A simulation study of capillary transport,preferential retention and distribution of salts in historic sandstone buildings

Salt crystallisation is a major problem of deterioration in historic stone buildings, monuments and sculptures. The capillary rise of soil water is one of the primary sources of salts in stone structures, which evaporates leaving the salts behind. It has been noted that the spatial distribution profile of different species of salts crystallised in historic stone buildings is not homogeneous, i.e. different salts crystallise at different locations. The capillary transport and inhomogeneous spatial distribution of different salts in the porous building materials has been considered to be a result of solubility-dependent crystallisation; however, the factors responsible for this phenomenon are not clearly known. This paper aims to investigate the factors influencing the differential distribution of salts during capillary rise of soil water. In this study, the capillary transport of salts was simulated on two different sandstones—Locharbriggs, a Permo–Triassic, red sandstone and Stoke Hall, a Carboniferous, buff sandstone. The experiments were carried out under controlled environmental conditions to eliminate the possibility of evaporation-driven crystallisation of salts depending on their solubilities. The results indicate that fractionation or differential distribution of salts takes place even in the absence of evaporation and crystallisation. The sandstones exhibit properties like an ion exchange column, and ionic species present in the salt solution show differential distribution within the porous network of sandstone.     

Permeameter data verify new turbulence process for MODFLOW

A sample of Key Largo Limestone from southern Florida exhibited turbulent flow behavior along three orthogonal axes as reported in recently published permeameter experiments. The limestone sample was a cube measuring 0.2 m on edge. The published nonlinear relation between hydraulic gradient and discharge was simulated using the turbulent flow approximation applied in the Conduit Flow Process (CFP) for MODFLOW-2005 mode 2, CFPM2. The good agreement between the experimental data and the simulated results verifies the utility of the approach used to simulate the effects of turbulent flow on head distributions and flux in the CFPM2 module of MODFLOW-2005.     

Source depletion and extent of melting in the Tongan sub-arc mantle

The fluid immobile High Field Strength Elements (HFSE) Nb and Ta can be used to distinguish between the effects of variable extents of melting and prior source depletion of the Tongan sub-arc mantle. Melting of spinel lherzolite beneath the Lau Basin back-arc spreading centres has the ability to fractionate Nb from Ta due to the greater compatibility of the latter in clinopyroxene. The identified spatial variation in plate velocities and separation of melt extraction zones, combined with extremely depleted lavas make Tonga an ideal setting in which to test models for arc melt generation and the role of back-arc magmatism.We present new data acquired by laser ablation-ICPMS of fused sample glasses produced without the use of a melt fluxing agent. The results show an arc trend towards strongly sub-chondritic Nb/Ta (< 17) with values as low as 7.2. Melting models show that large degree melts of depleted MORB mantle fail to reproduce the observed Nb/Ta. Alternatively, incorporation of residual back-arc mantle that has undergone less than 1% melting into the sub-arc melting regime reproduces arc values. However, the extent of partial melting required to produce the composition of the Lau Basin back-arc basalts averages 7%. This apparent discrepancy can be explained if only the lowermost 4 km of the residua from the mantle melt column beneath the back-arc is added to the source of arc magmas. We have identified that the degree of arc/back-arc coupling displayed in the rock record provides an index of the depth of hydrous melting beneath the arc. In this case, this would imply a depth of ~ 75 km for generation of arc magmas, indicating that hydrous melting in the mantle wedge is triggered by the breakdown of hydrous phases in the subducting slab.     

COMPUTER MODELING OF VERTICAL SEISMIC PROFILING*

There are numerous modeling techniques commonly employed for the computer simulation of seismic wave propagation. The capabilities of these techniques vary according to the theoretical foundations and subsequent approximations upon which the algorithms are based. This paper constitutes a comparative review of seven modeling methods: geometric ray theory, asymptotic ray theory, generalized ray theory, Kirchhoff wave theory, Fourier synthesis, finite differences, and finite elements. These methods can be categorized as ray or wave, acoustic or elastic, and can be contrasted according to their relative abilities to simulate such behavior as wave interference effects, diffractions, and mode conversions. As is implied by their names, geometric ray theory and asymptotic ray theory are both ray methods. The other five methods provide wave theory simulations. Geometric ray theory and Kirchhoff wave theory are normally implemented in acoustic form, while the other methods are readily adapted for computing elastic theory solutions. Generalized ray theory and Fourier synthesis are more limited in the complexity of geological model they can accommodate than are the other techniques. The methods which typically demand the greatest computer resources are the finite-difference and the finite-element techniques. All methods can incorporate at least some multiple events. Diffractions, however, are only inherent in the solutions computed by Kirchhoff wave theory, finite differences and finite elements. Attenuation is readily incorporated in both the Fourier synthesis and the finite-element methods. As an example of the application of seismic modeling, a geological model representative of a typical petroleum exploration target is used to compare vertical seismic profiles calculated by different modeling methods.     

A statistical study of pressure changes in the troposphere and lower stratosphere after strong solar flares

Summary The average change in height of several constant pressure levels in the troposphere and lower stratosphere after a strong solar flare is described. The analysis covers the northern hemisphere north of 10°N and is based on a sample of 81 carefully selected flares from the period July 1957 through December 1959.The statistical significance of the results is tested by drawing a comparison with the results obtained when one applies exactly the same analysis to three samples of 81 random key-dates selected from the same period.Properties of the reaction pattern are (1) it is pronounced at high as well as low latitudes, (2) it consists of alternating cells of positive and negative height change, (3) it is established within six hours after the flare, and (4) the maximum response occurs near the tropopause.It appears more likely that the atmospheric reaction pattern can be attributed to very energetic solar particles rather than to enhanced ultraviolet radiation.     

Spatial and seasonal distribution of bacterial physiological groups in two reservoirs with different trophic levels

The spatial and seasonal distribution of the viable heterotrophic population and three heterotrophic physiological groups, i.e. ammonifyers, nitrate reducers and sulphate reducers, were studied in two reservoirs in the province of Vizcaya (Spain). Using indicative parameters, both reservoirs were classified as warm monomictics, one hypereutrophic and the other mesotrophic. A direct relation between the size of the bacterial populations and the trophic levels of the reservoirs was observed. Likewise, the distributions of the bacterial populations in the water column are basically different. In the hypereutrophic lake there is a direct relationship between the bacterial distribution and the physical-chemical environment of the reservoir that cannot be observed in the mesotrophic lake.     

Statistical assessment of seismicity patterns in Italy: Are they precursors of subsequent events?

The variations of seismicity rate in Central Apenninesprior to the sequence started in September, 1997 (at00:33 UTC, M _L5.6) has been analysedby statistical methods, with the purpose of pointingup eventual periods of quiescence. The analysis wascarried out on the instrumental catalogue of theIstituto Nazionale di Geofisica (ING), covering theperiod from January 1975 to March 1998. In apreliminary phase, the catalogue was declustered usingthe Reasenberg algorithm. After that, eventualmagnitude shifts due to variations in the modalitiesof observation have been individuated and corrected.The subsequent analysis, carried out making use of theZmap software package, has put in evidence thatthe sequence of September 1997 was preceded bya 2.5 year period characterised by absence of eventsof magnitude larger than 3.2, in an area approximately20 × 40 km wide, including the epicentre of themain shock. The statistical methodology shows thatonly 1/10³ of the space-time volumes analysed inthis study, exhibited quiescence of the same level.The study of seismicity rate change correlated toprevious main shocks in a larger area of CentralApennines shows that none of them were preceded by aseismic quiescence, specially close to the epicentreof the main shock, and lasting until the time ofoccurrence of the main shock as in the 1997 case.Actually, we found other patterns of precursoryquiescence with different time or space distribution.We conclude that precursory quiescence is a realfeature of Central Apennines seismicity, but it isdifficult to define a simple hypothesis, which appliesto the generality of cases and can be tested beforeimplementation in a system of earthquake riskmitigation.