Mixing of magmatic CO2 into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.     

Inshore/offshore gradients of imposex and organotin contamination in Nassarius reticulatus (L.) along the Portuguese coast

Imposex and organotin (OT) tissue contamination of the netted whelk Nassarius reticulatus (L.) were assessed in the continental shelves around the main estuaries of the central coast of Portugal (Lisbon: Tagus estuary; Setúbal: Sado estuary) and the main coastal lagoon in the Southern of Portugal (Faro: Ria Formosa). Pollution levels were higher in areas of more intense boat traffic and shipyard activities and imposex showed a clear decreasing gradient from the estuaries to the offshore, in relation to a similar gradient of tissue contamination by tributyltin. Remarkably, imposex was extensively spread over the adjacent continental shelves of Tagus and Sado estuaries. The current work shows that TBT pollution is undoubtedly a matter of concern not only for the above estuaries where harbours are implanted but also for the adjacent continental shelves, regardless the massive dilution of contaminants that may occur in these deeper areas.     

Stable carbon isotope distribution of particulate organic matter in the ocean: a model study

The stable carbon isotopic composition of particulate organic matter in the ocean, δ¹³C_POC, shows characteristic spatial variations with high values in low latitudes and low values in high latitudes. The lowest δ¹³C_POC values (−32‰ to −35‰) have been reported in the Southern Ocean, whereas in arctic and subarctic regions δ¹³C_POC values do not drop below −27‰. This interhemispheric asymmetry is still unexplained. Global gradients in δ¹³C_POC are much greater than in δ¹³C_DIC, suggesting that variations in isotopic fractionation during organic matter production are primarily responsible for the observed range in δ¹³C_POC. Understanding the factors that control isotope variability is a prerequisite when applying δ¹³C_POC to the study of marine carbon biogeochemistry. The present model study attempts to reproduce the δ¹³C_POC distribution pattern in the ocean. The three-dimensional (3D) Hamburg Model of the Oceanic Carbon Cycle version 3.1 (HAMOCC3.1) was combined with two different parametrizations of the biological fractionation of stable carbon isotopes. In the first parametrization, it is assumed that the isotopic fractionation between CO₂ in seawater and the organic material produced by algae, _P, is a function of the ambient CO₂ concentration. The two parameters of this function are derived from observations and are not based on an assumption of any specific mechanism. Thus, this parametrization is purely empirical. The second parametrization is based on fractionation models for microalgae. It is supported by several laboratory experiments. Here the fractionation, _P, depends on the CO₂ concentration in seawater and on the (instantaneous) growth rates, μ_i, of the phytoplankton. In the Atlantic Ocean, where most field data are available, both parametrizations reproduce the latitudinal variability of the mean δ¹³C_POC distribution. The interhemispheric asymmetry of δ¹³C_POC can mostly be attributed to the interhemispheric asymmetry of CO₂ concentration in the water. However, the strong seasonal variations of δ¹³C_POC as reported by several authors, can only be explained by a growth rate-dependent fractionation, which reflects variations in the cellular carbon demand.     

Improved Estimates of Wide-Ranging Sea Surface Temperature from GMS S-VISSR Data

We have developed an algorithm to estimate the wide-ranging Sea Surface Temperature (SST) data from the GMS-5 (Geostationary Meteorological Satellite) S-VISSR (Stretched-Visible Infrared Spin Scan Radiometer). Better SST estimates are realized by averaging the temporal variation of the VISSR calibration table and decreasing noise of the split-window terms using a spatial filter. The effects of the satellite zenith angle were examined in detail for better estimates, and VISSR-derived SSTs with root-mean-square (rms) error of 0.8 K were achieved using a new algorithm. The accuracy of SST estimates has been improved by using the temporal-spatial average of the split-window terms. Using the new techniques, we demonstrate that the hourly wide-ranging SST image data can be used to study the daily variations of SSTs in the Northern and Southern Pacific Oceans.     

与季节内振荡-超级云团系统相关的赤道波的识别

文中重点研究与热带季节内振荡－超级云团系统相关联的赤道波的识别。考虑到赤道波的本质为截获在赤道地区的一般的气候平衡场附近的线性动力过程的固有模态,首先从原理上阐明了ＰＯＰｓ分析技术对于分离各类赤道波动的有效性,以后利用这种分析方法对日本静止气象卫星所观测到的黑体红外辐射温度资料进行了ＰＯＰｓ分析。结果表明,在热带季节内振荡－超级云团系统中,对应于４０ｄ振荡的模态基本表现为Ｋｅｌｖｉｎ波的结构;对应于１０ｄ左右的模态,亦为Ｋｅｌｖｉｎ波,而在２ｄ尺度上,则分别存在经向模态序号ｎ＝１和ｎ＝２的西进和东进惯性重力波。分析中还发现了西进的混合Ｒｏｓｓｂｙ重力波的存在。     

Impact of intra-daily SST variability on ENSO characteristics in a coupled model

This paper explores the impact of intra-daily Sea Surface Temperature (SST) variability on the tropical large-scale climate variability and differentiates it from the response of the system to the forcing of the solar diurnal cycle. Our methodology is based on a set of numerical experiments based on a fully global coupled ocean–atmosphere general circulation in which we alter (1) the frequency at which the atmosphere sees the SST variations and (2) the amplitude of the SST diurnal cycle. Our results highlight the complexity of the scale interactions existing between the intra-daily and inter-annual variability of the tropical climate system. Neglecting the SST intra-daily variability results, in our CGCM, to a systematic decrease of 15% of El Ni?o—Southern Oscillation (ENSO) amplitude. Furthermore, ENSO frequency and skewness are also significantly modified and are in better agreement with observations when SST intra-daily variability is directly taken into account in the coupling interface of our CGCM. These significant modifications of the SST interannual variability are not associated with any remarkable changes in the mean state or the seasonal variability. They can therefore not be explained by a rectification of the mean state as usually advocated in recent studies focusing on the diurnal cycle and its impact. Furthermore, we demonstrate that SST high frequency coupling is systematically associated with a strengthening of the air-sea feedbacks involved in ENSO physics: SST/sea level pressure (or Bjerknes) feedback, zonal wind/heat content (or Wyrtki) feedback, but also negative surface heat flux feedbacks. In our model, nearly all these results (excepted for SST skewness) are independent of the amplitude of the SST diurnal cycle suggesting that the systematic deterioration of the air-sea coupling by a daily exchange of SST information is cascading toward the major mode of tropical variability, i.e. ENSO.     

南海大气季节内振荡特征及其与ENSO循环的关系

采用1979—2009年NCEP/NCAR再分析资料、NOAA向外长波辐射(outgoing long-wave radiation,简称OLR)及扩展重建海表面温度资料,对南海大气季节内振荡(Intra-seasonal Oscillation,简称ISO)特征及其与ENSO循环的关系进行了诊断分析。结果表明:1)南海大气ISO的30~60 d周期在5—10月均显著。一般年南海大气ISO的对流传播在纬向上存在东传和西传,在经向上具有南北半球季节性摆动的特征。以低频动能表征的南海大气ISO强度年代际变化特征明显,近31 a来趋势增强,年变化呈单峰结构,峰值在7—8月。2)南海大气ISO的对流与ENSO循环显著相关,其强度在El Nio(La Nia)年减弱(增强)。与一般年对比,南海大气ISO对流在El Nio和La Nia年均表现为西传减弱、北传显著。北传特征表现为强对流活跃带于春季(4—5月)北跳至北半球(在La Nia年最北可至35°N),但在北半球的传播方向与一般年相比存在显著差异。3)南海大气ISO强度与ENSO循环关系密切,在El Nio(La Nia)年减弱(增强),两者表现为约半年(6~8个月)的滞后相关。Nio3区海表面温度异常序列与南海大气ISO强度的相关在中西太平洋地区和El Nio成熟前的春、秋季最显著,同时相关中心伴随低频动能高值区东移。     

NATURE OF PRECIPITATION AND ACTIVITY OF CUMULUS CONVECTION DURING THE 1991 MEIYU SEASON OF CHANGJIANG-HUAIHE RIVER BASIN*

Seasonal variability regarding the nature of precipitation and the activity of cumulus convection during the 1991 Meiyu season of Changjiang-Huaihe River Basin(Jianghuai)has been investigated by calculating apparent heat source/apparent moisture sink and analyzing TBB(cloud-top blackody radiation temperature)data.It is found that three periods of strong ascending motion during the Meiyu season lead to three episodes of heavy rain,and the latent heat due to the precipitation is of the sole heat source of the atmosphere.The nature of precipitation shows distinct seasonal variability,from frontal precipitation of the first episode to the extremely strong convective precipitation of the third episode.TBB field of East Asia may well reflect not only the intensity of convection and rainfall,but also the movement of rain belt and convection belt.In the whole Meiyu season.convection belt mainly stays in Jianghuai.but may shift within the domain of East Asia.Its locating in Jianghuai or not determines the maintenance or break of Meiyu.In the third episode,the narrow convection belt over Jianghuai is mainly caused by southwest monsoon which takes moist and convective atmosphere from tropical ocean.