. SPM concentrations were lowest in the winter when portions of the tidal flat were covered with ice, and biological activity was minimal. In contrast, the summer months had the highest SPM concentrations which reflected increased bottom resuspension. The two main sources of SPM were suspended matter carried in from offshore on the flooding tide and resuspended in situ bottom sediments. The offshore source was characterized by low SPM concentrations, coarse textures, and a high content of protein and chlorophyll ‘a’. Samples taken during resuspension events (storms/showers) had high SPM concentrations, finer textures, and were enriched in dead detrital organic material (phaeophytin). At any one time the SPM was primarily an admixture of these two sources. The highest SPM measurements were taken during storm events, with rainfall seeming to play a dominant physical role in aiding resuspension. SPM concentrations, textures, and compositions collected during the storms closely approximated SPM measurements made over newly dug ‘clam flats’.     

Cosmic structure growth and dark energy

Dark energy has a dramatic effect on the dynamics of the Universe, causing the recently discovered acceleration of the expansion. The dynamics are also central to the behaviour of the growth of large-scale structure, offering the possibility that observations of structure formation provide a sensitive probe of the cosmology and dark energy characteristics. In particular, dark energy with a time-varying equation of state can have an influence on structure formation stretching back well into the matter-dominated epoch. We analyse this impact, first calculating the linear perturbation results, including those for weak gravitational lensing. These dynamical models possess definite observable differences from constant equation of state models. Then we present a large-scale numerical simulation of structure formation, including the largest volume to date involving a time-varying equation of state. We find the halo mass function is well described by the Jenkins et al. mass function formula. We also show how to interpret modifications of the Friedmann equation in terms of a time-variable equation of state. The results presented here provide steps toward realistic computation of the effect of dark energy in cosmological probes involving large-scale structure, such as cluster counts, the Sunyaev–Zel'dovich effect or weak gravitational lensing.     

Mars: Experimental study of albedo changes caused by dust fallout

An experimental study was undertaken to determine how the spectral and photometric properties of representative Martian areas are affected by fallout of atmospheric dust suspended during dust forms. A laboratory apparatus was used to simulate the uniform fallout and deposition of particles 1 to 5 μm in diameter. Spectral measurements from 0.4- to 1.2-μm wavelengths and photometric measurements at several wavelengths were made for a number of Mars-analog materials before and after deposition of 6 × 10^?5 to 1.5 × 10^?3 g/cm² of simulated fallout. These results indicate that the spectral and photometric properties of Martian regions can be affected significantly even by minute amounts of fallout. For instance, the reflectance at 0.56 μm of an average dark area will increase by 35% after deposition of only 9 × 10^?5 g/cm², and by 70% after deposition of 1.5 × 10^?4 g/cm². Thus the fallout from even one dust storm season (～2 × 10^?3 g/cm²) is sufficient to change significantly the spectral and photometric characteristics of the substrate material, if the fallout were ubiquitous over the surface and if no competing processes of dust removal from surface grains occured.     

Studies of the solar chromosphere from millimetre and sub-millimetre observations

Spectroheliograms were obtained in bands centred at 1.2 mm, 0.8 mm and 0.4 mm wavelength during 1969 and 1971. In order to obtain photometrically valid data, a specialized set of reduction techniques was employed, obviating the effects of severe differential attenuation across the disc by atmospheric water vapour and of emission noise from the atmosphere, before taking out the instrumental spread functions of the telescope and detector.Comparison of our maps with those of other observers at 3 mm and 8.6 mm wavelength suggests that the chromospheric brightness temperature increments above active regions show a monotonic increase with increasing height above the photosphere over the normal increase in brightness temperature in the quiet chromosphere. Within the limit of angular resolution of 3 available, no evidence was recorded of normal limb brightening in our three passbands but the presence of isophotes at 50% of the central disc temperature consistently circumscribing the optical limb implies a narrow spike of sub-millimetre brightening close to the limb.     

Palaeomagnetic evidence for Tertiary counterclockwise rotation of Adria

With the aim of obtaining Tertiary palaeomagnetic directions for the Adriatic Foreland of the Dinaric nappe system, we carried out a palaeomagnetic study on platform carbonates from stable Istria, from the northwestern and the Central Dalmatia segment of imbricated Adria. Despite the weak to very weak natural remanences of these rocks, we obtained tectonically useful palaeomagnetic directions for 25 sites from 20 localities. All exhibit westerly declinations, both before and after tilt correction. Concerning the age of the magnetizations, we conclude that five subhorizontal and magnetite bearing Eocene localities from stable Istria are likely to carry primary remanence, whereas three tilted and hematite-bearing ones were remagnetized. In the northwestern segment of imbricated Adria the cluster of the mean directions improved after tectonic correction indicating pre-tilting magnetization. In contrast, Maastrichtian–Eocene platform carbonates from Central Dalmatian were remagnetized in connection with the late Eocene–Oligocene deformation or Miocene hydrocarbon migration. Based on the appropriate site/locality means, we calculate mean palaeomagnetic directions for the above three areas and suggest an alternative interpretation of the data of Kissel et al. [J. Geophys. Res. 100 (1995) 14999] for the flysch of Central Dalmatia. The four area mean direction define a regional palaeomagnetic direction of Dec=336°, Inc=+52°, k=107, α₉₅=9°. From these data we conclude that stable Istria, in close coordination with imbricated Adria, must have rotated by 30° counterclockwise in the Tertiary, relative to Africa and stable Europe. We suggest that the latest Miocene–early Pliocene counterclockwise rotations observed in northwestern Croatia and northeastern Slovenia were driven by that of the Adriatic Foreland, i.e. the rotation of the latter took place between 6 and 4 Ma.     

Initial interpretation of Titan plasma interaction as observed by the Cassini plasma spectrometer: Comparisons with Voyager 1

The Cassini plasma spectrometer (CAPS) instrument made measurements of Titan's plasma environment when the Cassini Orbiter flew through the moon's plasma wake October 26, 2004 (flyby TA). Initial CAPS ion and electron measurements from this encounter will be compared with measurements made by the Voyager 1 plasma science instrument (PLS). The comparisons will be used to evaluate previous interpretations and predictions of the Titan plasma environment that have been made using PLS measurements. The plasma wake trajectories of flyby TA and Voyager 1 are similar because they occurred when Titan was near Saturn's local noon. These similarities make possible direct, meaningful comparisons between the various plasma wake measurements. They lead to the following: (A) The light and heavy ions, H⁺and N⁺/O⁺, were observed by PLS in Saturn's magnetosphere in the vicinity of Titan while the higher mass resolution of CAPS yielded H⁺ and H₂⁺as the light constituents and O⁺/CH₄⁺ as the heavy ions. (B) Finite gyroradius effects were apparent in PLS and CAPS measurements of ambient O⁺ ions as a result of their absorption by Titan's extended atmosphere. (C) The principal pickup ions inferred from both PLS and CAPS measurements are H⁺, H₂⁺, N⁺, CH₄⁺ and N₂⁺. (D) The inference that heavy pickup ions, observed by PLS, were in narrow beam distributions was empirically established by the CAPS measurements. (E) Slowing down of the ambient plasma due to pickup ion mass loading was observed by both instruments on the anti-Saturn side of Titan. (F) Strong mass loading just outside the ionotail by a heavy ion such as N₂⁺ is apparent in PLS and CAPS measurements. (G) Except for the expected differences due to the differing trajectories, the magnitudes and structures of the electron densities and temperatures observed by both instruments are similar. The high-energy electron bite-out observed by PLS in the magnetotail is consistent with that observed by CAPS.