Sediment storage and severity of contamination in a shallow reservoir affected by historical lead and zinc mining

A combination of sediment-thickness measurement and bottom-sediment coring was used to investigate sediment storage and severity of contamination in Empire Lake (Kansas), a shallow reservoir affected by historical Pb and Zn mining. Cd, Pb, and Zn concentrations in the contaminated bottom sediment typically exceeded baseline concentrations by at least an order of magnitude. Moreover, the concentrations of Cd, Pb, and Zn typically far exceeded probable-effects guidelines, which represent the concentrations above which toxic biological effects usually or frequently occur. Despite a pre-1954 decrease in sediment concentrations likely related to the end of major mining activity upstream by about 1920, concentrations have remained relatively stable and persistently greater than the probable-effects guidelines for at least the last 50 years. Cesium-137 evidence from sediment cores indicated that most of the bottom sediment in the reservoir was deposited prior to 1954. Thus, the ability of the reservoir to store the contaminated sediment has declined over time. Because of the limited storage capacity, Empire Lake likely is a net source of contaminated sediment during high-inflow periods. The contaminated sediment that passes through, or originates from, Empire Lake will be deposited in downstream environments likely as far as Grand Lake O’ the Cherokees (Oklahoma).     

Could working less reduce pressures on the environment? A cross-national panel analysis of OECD countries, 1970–2007

Many scholars and activists are now advocating a program of economic degrowth for developed countries in order to mitigate demands on the global environment. An increasingly prominent idea is that developed countries could achieve slower or zero economic growth in a socially sustainable way by reducing working hours. Research suggests that reduced working hours could contribute to sustainability by decreasing the scale of economic output and the environmental intensity of consumption patterns. Here, we investigate the effect of working hours on three environmental indicators: ecological footprint, carbon footprint, and carbon dioxide emissions. Using data for 1970–2007, our panel analysis of 29 high-income OECD countries indicates that working hours are significantly associated with greater environmental pressures and thus may be an attractive target for policies promoting environmental sustainability.     

Theoretical predictions of deuterium abundances in the Jovian planets

Using current concepts for the origin of the Jovian planets and current constraints on their interior structure, we argue that the presence of large amounts of “ice” (H₂O, CH₄, and NH₃) in Uranus and Neptune indicates temperatures low enough to condense these species at the time Uranus and Neptune formed. Yet such low temperatures imply orders-of-magnetude fractionation effects for deuterium into the “ice” component if isotopic equilibration can occur. Our models thus imply that Uranus and Neptune should have a D/H ratio at least four times primordial, contrary to observation for Uranus. We find that the Jovian and Saturnian D/H should be close to primordial regardless of formation scenario. The Uranus anomaly could indicate that there was a strong initial radial gradient in D/H in the primordial solar nebula, or that Uranus is so inactive that no significant mixing of its interior has occurred over the age of the solar system. Observation of Neptune's atmospheric D/H may help to resolve the problem.     

Modelling the response of glaciers to climate warming

 Dynamic ice-flow models for 12 glaciers and ice caps have been forced with various climate change scenarios. The volume of this sample spans three orders of magnitude. Six climate scenarios were considered: from 1990 onwards linear warming rates of 0.01, 0.02 and 0.04 K a^-1, with and without concurrent changes in precipitation. The models, calibrated against the historic record of glacier length where possible, were integrated until 2100. The differences in individual glacier responses are very large. No straightforward relationship between glacier size and fractional change of ice volume emerges for any given climate scenario. The hypsometry of individual glaciers and ice caps plays an important role in their response, thus making it difficult to generalize results. For a warming rate of 0.04 K a^-1, without increase in precipitation, results indicate that few glaciers would survive until 2100. On the other hand, if the warming rate were to be limited to 0.01 K a^-1 with an increase in precipitation of 10% per degree warming, we predict that overall loss would be restricted to 10 to 20% of the 1990 volume. Received: 30 June 1997/Accepted: 21 October 1997     

Simulating sensitivity of soil moisture and evapotranspiration under heterogeneous soils and land uses

Soil moisture (SM) plays an important role in land surface and atmospheric interactions. It modifies energy balance at the surface and the rate of water cycling between the land and atmosphere. In this paper we provide a sensitivity assessment of SM and ET for heterogeneous soil physical properties and for three land uses including irrigated maize, rainfed maize, and grass at a climatological time-scale by using a water balance model. Not surprisingly, the study finds increased soil water content in the root zone throughout the year under irrigated farming. Soil water depletes to its lowest level under rainfed maize cultivation. We find a ‘land use’ effect as high as 36 percent of annual total evapotranspiration, under irrigated maize compared to rainfed maize and grass, respectively. Sensitivity analyses consisting of comparative simulations using the model show that soil characteristics, like water holding capacity, influence SM in the root zone and affect seasonal total ET estimates at the climatological time-scale. This ‘soils’ effect is smaller than the ‘land use’ effect associated with irrigation but, it is a source of consistent bias for both SM and ET estimates. The ‘climate’ effect basically masks the ‘soils’ effect under wet conditions. These results lead us to conclude that appropriate representation of land use, soils, and climate are necessary to accurately represent the water and energy balance in real landscapes.     

Characterization of Persistent Volatile Contaminant Sources in the Vadose Zone

Effective long‐term operation of soil vapor extraction (SVE) systems for cleanup of vadose‐zone sources requires consideration of the likelihood that remediation activities over time will alter the subsurface distribution and configuration of contaminants. A method is demonstrated for locating and characterizing the distribution and nature of persistent volatile organic contaminant (VOC) sources in the vadose zone. The method consists of three components: analysis of existing site and SVE‐operations data, vapor‐phase cyclic contaminant mass‐discharge testing, and short‐term vapor‐phase contaminant mass‐discharge tests conducted in series at multiple locations. Results obtained from the method were used to characterize overall source zone mass‐transfer limitations, source‐strength reductions, potential changes in source‐zone architecture, and the spatial variability and extent of the persistent source(s) for the Department of Energy's Hanford site. The results confirmed a heterogeneous distribution of contaminant mass discharge throughout the vadose zone. Analyses of the mass‐discharge profiles indicate that the remaining contaminant source is coincident with a lower‐permeability unit at the site. Such measurements of source strength and size as obtained herein are needed to determine the impacts of vadose‐zone sources on groundwater contamination and vapor intrusion, and can support evaluation and optimization of the performance of SVE operations.     

Diurnal fluctuations in glacier ice deformation: Haut Glacier d'Arolla,Switzerland

Measurements of surface velocity, ice deformation (at 42 and 89% ice depth) and proglacial stream discharge were made at Haut Glacier d'Arolla, Switzerland, to determine diurnal patterns of variation in each. Data are analysed in order to understand better the relationship between hydraulically induced basal motion and glacier ice deformation over short timescales. The data suggest that hydraulically induced localized basal ‘slippery’ spots are created over diurnal cycles, causing enhanced basal motion and spatially variable glacier speed‐up. Our data indicate that daily glacier speed‐up is associated with reduced internal deformation over areas previously identified as slippery spots and increased deformation in areas located adjacent to or down‐glacier from slippery spots. We interpret this pattern in terms of a transfer of mechanical support for basal shear stress away from slippery spots to adjacent sticky areas, where the resulting stronger ice–bed coupling causes increased ice deformation near the bed. These patterns indicate that basal ice is subjected to stress regimes that are variable at a high spatial and temporal resolution. Such variations may be central to the creation of anomalous vertical velocity profiles measured above and down‐glacier of basal slippery zones, which have shown evidence for ‘plug flow’ and extrusion flow over annual timescales. Copyright © 2007 John Wiley & Sons, Ltd.     

Autogenic incision‐backfilling cycles and lobe formation during the growth of alluvial fans with supercritical distributaries

Autogenic cycles of channelization, terminal deposit formation, channel backfilling and channel abandonment have been observed in the formation of fans and deltas. In subcritical flow, these terminal deposits are characterized as mouth bars that lead to flow bifurcation, backwater and eventual channel backfilling. Similar, although less well characterized, cycles also take place on supercritical subaerial and submarine fans. This study investigates the hydraulics and morphodynamics of autogenic incision and backfilling cycles associated with supercritical distributive channel flow in alluvial fans. The research questions of the study are: (i) how are supercritical autogenic cycles on alluvial fans different from the subcritical cycles; (ii) what are the hydraulic and sediment transport characteristics at the various stages of autogenic feedback cycles; and (iii) what role do the cycles play in the overall fan evolution? These questions are investigated in the laboratory, and emphasis is placed on measuring the hydraulic and topographic evolution of the systems during the cycles. The cycles arise quasi‐periodically under constant water and sediment discharge. Periods of sheet‐like flow are competent to move sediment () but not competent enough to carry the full imposed load. The net result is preferential deposition near the inlet, resulting in fan steepening and an increase in flow competency with time. At a sediment supply to capacity ratio of , the sheet‐like flow is unstable to small erosional events near the inlet, resulting in the collapse of the distributed flow to a strong channelized state. During channelization, a graded () supercritical (Fr > 1) channel develops and transports eroded and fed sediment up to and through the fan front – extending the fan, initiating a lobe shaped deposit and reducing the local slope. The slopes defined by a sheet‐like flow with and channelized flow with set the maximum and minimum slopes on the fan, respectively. Once formed, graded channels act as bypass conduits linking the inlet with the terminal deposit. On average, deposits are up to six channel depths in thickness and have volumes approximately five times that of the excavated channel. The main distinctive characteristics of the supercritical cycles relate to how the flow interacts with the terminal deposit. At the channel to deposit transition, the flow undergoes a weak hydraulic jump, resulting in rapid sedimentation, dechannelization and lateral expansion of the flow, and deposition of any remaining sediment on top of the channel fill and floodplain. This process often caps the channel as the deposit propagates up channel erasing memory of the excavated channel.     

Global and regional evolution of short-lived radiatively-active gases and aerosols in the Representative Concentration Pathways

In this paper, we discuss the results of 2000?C2100 simulations following the emissions associated with the Representative Concentration Pathways (RCPs) with a chemistry-climate model, focusing on the changes in 1) atmospheric composition (troposphere and stratosphere) and 2) associated environmental parameters (such as nitrogen deposition). In particular, we find that tropospheric ozone is projected to decrease (RCP2.6, RCP4.5 and RCP6) or increase (RCP8.5) between 2000 and 2100, with variations in methane a strong contributor to this spread. The associated tropospheric ozone global radiative forcing is shown to be in agreement with the estimate used in the RCPs, except for RCP8.5. Surface ozone in 2100 is projected to change little compared from its 2000 distribution, a much-reduced impact from previous projections based on the A2 high-emission scenario. In addition, globally-averaged stratospheric ozone is projected to recover at or beyond pre-1980 levels. Anthropogenic aerosols are projected to strongly decrease in the 21st century, a reflection of their projected decrease in emissions. Consequently, sulfate deposition is projected to strongly decrease. However, nitrogen deposition is projected to increase over certain regions because of the projected increase in NH₃ emissions.