Size distribution of condensed aromatic rings in various soil humic acids

Condensed aromatic rings are important skeletal components with regard to the recalcitrant nature of humic acids (HAs) in the environment. However, they have not been extensively studied. The relative content and composition (size distribution) of condensed aromatic rings in HAs were obtained from various soils subjected to transmission electron microscopy (TEM) and X-ray diffraction (XRD) profile analysis. In the XRD profiles of all the HAs, the 11 band that was derived from the carbon layer planes was clearly observed. Analysis of the 11 band indicated that the size of the carbon layer planes in HAs ranged from 0.48-1.68 nm, corresponding to 4- to 37-ring condensed aromatic structures. The contents of the total and larger carbon layer planes were larger in HAs with darker color and larger aromatic carbon content. At the same time, the carbon layer planes in HAs were smaller than those in a carbon black reference (from 0.24 to >3.66 nm). In the TEM analysis, fringes observed in HAs were less distinct and less ordered than those in carbon black, which was in agreement with the XRD result.     

Thermal maturity assessment of the Upper Triassic to Lower Jurassic Nampo Group, mid-west Korea: Reconstruction of thermal history

Abstract   Thermal maturity of the Upper Triassic to Lower Jurassic Nampo Group, a sediment-fill of the Chungnam Basin located in the central western part of South Korea, was assessed by illite crystallinity measurement and sandstone microtexture analysis. The Nampo Group consists of a fluvio-lacustrine deposit bearing meta-anthracitic coals and was over-thrusted by the basement rocks. Sandstones are characterized by down sequence increasing illite crystallinity, from anchizone to epizone, which is strongly suggestive of burial heating. Deep-burial diagenesis and deformation are evidenced by well-developed pressure solution textures, whose intensity tends to increase down sequence, and by ductile deformation in the lowermost strata. On the basis of the result of illite crystallinity measurement, the maximum paleo-temperature and total burial depth of the Nampo Group are estimated to be ca 340°C and 10 km, respectively; these conditions are in good agreement with the observed ductile deformation features. The absence of strata younger than the Nampo Group in and around the Chungnam Basin suggests that deep burial of the Nampo Group was caused by tectonic crustal loading. The tectonic overload was because of basement over-thrusting that occurred during the Jurassic Daebo orogeny, which is closely related to the orthogonal subduction of the Izanagi Plate beneath the East Asian continent. Subsequent hydrothermal alteration disturbed the thermal maturity pattern, resulting in anomalously high illite crystallinity and meta-anthracitization.     

Broadband ground-motion simulation of the 24 May 2014 Gokceada (North Aegean Sea) earthquake (Mw 6.9) in NW Turkey considering local soil effects

On 24 May 2014, a Mw 6.9 earthquake occurred in the west of Gokceada Island, northern Aegean Sea. The earthquake was close to Canakkale, Enez, Tekirdag cities, and damaged 300 buildings in the Marmara Region, NW Turkey. We simulated its broadband (0.1–10 Hz) ground motions including 1D deep and shallow structures soil amplification effects at the 12 strong ground motion stations in the western Marmara Region. The 1D deep velocity structures from the focal layer to the engineering bedrock with an S-wave velocity of 0.78 km/s in different azimuthal directions were tuned by comparing the observed group-velocity dispersion curves of Rayleigh and Love waves from the mainshock with theoretical ones. We also added the shallow parts from previous surveys into the 1D models. Synthetic seismograms on the engineering bedrock were generated using the discrete wave number method with a source model and the 1D deep velocity structures. Then the surface motion was generated considering shallow soil amplification. The synthetic seismograms are generally in good agreement with the observed low and high-frequency parts at most of the stations indicating an appropriateness of the source model and the 1D structural model.     

Effect of silica concentration on the diopsidic pyroxenes in the system diopside-CaTiAl2O6SiO2

The effect of silica concentration on the solubility of Al and Ti in diopsidic pyroxenes has been investigated at one atmosphere in the system diopside-CaTiAl₂O₆-SiO₂ at temperatures between 1150–1420° C. The composition of pyroxene in the system diopside-CaTiAl₂O₆-SiO₂ is influenced by the total SiO₂ content. Near the join diopside-CaTiAl₂O₆, the pyroxene forms a solid solution with the CaTiAl₂O₆ molecule, and co-exists with perovskite for compositions greater than 11 weight percent CaTiAl₂O₆. Anorthite is an accompanying phase. With increasing total SiO₂ content a series of mineralogical changes involving Ti-bearing phases occur. Sphene solid solution co-exists with diopside solid solution, anorthite, and perovskite in a small compositional range near the diopside-CaTiAl₂O₆ join. Additional total SiO₂ results in the elimination of perovskite and a decrease of solid solution in the pyroxenes. With further increase in SiO₂ content, tridymite appears and the pyroxene is approximately pure diopside. Rutile joins diopside, anorthite, sphene solid solution and tridymite over a broad compositional range in the Ti, Si-rich part of the system. These results demonstrate that increased silica concentration decreases the solubility of Al and Ti in diopsidic pyroxenes and controls the stability of co-existing Ti-bearing phases.     

Exploration of S-wave velocity profiles at strong motion stations in Eskisehir,Turkey, using microtremor phase velocity and S-wave amplification

We have explored 1D S-wave velocity profiles of shallow and deep soil layers over a basement at strong motion stations in Eskisehir Province, Turkey. Microtremor array explorations were conducted at eight strong motion stations in the area to know shallow 1D S-wave velocity models. Rayleigh wave phase velocity at a frequency range from 3 to 30 Hz was estimated with the spatial autocorrelation analysis of array records of vertical microtremors at each station. Individual phase velocity was inverted to a shallow S-wave velocity profile. Low-velocity layers were identified at the stations in the basin. Site amplification factors from S-wave parts of earthquake records that had been estimated at the strong motion stations by Yamanaka et al. (2017) were inverted to the S-wave velocities and Q-values of the sedimentary layers. The depths to the basement with an S-wave velocity of 2.2 km/s are about 1 km in the central part of the basin, while the basement becomes shallow as 0.3 km in the marginal part of the basin. We finally discussed the effects of the shallow and deep sedimentary layers on the 1D S-wave amplification characteristics using the revealed profiles. It is found that the shallow soil layers have no significant effects in the amplification at a frequency range lower than 3 Hz in the area.     

Study on the relation of river morphology and tsunami propagation in rivers

The relations of river morphology and tsunami propagation in rivers were studied at several rivers in the Tohoku region during The Great Chilean Tsunami of 2010 and The Great East Japan Tsunami of 2011. It was found that river mouth morphological features play an important role in the intrusion of low magnitude tsunamis in which the geological and geographical conditions are an important factor. Nevertheless, the effects of these features were not found in the case of an extreme tsunami wave. As the wave enters the river, the propagation depends on other factors. It was found that the intrusion distance correlates well to the riverbed slope. The measurements of water level and riverbed slope were analyzed to propose an empirical method for estimating the damping coefficient for the tsunami propagation in rivers based on the tsunami of 2011. The proposed empirical method was used to approximate the length of the tsunami intrusion into a river by assuming that the furthest distance is given for the ratio of local tsunami wave height to the tsunami wave height at the river entrance of 0.05 (5 %). The estimated intrusion length from the proposed method in this study shows a good comparison with measurement data.     

Jurassic synorogenic basin filling in western Korea: sedimentary response to inception of the western Circum-Pacific orogeny

This is the first sedimentologic and stratigraphic attempt to demonstrate Jurassic subduction-induced basin-filling processes in the early stage of the western Circum-Pacific orogeny. The Chungnam Basin in western Korea was filled with a Lower to Middle Jurassic nonmarine succession, the Nampo Group, whose deposition postdated the Triassic final assembly of Chinese continental blocks. The Nampo Group consists of two repeated, fining- to coarsening-upward alluvio-lacustrine sequences, separated by an interval of thick breccia–gravel progradation deposits and its related strong proximal unconformities. No temporal variation in the degree of chemical weathering, along with the predominance of coals and a tropic to subtropic paleoflora, reveals little or no climate fluctuations during deposition of the Nampo Group. The observed relationships provide a record of sedimentation most likely controlled by temporal variations of tectonically driven sediment flux. Such syntectonic sedimentation of the Chungnam Basin occurred at a convergent margin of continental-arc setting during the Daebo orogeny, synchronous with the early subduction of the western paleo-Pacific ocean that resulted in formation of an accretionary complex along the East Asian continental margin during Jurassic time. Hence, synorogenic deposition in the Chungnam Basin is interpreted as sedimentary response to subduction–accretion of the western paleo-Pacific plate.     

Alteration of gene expression profiles in the brain of Japanese medaka (Oryzias latipes) exposed to KC-400 or PCB126

Polychlorinated biphenyls (PCBs) are known as neurotoxic chemicals and possibly alter animal behavior. We previously reported that PCB-exposure induced abnormal schooling behavior in Japanese medaka (Oryzias latipes). This abnormal behavior might be caused by the functional alteration of central or terminal nervous system. To understand the mechanism(s) of behavioral change by PCB-exposure, we analyzed the gene expression profiles in the brain of medaka exposed to 3,3′,4,4′,5-pentachlorobiphenyl (PCB126) or a PCB mixture (Kanechlor-400: KC-400) using a cDNA microarray that we constructed. Twelve FLF-II strain medaka (six individuals per treatment) were dietary exposed to PCB126 (0.01 μg/g b.w./day) or KC-400 (1 μg/g b.w./day) for three weeks. For the control, six fish were fed a control diet. After the exposure period, fish were dissected, and the brain samples were collected. The samples from control fish were pooled and used as a common reference in the microarray experiment. Microarray data were normalized by the LOWESS method, and we screened the genes whose expression levels were altered more than 1.5-fold. Gene expression profiling showed 97 down-regulated and 379 up-regulated genes in the brain of medaka exposed to PCB126. KC-400 exposure suppressed 15 genes and induced 266 genes in medaka brain. Among these genes, the expression levels of 7 and 188 genes were commonly down- or up-regulated, respectively in both treatment groups. On the other hand, 31 gene expressions were significantly different between PCB126 and KC-400 treatment groups, and three out of 31 genes were received opposite effects. In addition, the microarray data showed that thyroid hormone-responsive genes were up-regulated by PCB-exposure, which may imply that PCBs or their metabolites mimic thyroid hormone effects in the brain of PCB-exposed medaka.