The Cathedral of S. Giorgio in Ragusa Ibla (Italy): characterization of construction materials and their chromatic alteration

The Cathedral of St. Giorgio in Ragusa Ibla (Sicily) is one of the most important Baroque monuments of eastern Sicily. The restoration of the monument underway has put forward notable questions regarding the stone materials used and their state of degradation. The façade appears to be made mainly of a creamy white calcarenite, and of mortars and plasters. However, detailed analysis has highlighted a more complex use of the raw material. The mortar and plaster have a different composition in regards to their architectural use while the natural stone material is distinguished not only by a creamy-white calcarenite but also by a dark coloured bituminous calcarenite (pitch rock), which now appears whiter because of superficial chromatic alterations. This process was reproduced in the laboratory using an accelerated aging technique on samples of bituminous calcarenite, which allowed the cause of the alternation to be identified as photo-oxidation of the asphaltenes. Following this process of photo-oxidation, other forms of chromatic alterations affected the façade (brown–orange-coloured patinas). FTIR, Scanning Electron Microscope and thin section microscopic observation allowed the characterization of also the products of this process to be carried out, highlighting the complex mechanism which the processes underwent.     

非均匀下垫面局地气候效应的数值模拟

使用美国NCAR非静力平衡模式MM 5V3,模拟了黑河地区非均匀下垫面局地小气候效应 ,再现了山谷风环流及夏季“绿洲效应”、沙漠上的“逆湿”和由于地表热力分布不均匀引起的绿洲—沙漠垂直环流等绿洲—沙漠相互作用的典型特征 ,较全面地揭示了非均匀地表大气边界层内的风、温、湿度场与陆面相互作用的物理机理 ,验证了野外实验的结果     

西藏高原夏季降水对ENSO的响应

通过合成分析指出包括雅藏布江中西段在内的西藏高原中西部地区夏季（6－8月）降水在ENSO的不同位相期间存在着显著的差异。利用交叉谱和奇异值分解等方法，分析了高原夏季降水场与太平洋海温场在时间和空间上的联系，结果表明，ENSO的暖（冷）位相期，高原大部分地区夏季降水以偏少（多）为主。     

The geomagenetic storm effect in the middle atmosphere — First results

Summary Geomagnetic storms belong to the most important phenomena of solar origin which affect the ionosphere and atmosphere. We study the responses of the lower ionosphere, middle stratospheric ozone, total ozone and the troposphere (vorticity area index at 500 hPa) to isolated and major geomagnetic storms. The expected positive effect is observed in the lower ionosphere. No observable effect is detected in the middle stratospheric ozone. An effect (not very significant) can be found in the total ozone and the troposphere.Contribution No, 109/90, Geophysical Institute, Czechosl. Acad. Sci., Prague.     

Nitric oxide density measurements at middle latitudes

Summary The measurements of nitric oxide density were made by the photoionization method at 30–90km in several rocket flights near Volgograd. TheseNO densities are well within the range of other measurements below 60km, but become rather high above 70km. The upper mesosphericNO densities estimated by two different methods from ionospheric data in Central Europe (50 °N) are rather high, as well. The appropriateNO densities in the upper mesosphere still seem to be an open question.     

Complementary Investigative Techniques for Site Assessment with Low-Level Contaminants

A remedial investigation (RI) was performed in an area downgradient from an abandoned missile silo at Vandenberg Air Force Base, California, as part of the United States Air Force Installation Restoration Program (IRP). A number of complementary investigative techniques were used to assure a reliable assessment of site contamination. These included the review of aerial photographs, the use of an organic vapor analyzer (OVA) and carbon adsorption/mass spectrometer (MS) method to conduct a soil-gas survey; magnetic and electromagnetic geophysical surveys; bedrock permeability testing; and the chemical analysis of soil, sediment, surface water, and ground water samples. The results from this investigation revealed the presence of an undocumented landfill and a small trichloroethylene plume in ground water at concentrations ranging from 6.7 ppb to 31 ppb. The investigation also identified local ground water flow direction, provided strong evidence of the location of potential sources of contamination, and defined the downgradient extent of ground water contamination. Because the identified contaminants have not as yet reached the environmentally sensitive wetland at the base of the slope below this facility, there is still time to propose remedial alternatives that would serve to protect this environmentally sensitive area.     

Diel feeding of the transparent goby Aphia minuta (Pisces,Gobiidae) in the Northwestern Adriatic Sea in spring time

The present study provides the first estimate of the daily ration for a goby species in the Mediterranean Sea, using a new approach to determine the mass of fish stomach contents through the sum of individual prey dry mass derived indirectly from prey size. Diel feeding activity and daily ration of the pelagic goby Aphia minuta were studied under natural conditions in the coastal waters off Comacchio (Northwestern Adriatic Sea) during the spring season. A total of 318 individuals of A. minuta, collected by 14 trawls carried out on 4 consecutive days, was examined for gut contents. The diel pattern of the vacuity index and the stomach fullness index indicated that A. minuta has nocturnal feeding behaviour. The daily ration, computed over a period of 16 h, was equivalent to 2.23% wet body mass.     

Heterotrophic bacteria community and pollution indicators of mussel--farm impact in the Gulf of Gaeta (Tyrrhenian Sea).

Field studies were carried out to determine and compare the impact of organic loads due to the biodeposition of a mussel farm on the water quality and sediment in a coastal area of the Tyrrhenian Sea (Western Mediterranean). A total of five environmental and five microbial parameters were examined from March, 1997 to February, 1998 on a monthly basis at three stations: the first was located under the mussel farm, the second located at about 40 m away from the mussel farm, while the third designed as a control was at about 1-km. No clear changes in the physical characteristics of the water masses were observed, comparing the three sampling sites and the water column generally showed homogeneous conditions (in terms of temperature and salinity). Changes in density of aerobic heterotrophic bacteria, Escherichia coli and Enterococci in the water column are apparently independent from changes in environmental parameters. At all stations a constant significant correlation between temperature and presumptive Vibrio parahaemolyticus was reported suggesting that this abiotic factor exerted a major control on this bacterial group and its distribution in the water column is not related to the biodeposition of the mussel farm. The major impact identified was on the sediment where variations in bacterial abundance was observed. In the Mussel station sediment enrichment of organic compounds, and the consequent modification of the characteristics of the benthic environment, determined an increase in aerobic heterotrophic bacteria, and particularly of vibrios density (on average about 60%), suggesting that these bacteria are good indicators of organic enrichment.     

Effects of oil on phytoplankton metabolism in natural and experimental estuarine ponds

A low level oil spill was simulated in small shallow natural estuarine marsh ponds in Ocean Springs and in experimental impoundments near St. Louis Bay, Mississippi. In the natural tidal pond in situ light and dark BOD bottle experiments on the phytoplankton community revealed a 44 to 65 % reduction in primary production and a 30 to 50 % reduction in respiration 2 weeks after spillage of 1·45 mg Empire Mix crude oil per litre of water. Two months after the spill, primary productivity and respiration in the oiled pond were only 17% and 7% lower, respectively than in the control pond. In the experimental impoundments at a concentration of 0·2 mg Arabian, Empire Mix and Nigerian oil per litre of water, in situ radiocarbon uptake by phytoplankton was lower—but not significantly lower—than that of the control impoundment. One to two months later, primary productivity was significantly higher in the Nigerian and Arabian oil ponds than control and Empire Mix ponds. The changes in plankton metabolism in both natural ponds and impoundments were evaluated on the basis of data simultaneously obtained from adjoining control ponds.