Ultra-Trace Element Analysis of NIST SRM 616 and 614 using Laser Ablation Microprobe-Inductively Coupled Plasma-Mass Spectrometry (LAM-ICP-MS): a Comparison with Secondary Ion Mass Spectrometry (SIMS)

The microanalytical capability of laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS) to determine ultra trace elemental concentrations has been demonstrated by the analysis of two low concentration glass standard reference materials, NIST SRM 614 and 616. Results for fifty two elements at concentrations in the low ng g^-1 range are compared with those determined using secondary ion mass spectrometry (SIMS). Both techniques provide results at these concentrations that generally agree within 95% confidence limits, demonstrating the accuracy for ultra-trace level of in situ determinations by the two techniques. At concentrations of less than 20 ng g^-1 in NIST SRM 616, an accuracy and precision of better than 10% has been obtained for most mono-isotopic rare earth elements, when a spot size of 50 μm is used. Limits of detection for selected elements were as low as 0.5 ng g^-1.     

Asymmetrical turbid surface-plume deposition near ice-outlets of the Pleistocene Laurentide ice sheet in the Labrador Sea

 Ice-sheet drainage of glacial detritus into the sea involves size fractionation by ice-margin winnowing on a giant scale caused by the lower density of meltwater entering cold seawater. Despite its load of suspended sediment, the fresh water rises to or stays at the sea surface forming turbid surface plumes, whereas the coarse-grained sediment forms bed load. On the Labrador Slope south of the Hudson Strait turbid plumes were supplied by meltwater from the Pleistocene ice sheet (LIS). Sediments with the seismic characteristics of plume deposits occur in a 200-km-long slope sector up to 130 km seawards from the strait. The widespread distribution of these deposits is attributed to entrainment of the surface plumes by the south-flowing Labrador Current and suppressed flocculation due to the high detrital carbonate-content of the suspended sediment. Deposits with typical characteristics of surface plume deposits have been recovered within 20 km from former ice margin south of or in front of outlets, but not north of outlets. They consist of 1 to 2-cm-thick alternations of fine sandy silt/coarse silt layers with finer-grained clayey silt/silty clay, and for brevity are called plumites. Received: 6 August 1996/Revision received: 21 January 1997     

Noble gas studies in CAIs from CV3 chondrites: No evidence for primordial noble gases

Abstract— Calcium‐aluminum‐rich inclusions (CAIs) were among the first solids in the solar system and were, similar to chondrules, created at very high temperatures. While in chondrules, trapped noble gases have recently been detected, the presence of trapped gases in CAIs is unclear but could have important implications for CAI formation and for early solar system evolution in general. To reassess this question, He, Ne, and Ar isotopes were measured in small, carefully separated and, thus, uncontaminated samples of CAIs from the CV3 chondrites Allende, Axtell, and Efremovka. The ²⁰Ne/²²Ne ratios of all CAIs studied here are <0.9, indicating the absence of trapped Ne as, e.g., Ne‐HL, Ne‐Q, or solar wind Ne. The ²¹Ne/²²Ne ratios range from 0.86 to 0.72, with fine‐grained, more altered CAIs usually showing lower values than coarse‐grained, less altered CAIs. This is attributed to variable amounts of cosmogenic Ne produced from Na‐rich alteration phases rather than to the presence of Ne‐G or Ne‐R (essentially pure ²²Ne) in the samples. Our interpretation is supported by model calculations of the isotopic composition of cosmogenic Ne in minerals common in CAIs. The ³⁶Ar/³⁸Ar ratios are between 0.7 and 4.8, with fine‐grained CAIs within one meteorite showing higher ratios than the coarse‐grained ones. This agrees with higher concentrations of cosmogenic ³⁶Ar produced by neutron capture on ³⁵Cl with subsequent β^?‐decay in finer‐grained, more altered, and thus, more Cl‐rich CAIs than in coarser‐grained, less altered ones. Although our data do not strictly contradict the presence of small amounts of Ne‐G, Ne‐R, or trapped Ar in the CAIs, our noble gas signatures are most simply explained by cosmogenic production, mainly from Na‐, Ca‐, and Cl‐rich minerals.     

Paleomagnetism of the western Cape Fold belt, South Africa, and its bearing on the Paleozoic apparent polar wander path for Gondwana

In order to test two different proposals for the poorly defined African Paleozoic apparent polar wander path (APWP), a paleomagnetic study was carried out on Ordovician through Carboniferous clastic sediments from the Cape Fold belt, west of the 22nd meridian. One proposal involves a relatively simple APWP connecting the Ordovician Gondwana poles in North Africa with the Late Paleozoic poles to the east of South Africa in a more or less straight line crossing the present equator in the Devonian. The other proposal adds a loop to this path, connecting Ordovician poles in North Africa with poles to the southwest of South Africa and then returning to central Africa. This loop would occur mainly in Silurian time. New results reported herein yield paleopoles in northern and central Africa for Ordovician to lowermost Silurian and Lower to Middle Devonian formations. The best determined paleopole of our study is for the Early Ordovician Graafwater Formation and falls at 28°N, 14°E (k = 25, α₉₅ = 8.8°, N = 28 samples). The other paleopoles are not based on sufficient numbers of samples, but can help to constrain the apparent polar wander path for Gondwana. Our results give only paleopoles well to the north of South Africa and we observe no directions within the proposed loop. Hence, if the loop is real, it must have been of relatively short duration (60–70 Ma) and be essentially of Silurian/Early Devonian age, implying very high drift velocities for Gondwana (with respect to the pole) during that interval.     

The spatial configuration of innovation networks in China

China is rising and gradually developing into an innovation-oriented economy. This transition is fueled by public and private investment in education and by increasing inputs into science and technology. Little attention, however, has been paid to the great differences in China-specific context peculiarity. Hence, the paper assesses Chinese innovation networks using a comprehensive analytical model that includes network configuration, regional environment, government interference and firm attributes. The empirical analysis examines China’s machinery manufacturing industry to test the determinants of the spatial character of Chinese innovation networks based on questionnaire surveys and illustrative cases. Our study finds that Chinese innovation networks are affected not only by innovation resource endowments and firm attributes, but also by government interference and regional culture. Regarding the influence of regional culture, the typical Northern culture with the importance of guanxi plays an important role in the process of searching for partners and makes the innovation network and interpersonal network interwoven. Firms’ ownership and innovation ability are the two essential variables to determine whether any of the regional elements are of significance.     

The Mangrove Ecosystem of the Ciénaga Grande de Santa Marta (Colombia): Observations on Regeneration and Trace Metals in Sediment

Alteration of water flows and consequent hypersalinization caused the death of nearly 70% of mangroves at the Ciénaga Grande de Santa Marta, Colombia. Efforts to rehabilitate the ecosystem have been made through the construction of freshwater channels. Mangrove recovery was observed along a freshwater channel and at a small lagoon behind the beach ridge. Factors identified in this study influencing mangrove regeneration are: salinity of surface water, duration and height of flooding, leaching property of soils, dispersal of propagules and presence of fertile trees. Besides mangrove regeneration, a notable extension of freshwater plants was observed in the channel. Trace metal concentrations in sediments from the Magdalena River and its area of influence were investigated before the complete opening of the first channel. A relative comparison indicated that the highest concentrations of Cd, Cu, Ni and Zn were above international recommended limits. However, metal concentrations found in sediments at Clarín Channel did not affect the mangrove recovery.     

The production of cosmogenic nuclides in stony meteoroids by galactic cosmic‐ray particles

Abstract— We present a purely physical model for the calculation of depth‐ and size‐dependent production rates of cosmogenic nuclides by galactic cosmic‐ray (GCR) particles. besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on only one free parameter—the integral number of gcr particles in the meteoroid orbits. We derived this value from analysis of radionuclide data in Knyahinya. We also show that the mean GCR proton spectrum in the meteoroid orbits has been constant over about the last 10 Ma. For the major target elements in stony meteoroids, we present depth‐ and size‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl, and ⁵³Mn as well as for the rare gas isotopes ³He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, and ³⁸Ar. The new data differ from semi‐empirical estimates by up to a factor of 4 but agree within ～20% with results obtained by earlier parametric or physical approaches. The depth and size dependence of the shielding parameter ²²Ne/²¹Ne and the correlations ²⁶Al vs. ¹⁰Be, ²⁶Al vs. ⁵³Mn, ¹⁰Be/²¹Ne vs. ²²Ne/²¹Ne, and ³⁶Ar vs. ³⁶Cl for deciphering preatmospheric sizes, shielding depths, terrestrial residence times, and exposure histories are also discussed.