Research on Formation Mechanisms of Hot Dry Rock Resources in China

As an important geothermal resource, hot dry rock(HDR) reserves have been studied in many countries. HDR resources in China have huge capacity and have become one of the most important resources for the potential replacement of fossil fuels. However, HDR resources are difficult to develop and utilise. Technologies for use with HDR, such as high–temperature drilling, reservoir characterisation, reservoir fracturing, microseismic monitoring and high–temperature power stations, originate from the field of oil and drilling. Addressing how to take advantage of these developed technologies is a key factor in the development of HDR reserves. Based on the thermal crustal structure in China, HDR resources can be divided into four types: high radioactive heat production, sedimentary basin, modern volcano and the inner–plate active tectonic belt. The prospective regions of HDR resources are located in South Tibet, West Yunnan, the southeast coast of China, Bohai Rim, Songliao Basin and Guanzhong Basin. The related essential technologies are relatively mature, and the prospect of HDR power generation is promising. Therefore, analysing the formation mechanisms of HDR resources and promoting the transformation of technological achievements, large–scale development and the utilisation of HDR resources can be achieved in China.     

Characteristics and Origin of Tight Oil Accumulations in the Upper Triassic Yanchang Formation of the Ordos Basin, North-Central China

The Upper Triassic oil accumulations in the Ordos Basin is the most successful tight oil play in China,with average porosity values of less than 10% and permeability values below 1.0 mD.This study investigated the geological characteristics and origin of the tight oil accumulations in the Chang 6 member of the Upper Triassic Yanchang Formation in the Shanbei area based on over 50,000 petrological,source-rock analysis,well logging and production data.The tight oil accumulation of the Chang 6 member is distributed continuously in the basin slope and the centre of the basin.The oilwater relationships are complex.Laumontite dissolution pores are the most important storage spaces,constituting 30%-60% of total porosity and showing a strong positive relationship with oil production.The pore-throat diameter is less than 1 μm,and the calculated critical height of the oil column is much larger than the tight sand thickness,suggesting that the buoyancy was probably of limited importance for oil migration.The pressure difference between the source rocks and sandstone reservoirs is inferred to have provided driving force for hydrocarbon migration.Two factors of source-reservoir configuration and laumontite dissolution contributed to the formation of the Chang 6 tight oil accumulations.Intense hydrocarbon generation and continuous sand bodies close to the hydrocarbon kitchen are the foundation for the large-scale oil distribution.Dissolution of feldspar-laumontite during the process of organic matter evolution generated abundant secondary pores and improved the reservoir quality.     

Triterpenols as Proxies for Tracking the Mangrove Evolution in China

正Objective Located at the interface of terrestrial and marine ecosystems,mangroves are particularly sensitive to environmental changes.They provide a sedimentary sink for organic carbon,whereby core samples could provide detailed records of mangrove evolution.Human induced,rapid environmental changes in recent years require a better understanding of the mangrove ecosystems evolution in the past,by reconstructing the past mangrove     

天津市地热资源开发利用特征及存在问题分析

天津地区的地热地质条件良好,蕴藏着丰富的地热资源。在地热资源的开发利用过程中,每年可产生可观的经济、社会和环境效益,但由于开发方式的不尽合理,带来诸多问题。文章阐述了天津开发利用地热资源的特征,分析了存在的问题。认为不同热储层间水力联系的存在和地热井间距的过小,造成开采层间相互影响较大;地热井布局不合理、开采层位相对集中、回灌程度不高导致局部热储层压力大幅度下降,持续的大幅度压力下降将引发吊泵和地面沉降;超标准排放地热尾水会造成资源浪费和热污染;采、灌井间距的过小和相对位置的不合理,存在冷突破风险。针对不同问题,给出了针对性解决问题的建议。     

透明类岩石内置三维裂纹扩展变形试验研究

采用力学试验手段探究岩石受压情况下内部裂纹扩展贯通机制是了解岩石破坏失稳机制的重要手段。由于无法观察真实岩体内部裂纹扩展过程且CT扫描实时性不足等原因,自行研制了一种各项性质与岩石接近的透明类岩石材料,以观察研究其内部三维裂纹的扩展贯通机制。这一方法克服了真实岩体不透明的特点,可更方便地观察岩体内部裂纹萌生、扩展不同阶段的形状。然后制作了一批内置单裂隙和双裂隙的试件,在RMT-150B多功能全自动刚性岩石伺服试验机上进行单轴压缩试验,详细观察研究了单裂隙和双裂隙试件在不同岩桥角和裂隙间距情况下的裂纹扩展贯通模式以及裂隙数量和间距对试件抗压强度的影响,并从理论方面对翼形裂纹的扩展过程进行了解释。试验表明,在不同的岩桥角和裂隙间距下,次生裂纹将呈现不同的扩展贯通模式,试验中观察到的次生裂纹有张拉翼裂纹、与翼裂纹反向生长的反翼裂纹和拉剪作用下的花瓣状裂纹等,试件最终破坏是各种形式的裂纹汇合贯通的结果。裂隙的存在极大地降低了试件的抗压强度,且随着裂隙数目增加,试件峰值强度呈降低趋势,同时裂隙间距也对试件的峰值强度产生一定的影响。试验成果对分析真实岩体的破坏失稳机制有着重要的参考价值。     

钦-杭成矿带东段村前含矿斑岩地球化学特征及其构造环境与成矿意义

村前铜多金属矿床位于钦杭成矿带东段,为一具有矽卡岩型矿化和斑岩型矿化的铜多金属矿床,含矿岩体为燕山早期花岗闪长斑岩,岩石具有富硅、富铝、富碱的特点,属于偏铝-过铝质钙碱性花岗岩类。岩体具有从深部向浅部蚀变增强,大部分组分活动性不明显,而成矿元素Cu-Mo-Fe-Pb-Zn-Au-Ag含量明显增加,Na2O、Sr含量降低,REE元素除Eu少量丢失外,其余均呈一致的迁入特征。岩体属Ⅰ型花岗质岩石,由具角闪石+石榴子石残留相的火成岩部分熔融形成的熔浆,混合或混染了地壳重熔型岩浆上侵就位而成。钦杭结合带东段,燕山期中酸性岩浆活动具有从176~150Ma的埃达克岩或具岛弧花岗岩特征的Ⅰ型花岗岩,至150~140Ma的S型花岗岩,向140~110Ma的A型花岗岩演化趋势,显示了地壳由厚减薄的过程,暗示其大地构造背景为岩石圈的伸展减薄环境,而形成于169.3±1.1Ma的村前斑岩体正处于伸展阶段早期。综合岩体成矿特征表明,钦杭成矿带东段及邻近地区,176~160Ma主要形成与Ⅰ型花岗质岩石有关的以Cu为主的多金属矿床;160~150Ma主要形成与Ⅰ型花岗质岩石有关的Cu-Mo矿床与W-Sn矿床;150~140Ma主要形成与S型花岗质岩石有关的以W-Sn-Mo为主的多金属矿床,以及以Ag-Pb-Zn为主的多金属矿床;140~110Ma主要形成与A型花岗质岩石有关的以W-Sn-Mo为主的多金属矿床,少量与Ⅰ型花岗质岩石有关的Pb-Zn矿床。     

新疆塔县达布达尔地区二叠系神仙湾组杂砂岩沉积构造背景分析

新疆塔县达布达尔地区二叠系神仙湾组位于塔阿西构造混杂岩带南侧,总体为一套深海复理石建造,主要以杂砂岩为主。源区岩石没有经过充分的搬运、分选,成熟度比较低。杂砂岩的稀土元素特征表现为轻稀土元素富集和Eu亏损明显的特征,与典型的后太古宙页岩和上地壳非常相似。微量元素含量也接近于大陆上地壳值,说明杂砂岩中的物源来自上地壳。沉积环境分析表明,杂砂岩母岩原岩为大量长英质火成物质和少量沉积物,其形成于深海厌氧环境。大地构造背景分析表明,杂砂岩物源区的构造背景以大陆岛弧为主,兼具活动大陆边缘的性质。结合区域地质构造背景,认为下-中二叠统神仙湾组为裂陷盆地沉积。     

动力学模型预测深海鲣鱼(Katsuwonus pelamis)调理食品常温下的货架期

为了预测鲣鱼(Katsuwonus pelamis)调理食品的货架期,将鲣鱼调理食品贮藏在25°C、30°C、35°C温度条件下,通过测定在贮藏期间菌落总数、挥发性盐基氮、过氧化值三个指标的变化,分别对这三个指标与贮藏时间、温度建立一级动力学模型,来预测鲣鱼调理食品的货架期。经计算得出,菌落总数预测模型中的活化能(Ea)及指前因子(k0)分别为30.96 k J/mol和2.06×103,挥发性盐基氮预测模型中的的活化能及指前因子分别为24.35 k J/mol和75.1,过氧化值预测模型中的活化能及指前因子分别为48.75 k J/mol和2.92×106。在32°C和37°C条件下验证动力学模型,结果表明相对误差分别为–5.52%和–6.45%,准确性较好。进一步推算得出,在18°C和23°C常温下贮藏鲣鱼调理食品,产品的货架期为209d和172d。     

褐菖鲉(Sebastiscus marmoratus)受精卵以及仔鱼期氨基酸与脂肪酸变化研究

为研究褐菖鲉(Sebastiscus marmoratus)发育早期氨基酸和脂肪酸的组成及变化规律,采用GC/MS法等方法分析了褐菖鲉的受精卵、初产仔鱼、前仔鱼期和后仔鱼期四个阶段的氨基酸和脂肪酸组成特点及其含量变化。结果表明:(1)总氨基酸含量从受精卵至初产仔鱼显著下降、前仔鱼期又显著回升、至后仔鱼期再次呈显著下降(P0.05);(2)总游离氨基酸量以初产仔鱼最高,是受精卵的10倍,各期的游离氨基酸占总氨基酸比值为1.4%—20.0%;(3)受精卵中以DHA、C16:0两者实际含量最高,分别为104.88 mg/g和68.74 mg/g,C18:1n-9和EPA次之,分别为41.23 mg/g和27.23 mg/g;(4)褐菖鲉内源性营养阶段被选择性消耗的主要脂肪酸依次为C16:0C18:1EPADHAARA,就脂肪酸的利用率而言MUFASFAPUFA;(5)褐菖鲉仔鱼在开口后的外源营养阶段对脂肪酸的利用率为PUFASFAMUFA,其中DHA相对EPA和ARA被选择性消耗。研究表明,褐菖鲉受精卵的游离氨基酸/总氨基酸比值符合海水鱼类沉性卵的特征,褐菖鲉在早期发育不同阶段对脂肪酸消耗具有不同的选择性,C16:1、C16:0、C18:0和C18:1是褐菖鲉早期发育的主要能源物质,在褐菖鲉开口饵料中添加一定水平的异亮氨酸、亮氨酸、酪氨酸等氨基酸及高度不饱和脂肪酸DHA等是十分必要的。     

白令海夏季浮游植物的群落结构与时空变化

通过1999年和2010年夏季同期7月在白令海(169°E~166°W,50°N~67°N)获取的94份浮游植物样品分析,获得了近十年的始末两个时间节点的浮游植物群落结构与时空变化,探讨了浮游植物群落动态及其与环境因素的关联。研究结果显示,共鉴定浮游植物(>10μm)5门58属153种,分为3个生态类群。硅藻是浮游植物的主体,种类多丰度高,占总种类数目的66.7%,占总丰度的95.2%。鉴于样品属性和空间范围的不同,物种组成有细微差别,丰度有较大差异且空间分布明显不同,高丰度区受控于上层营养盐供给和表层环流系统。优势种从北方温带大洋性硅藻演变为广温广盐性与冷水性硅藻,1999年以西氏新细齿状藻为第一优势种,柔弱伪菱形藻次之;2010年以丹麦细柱藻为第一优势种,冷水性的诺登海链藻次之并在陆架和陆坡占优。浮游植物群落结构较为稳定,由深水群落和浅水群落组成。深水群落分布于太平洋西北部和白令海盆,种类组成以温带大洋性的西氏新细齿状藻、长海毛藻、大西洋角毛藻和广布性的菱形海线藻、扁面角毛藻、笔尖根管藻为主,丰度低,种间丰度分配均匀,优势种多元化,物种多样性高;浅水群落分布于白令海陆坡和陆架,主要由冷水性的诺登海链藻、叉尖角毛藻、聚生角毛藻和广布性的丹麦细柱藻、旋链角毛藻组成,丰度高,种间丰度分配不均匀,优势种突出,物种多样性低。白令海夏季浮游植物种类组成及丰度变化直接受控于表层环流、营养盐、春季冰缘线等环境因素。