Mössbauer studies of structural features in tourmaline of various genesis

Nuclear gamma ray (Mössbauer) spectroscopy (ngr) was used to examine 114 samples of tourmaline from different deposits. The absorption curve shape of the ngr spectra was found to depend not only on tourmaline composition, but also on the character of cation distribution in the crystal structure. The complex superpositional nature of the spectra corresponds to a statistical distribution of iron ions, whereas a minimum number of doublets is observed in an ordered distribution of these ions in the structure. The existence of nonequivalent Fe sites with statistical cation distribution in Y and Z positions was confirmed by experiments on iron oxidation in tourmaline, temperature studies of quadrupole splitting, and probability analysis of formation of nonequivalent sites in accordance with the tourmaline structure. We established experimentally that iron ions in Y positions have a lower ionization potential than in Z positions. The coefficient of iron oxidation in tourmaline, the occupancy of crystallographic positions, and the nature of cation distribution in the structure are features permitting identification of the particular genetic type to which the test sample belongs.     

Olivine in the Udachnaya-East Kimberlite (Yakutia, Russia): Types, Compositions and Origins

Olivine is the principal mineral of kimberlite magmas, and isthe main contributor to the ultramafic composition of kimberliterocks. Olivine is partly or completely altered in common kimberlites,and thus unavailable for studies of the origin and evolutionof kimberlite magmas. The masking effects of alteration, commonin kimberlites worldwide, are overcome in this study of theexceptionally fresh diamondiferous kimberlites of the Udachnaya-Eastpipe from the Daldyn–Alakit province, Yakutia, northernSiberia. These serpentine-free kimberlites contain large amountsof olivine (50 vol.%) in a chloride–carbonate groundmass.Olivine is represented by two populations (olivine-I and groundmassolivine-II) differing in morphology, colour and grain size,and trapped mineral and melt inclusions. The large fragmentalolivine-I is compositionally variable in terms of major (Fo_85–94)and trace element concentrations, including H₂O content (10–136ppm). Multiple sources of olivine-I, such as convecting andlithospheric mantle, are suggested. The groundmass olivine-IIis recognized by smaller grain sizes and perfect crystallographicshapes that indicate crystallization during magma ascent andemplacement. However, a simple crystallization history for olivine-IIis complicated by complex zoning in terms of Fo values and traceelement contents. The cores of olivine-II are compositionallysimilar to olivine-I, which suggests a genetic link betweenthese two types of olivine. Olivine-I and olivine-II have oxygenisotope values (+ 5·6 ± 0·1 VSMOW, 1 SD)that are indistinguishable from one another, but higher thanvalues (+ 5·18 ± 0·28) in ‘typical’mantle olivine. These elevated values probably reflect equilibriumwith the Udachnaya carbonate melt at low temperatures and ¹⁸O-enrichedmantle source. The volumetrically significant rims of olivine-IIhave constant Fo values (89·0 ± 0·2 mol%),but variable trace element compositions. The uniform Fo compositionsof the rims imply an absence of fractionation of the melt'sFe²⁺/Mg, which is possible in the carbonatite melt–olivinesystem. The kimberlite melt is argued to have originated inthe mantle as a chloride–carbonate liquid, devoid of ‘ultramafic’or ‘basaltic’ aluminosilicate components, but becameolivine-laden and olivine-saturated by scavenging olivine crystalsfrom the pathway rocks and dissolving them en route to the surface.During emplacement the kimberlite magma changed progressivelytowards an original alkali-rich chloride–carbonate meltby extensively crystallizing groundmass olivine and gravitationalseparation of solids in the pipe. KEY WORDS: kimberlite; olivine; partial melting; carbonatitic melt; oxygen isotopes; H₂O     

Eclogite trace in evolution of Late Cenozoic alkaline basalt volcanism on the southwestern flank of the Baikal Rift Zone: Geochemical features and geodynamic consequences

Eclogitized material from the oceanic lithosphere are the most likely source of alkaline basalt magmas in the formation of Late Cenozoic volcanic areas on the southwestern flank of the Baikal Rift Zone. Basaltic trachyandesites of the early stage of volcanism (Pg₃² ~ 28–23 Ma) are rich in high field strength elements (HFSE), P₂O₅, F, Zn, Ga, Sr, Sn, and light rare earth elements (LREE); they are characterized by high values of the following ratios: Fe/Mn = 72–77, Sm/Yb = 7.7–8.5, Sr/Y = 57–63, and Ga/Sc = 2.1–2.3. At this stage, magmas are formed under conditions with a 2–8% degree of partial melting of the mantle substrate enriched with the material of the eclogite source (50–70%) (Cpx/Grt = 1.5–1.7). Basaltoid magmas of the final stage of volcanism (N₁³–N₂¹ ~ 6–4 Ma) are formed from melting (1.5–4%) of a less fertilized mantle (Cpx/Grt = 2.1–3.1, Fe/Mn = 62–71, Sm/Yb = 3.5–4.6, Sr/Y = 29–44, Ga/Sc = 1.0–1.4). The directed variations of the compositions of the successive basaltoid magmas, which were formed in the Late Cenozoic, create an “eclogite trace” in this area.     

Geochemistry of obsidian from Krasnoe Lake on the Chukchi Peninsula (Northeastern Siberia)

Doklady Earth Sciences - This report considers features of the geochemical composition of obsidian from beach sediments of Krasnoe Lake along the lower course of the Anadyr River, as well as from...     

Felsic magmas of the caldera-forming eruptions on the Iturup Island: the first results of studies of melt inclusions in phenocrysts from pumices of the Lvinaya Past and Vetrovoy Isthmus calderas

The paper reports the first results of the petrological studies of magmatic melts that formed siliceous pyroclastic deposits related to voluminous eruptions on Iturup Island. The caldera-forming eruptions of the Lvinaya Past and the Vetrovoy Isthmus, having similar features, resulted from the evolution of silicic melts that originated from partial melting of metabasalts. According to the mineral thermometry results, the melt was crystallized at ~800°C. The phenocrysts from the Vetrovoy Isthmus pumices were crystallized at <1 kbar, while those from the Lvinaya Past were formed at higher pressures. The pyroclastic rock compositions in both calderas correspond to moderately aluminous dacite and rhyolitic dacite of the normal series, whose melts likely did not undergo significant crystallization differentiation before the eruptions. The main volatile components of the magma include H₂O, CO₂, S, F, and Cl. Degassing with emission of water–carbon-dioxide fluid accompanied the early crystallization of plagioclase in the Vetrovoy Isthmus pumice. Evidence of pre-eruption melt degassing in the Lvinaya Past were not found. Water release from the melts may be related to both the early magma degassing and the eruptions. The lack of data evidencing the deep differentiation and mixing of contrasting melts implies a relatively small time period between the acid melt appearance and eruptions.     

Peculiarities of giant pulses from the crab pulsar at frequencies of 594 and 2228 MHz

We present the results of our simultaneous observations of giant pulses from the Crab pulsar B0531+21 at frequencies of 594 and 2228 MHz with a high (62.5 ns) time resolution. The pulse broadening by scattering was found to be 25 and 0.4 µs at 594 and 2228 MHz, respectively. We obtained the original giant-pulse profiles compensated for interstellar scattering. The measured profile widths at the two frequencies are approximately equal, ≈0.5 µs; i.e., the giant pulses are narrower than the integrated profile by a factor of about 1000. We detected an extremely high brightness temperature of radio emission, T_b≥10³⁶ K radio emission, which is higher than the previous estimates of this parameter by five orders of magnitude. The decorrelation bandwidth of the radio-spectrum diffraction distortions has been determined for this pulsar for the first time: 10 kHz at 594 MHz and 300 kHz at 2228 MHz.     

Convection and field-aligned currents, related to polar cap arcs, during strongly northward IMF (11 January 1983)

Electric and magnetic fields and auroral emissions have been measured by the Intercosmos-Bulgaria-1300 satellite on 10–11 January 1983. The measured distributions of the plasma drift velocity show that viscous convection is diminished in the evening sector under IMF B_y < 0 and in the morning sector if IMF B_y > 0. A number of sun-aligned polar cap arcs were observed at the beginning of the period of strongly northward IMF and after a few hours a θ-aurora appeared. The intensity of ionized oxygen emission [O⁺(²P), 7320 Å] increased significantly reaching up to several kilo-Rayleighs in the polar cap arc. A complicated pattern of convection and field-aligned currents existed in the nightside polar cap which differed from the four-cell model of convection and NBZ field-aligned current system. This pattern was observed during 12 h and could be interpreted as six large scale field-aligned current sheets and three convective vortices inside the polar cap. Sun-aligned polar cap arcs may be located in regions both of sunward and anti-sunward convection. Structures of smaller spatial scale correspond to the boundaries of hot plasma regions related to polar cap arcs. Obviously these structures are due to S-shaped distributions of electric potential. Parallel electric fields in these S-structures provide electron acceleration up to 1 keV at the boundaries of polar cap arcs. The pairs of field-aligned currents correspond to those S-structures: a downward current at the external side of the boundary and an upward current at the internal side of it.     

Mass-Wasting Processes on the Surface of Phobos

This paper considers morphologic signatures of mass-wasting processes on the surface of Phobos. Two types of downslope movement of material are distinguished: (i) intracrater volume landslides inside impact craters and (ii) downslope near-surface movement of material. Crater statistics for the Stickney area (based on new images of Phobos) showed that the landslide in the crater Stickney could have been formed after resurfacing of the outer rim of the crater in the process of meteorite bombardment. An estimate of the volume of the landslide in Stickney (1–2 km³) and simulation of its movement allowed us to classify the landslide as a long-runout one. The possibility of forming a hummocky topographic relief to the east of Stickney due to the crater ejecta and the emplacement of the frontal part of the long-runout landslide is discussed.     

Orbital forcing of continental climate during the Pleistocene: a complete astronomically tuned climatic record from Lake Baikal, SE Siberia

A new composite BDP-96 biogenic silica record over the entire Pleistocene was generated by splicing BDP-96-1 and BDP-96-2 drill cores from Lake Baikal, crosschecked against a similar record from a nearby BDP-98 drill core. A new astronomically tuned age model is proposed based on correlating peak biogenic silica responses with the timing of September perihelia. This target is derived from analysis of regional climate proxy responses during the Holocene, the last interglacial and around paleomagnetic reversals. By resolving virtually every precessional cycle during the Pleistocene, the new age model represents a major improvement compared with previously reported Lake Baikal timescales. The astronomically tuned ages of the Pleistocene paleomagnetic reversals are consistent with published dates. The minimal tuning approach we used (precession only) has also aligned high signal power in a narrow obliquity band, confirming the strong presence of orbital forcing. There are also strong ca 100-ka scale cycles, but these are not aligned with the orbital eccentricity.Despite the location of Lake Baikal in a continental interior that is highly sensitive to insolation forcing, the tuned biogenic silica record reveals a consistent phase difference of −32° (ca 4 ka) relative to insolation in the obliquity band. An inherent lag embedded in a continental proxy record, not driven by global ice volume, is an intriguing finding. Another new observation is that long-term changes in sedimentation rates in Lake Baikal appear to be related to the amplitude of orbital forcing; both amplitudes and sedimentation rates undergo significant changes during MIS 24-MIS 19 interval corresponding to the Middle Pleistocene Transition. With potential for linking continental and marine climato-stratigraphies, the new Baikal record serves a new benchmark correlation target in continental Eurasia, as an alternative to June 65°N insolation and ODP-correlated timescales.