Determination of inorganic sulphur speciation with polarographic techniques: Some preliminary results for recent hypersaline anoxic sediments

Polarographic techniques have been used to determine reduced inorganic sulphur speciation in recent anoxic marine sediments from two hypersaline basins, the Tyro and the Bannock Basins, in the Eastern Mediterranean. The following phases were determined: acid volatile sulphur (AVS), pyritic sulphur and zerovalent sulphur. The determination of AVS and pyrite was based respectively on the acidification and Cr(II) reduction of these sulphur components to H₂S. H₂S was collected in base and the sulphide concentration was measured by polarography. Standard Na₂S and pyrite gave recoveries of 99.6% ± 3.9% and 97% ± 12% respectively. Total zerovalent sulphur in a sediment sample was measured by the reaction of sulphite with thiosulphate. Thiosulphate was measured directly by polarography.

Pyrite is the main phase of inorganic reduced sulphur in the sediments from the Tyro and the Bannock Basins, and it has about the same average level (125 υmoles per gramme dry weight) in the cores recovered from the two areas. However, the distribution of pyrite in the top 100 cm of the two cores differs significantly. In the Bannock Basin a sharp increase is observed with depth, whereas in the Tyro Basin there is a small decrease with depth.

The total amount of reduced inorganic sulphur is less than the total amount of sulphur in the sediments. This indicates that there must be additional sulphur-bearing phases. One of these phases may be gypsum, and indeed, gypsum crystals have been observed in the Bannock Basin.

In neither basin is there a significant correlation between reduced sulphur and organic carbon. The pyrite that occurs in these basins may have been formed syngenetically at the interface of the anoxic brine and oxic seawater. Diagenetic pyrite may have been formed within the sediments of the basins. AVS and total zerovalent sulphur are still observed at depth. We therefore suggest that this may be due to the incomplete transformation of AVS and zerovalent sulphur into pyrite.     

Burial and degradation of Rena oil within coastal sediments of the Bay of Plenty

ABSTRACT

During the Rena oil spill, no data existed for New Zealand conditions on the likely depth of burial and the expected degradation of oil deposited on sandy beaches. Sediment cores were taken from 12 locations along the Bay of Plenty coastline c. 1 year after the Rena oil spill. No visible oil was detected in cores and trenches dug within the beaches. Chemical extraction was performed on 20?cm slices from the upper 40?cm of 26 cores, and the elutriates were analysed for the presence of polycyclic aromatic hydrocarbons (PAHs). The results were compared with known PAH fingerprints of Rena oil and its degradation products. Only seven samples contained some marker PAHs, and none had a complete Rena profile, indicating stormwater contamination. Despite extensive deposition of Rena oil on beaches, no evidence of ongoing contamination could be located, indicating that the clean-up and degradation were effective at removing the oil.     

A Frequency Matching Method: Solving Inverse Problems by Use of Geologically Realistic Prior Information

The frequency matching method defines a closed form expression for a complex prior that quantifies the higher order statistics of a proposed solution model to an inverse problem. While existing solution methods to inverse problems are capable of sampling the solution space while taking into account arbitrarily complex a priori information defined by sample algorithms, it is not possible to directly compute the maximum a posteriori model, as the prior probability of a solution model cannot be expressed. We demonstrate how the frequency matching method enables us to compute the maximum a posteriori solution model to an inverse problem by using a priori information based on multiple point statistics learned from training images. We demonstrate the applicability of the suggested method on a synthetic tomographic crosshole inverse problem.     

The Planck High Frequency Instrument, a third generation CMB experiment, and a full sky submillimeter survey

The High Frequency Instrument (HFI) of Planck is the most sensitive CMB experiment ever planned. Statistical fluctuations (photon noise) of the CMB itself will be the major limitation to the sensitivity of the CMB channels. Higher frequency channels will measure galactic foregrounds. Together with the Low Frequency Instrument, this will make a unique tool to measure the full sky and to separate the various components of its spectrum. Measurement of the polarization of these various components will give a new picture of the CMB. In addition, HFI will provide the scientific community with new full sky maps of intensity and polarization at six frequencies, with unprecedented angular resolution and sensitivity. This paper describes the logics that prevailed to define the HFI and the performances expected from this instrument. It details several features of the HFI design that has not been published up to now.     

The Ries impact and its distal effects in sediments of Central Europe—A review

The Ries impact is the most important cosmic event in the younger geological history of Europe. Its effects reach far beyond the area considered so far and are documented in manifold evidence. In this paper, the widely scattered reports in the literature are compiled and supported with investigations by the authors. Besides well-known ejecta features like the Brockhorizont, Reuter's blocks, and moldavites, little known or forgotten indications, like a lechatelierite and β-cristobalite occurrence in Bavaria and unusual sedimentation phenomena in northern Germany, are presented. The paleogeographic reconstruction shows that the Ries impact occurred on the southern side of the Neogene Central European mainland. Large parts of this erosional area were devastated by the impact. Pressure waves and thermal radiation had a lasting effect on the landscape within hundreds of kilometers around the impact site. Destruction of the vegetation cover by impact-induced storms, wildfires, and heavy rainfall generated intense erosion. The adjacent sedimentation area to the north (Paleo-North Sea) experienced an increased and short-term supply of terrestrial debris to the marine environment. The stratigraphic coincidence of these exceptional sediments with the Ries event leads us to conclude that the distal effects of the impact are present here, which have so far received little or no attention in this context. The paper considers the different indications and sets them in a large-scale context.     

Matching INSPIRE Quality of Service Requirements with Hybrid Clouds

A lot of effort has been invested in Spatial Data Infrastructures (SDIs) during the last decade regarding interoperable standards for services and data. But still the scalability and performance of SDI services is reported to be crucial especially if they are accessed concurrently by a high number of users. Furthermore, laws and provisions such as the INSPIRE directive specify challenging requirements regarding the performance, availability and scalability of SDI services. This article presents a Hybrid Cloud architecture for matching INSPIRE‐related Quality of Service (QoS) requirements, without investing in rarely used hardware in advance, by occupying external third‐party resources on a pay‐as‐you‐go basis. The presented Hybrid Cloud is a composition of a local IT‐infrastructure (Private Cloud) and the computational resources of third‐party vendors (Public Cloud). The local infrastructure is laid out to handle the average main load of a service and in lasting peak times additional resources of external providers are allocated and integrated on demand into the local infrastructure to provide sufficient service quality automatically. A proof‐of‐concept implementation of the proposed Hybrid Cloud approach is evaluated and benchmarked with respect to INSPIRE‐related QoS requirements.     

Evaluating the functionality and streamflow impacts of explicitly modelling forest–snow interactions and canopy gaps in a distributed hydrologic model

Many plot‐scale studies have shown that snow‐cover dynamics in forest gaps are distinctly different from those in open and continuously forested areas, and forest gaps have the potential to alter the magnitude and timing of snowmelt. However, the watershed‐level impacts of canopy gap treatment on streamflows are largely unknown. Here, we present the first research that explicitly assesses the impact of canopy gaps on seasonal streamflows and particularly late‐season low flows at the watershed scale. To explicitly model forest–snow interactions in canopy gaps, we made major enhancements to a widely used distributed hydrologic model, distributed hydrology soil vegetation model, with a canopy gap component that represents physical processes of snowpack evolution in the forest gap separately from the surrounding forest on the subgrid scale (within a grid typically 10–150 m). The model predicted snow water equivalent using the enhanced distributed hydrology soil vegetation model showed good agreement (R² > 0.9) with subhourly snow water equivalent measurements collected from open, forested, and canopy gap sites in Idaho, USA. Compared with the original model that does not account for interactions between gaps and surrounding forest, the enhanced model predicted notably later melt in small‐ to medium‐size canopy gaps (the ratio of gap radius (r) to canopy height (h) ≤ 1.2), and snow melt rates exhibited great sensitivity to changing gap size in medium‐size gaps (0.5 ≤ r/h ≤ 1.2). We demonstrated the watershed‐scale implications of canopy gaps on streamflow in the snow‐dominated Chiwawa watershed, WA, USA. With 24% of the watershed drainage area (about 446 km²) converted to gaps of 60 m diameter, the mean annual 7‐day low flow was increased by 19.4% (i.e., 0.37 m³/s), and the mean monthly 7‐day low flows were increased by 13.5% (i.e., 0.26 m³/s) to 40% (i.e., 1.76 m³/s) from late summer through fall. Lastly, in practical implementation of canopy gaps with the same total gap areas, a greater number of distributed small gaps can have greater potential for longer snow retention than a smaller number of large gaps.     

The Late Holocene tephra record of the central Mediterranean Sea: Mapping occurrences and new potential isochrons for the 4.4–2.0 ka time interval

Five cores from the southern Tyrrhenian and Ionian seas were studied for their tephra and cryptotephra content in the 4.4–2.0 ka time interval. The chronological framework for each core was obtained by accelerator mass spectrometry ¹⁴C dating, the occurrence of distinct marker tephra and stratigraphic correlation with adjacent records. Tephrochronology allowed us to correlate the analyzed deposits with tephra markers associated with Somma-Vesuvius (79 ad ), Ischia Island (Cretaio), Mt Etna (FG, FL and FS) and Campi Flegrei (Astroni-Agnano Monte Spina) events. For the first time in the marine setting, a large single glass data set is provided for the Late Holocene Etnean marker beds including the FS tephra (ca. 4.3 ka). Moreover, unknown deposits from Lipari (ca. 2.2–2.0 ka) and Vulcano (3.6–3.3 ka) are also recognized at more distal sites than previously reported. These results contribute to improve the high-resolution tephrostratigraphic framework of the central Mediterranean Sea. They also provide new insights into the chemical composition and dispersal pattern of tephras that can be used as inter-archive tools for regional and ‘local’ stratigraphic correlations and for addressing paleoclimate research.     

2009年9月印度尼西亚巴东地震

2009年9月30日,印度尼西亚巴东市发生7.6级地震。之后,印度尼西亚又接连遭受了几次强震袭击,如2009年12月23日6.1级、2010年3月6日7.1级、2010年4月7日7.8级和2010年5月9日7.4级地震。2010年6月16日一天之内,印度尼西亚又接连发生了3次地震,震级分别为6.3级、7.0级和6.3级。2010年2月,由John McCloskey领军的一个科学家团队就2009年9月巴东地震致函英国《自然—地球科学》杂志(Nature Geoscience),题为:The September 2009 Padang Earthquake。信中提出警告:印度尼西亚苏门答腊沿海地区或将发生引发巨大海啸的强烈地震,其灾害程度足以造成与2004年南亚大海啸相匹敌的惨重伤亡,提醒居民要为更加强烈的地震来袭做好准备。为此,"Nature Geoscience"特发表了一篇社论,题为:Earthquakes off Sumatra(见本期译文"苏门答腊近海地震")。下边是John McCloskey等致"Nature Geoscience"的信函译文。