Ancient geochemical cycling in the Earth as inferred from Fe isotope studies of banded iron formations from the Transvaal Craton

Variations in the isotopic composition of Fe in Late Archean to Early Proterozoic Banded Iron Formations (BIFs) from the Transvaal Supergroup, South Africa, span nearly the entire range yet measured on Earth, from –2.5 to +1.0‰ in ⁵⁶Fe/⁵⁴Fe ratios relative to the bulk Earth. With a current state-of-the-art precision of ±0.05‰ for the ⁵⁶Fe/⁵⁴Fe ratio, this range is 70 times analytical error, demonstrating that significant Fe isotope variations can be preserved in ancient rocks. Significant variation in Fe isotope compositions of rocks and minerals appears to be restricted to chemically precipitated sediments, and the range measured for BIFs stands in marked contrast to the isotopic homogeneity of igneous rocks, which have δ⁵⁶Fe=0.00±0.05‰, as well as the majority of modern loess, aerosols, riverine loads, marine sediments, and Proterozoic shales. The Fe isotope compositions of hematite, magnetite, Fe carbonate, and pyrite measured in BIFs appears to reflect a combination of (1) mineral-specific equilibrium isotope fractionation, (2) variations in the isotope compositions of the fluids from which they were precipitated, and (3) the effects of metabolic processing of Fe by bacteria. For minerals that may have been in isotopic equilibrium during initial precipitation or early diagenesis, the relative order of δ⁵⁶Fe values appears to decrease in the order magnetite > siderite > ankerite, similar to that estimated from spectroscopic data, although the measured isotopic differences are much smaller than those predicted at low temperature. In combination with on-going experimental determinations of equilibrium Fe isotope fractionation factors, the data for BIF minerals place additional constraints on the equilibrium Fe isotope fractionation factors for the system Fe(III)–Fe(II)–hematite–magnetite–Fe carbonate. δ⁵⁶Fe values for pyrite are the lowest yet measured for natural minerals, and stand in marked contrast to the high δ⁵⁶Fe values that are predicted from spectroscopic data. Some samples contain hematite and magnetite and have positive δ⁵⁶Fe values; these seem best explained through production of high ⁵⁶Fe/⁵⁴Fe reservoirs by photosynthetic Fe oxidation. It is not yet clear if the low δ⁵⁶Fe values measured for some oxides, as well as Fe carbonates, reflect biologic processes, or inorganic precipitation from low-δ⁵⁶Fe ferrous-Fe-rich fluids. However, the present results demonstrate the great potential for Fe isotopes in tracing the geochemical cycling of Fe, and highlight the need for an extensive experimental program for determining equilibrium Fe isotope fractionation factors for minerals and fluids that are pertinent to sedimentary environments.     

The origin of glasses in hydrous mantle xenoliths from the West Eifel,Germany: incongruent break down of amphibole

Patches of glass with a second generation of small crystals of olivine, clinopyroxene, and spinel are abundant in hydrous peridotite mantle xenoliths with tabular equigranular textures from two maar-type volcanoes, Meerfelder Maar and Dreiser Weiher (West Eifel, Germany). The patches are similar in size to the main phases of the hosting peridotite. Their central part is often occupied by relics of pargasitic amphibole. Mass-balance calculations show that the patches were formed by surface controlled incongruent thermal breakdown of amphibole according to the reaction: amphibole olivine + clinopyroxene + spinel + melt. Simultaneously with the decomposition of amphibole, small crystals of olivine, clinopyroxene, and spinel grew radially from the patch/peridotite interface toward the centre of the patch. Apart from sector zoning of clinopyroxene, the crystals are virtually homogeneous and are separated from the amphibole by a seam of melt (glass). Secondary olivines reveal higher Mg-numbers, secondary clinopyroxenes higher Cr₂O₃ concentrations than olivines and clinopyroxenes, respectively, of the host peridotite. The silica contents of melts produced by the above breakdown reaction range from 48 to 52% SiO₂ as a function of the composition of the parent amphiboles. Patches surrounded by primary olivines only reveal no reaction with the host peridotite. The variation of SiO₂, MgO and CaO in melts from these patches is the result of minor precipitation of olivine and clinopyroxene during fast cooling. If patches are in contact with primary olivine and orthopyroxene, melts are additionally modified by the reaction liquid 1 + orthopyroxene liquid 2 + olivine + clinopyroxene resulting in more silica-rich compositions between 54 and 58%. For the rare glasses richer in silica, a more complex formation is required. Veinlets along grain boundaries are filled with glasses which are chemically identical to those from nearby patches. This suggests that the veinlets were filled by melts formed by amphibole breakdown during entrainment of the xenoliths to the host magmas.     

Sintering,crystallization, and breccia formation

The process of breccia formation by viscous sintering in the absence of pressure, advanced forcefully by Simonds (1973), is examined in detail. The limitations on the standard model for such sintering are considered. The competing process of crystallization is analyzed kinetically in terms of time-temperature-transformation curves corresponding to various degrees of crystallinity. The analysis is applied to Lunar Composition 15418 to illustrate the approach. The results indicate that close constraints can be placed on the thermal histories of lunar breccias, particularly breccias with modest degrees of crystallinity, from microstructural observations and kinetic measurements.     

Observations of the microwave emission of Venus from 1.3 to 3.6 cm

Laboratory measurements of Steffes (1986) have suggested that the intensity and shape of the microwave spectrum of Venus might be especially sensitive to the subcloud abundance of constituents such as SO2 and gaseous H2SO4. It was likewise suggested that some variations of the shape of the emission spectrum might occur between 1.5 and 3 cm (10 to 20 GHz), a wavelength range which had previously only been sparsely observed. As a result, coordinated observations of Venus emission were conducted at four wavelengths between 1.35 cm (22.2 GHz) and 3.6 cm (8.42 GHz) using the 43-m NRAO antenna at Green Bank, West Virginia, and the 64-m antenna at NASA's Deep Space Communication Complex, Goldstone, California. In this paper, we report the methodology and results of these observations, and compare the results with other observations and with calculated emission spectra. We conclude that the observed emission spectrum is consistent with an average subcloud abundance of gaseous H2SO4 in equatorial and midlatitude regions which is approximately 5 ppm. It is suggested that additional measurements of atmospheric microwave opacity be made with the Pioneer-Venus Orbiter Radio Occultation experiment to search for temporal and spatial variations in gaseous H2SO4 abundance in the Venus atmosphere. An upper limit for the subcloud abundance of SO2 is also determined.     

On the variability of 18 Degree Water formation as observed from moored instruments at 55°W

The analysis of hydrographic time series from moored sensors from the eastern end of the Sargasso Sea has shown that in the late 1980s the Subtropical Mode Water was dominated by high temperatures. The 18 Degree Water observed during this period was warmer and saltier than the definition given by Worthington, with an increase in values over the observation period. Although severe winter conditions in 1988 led to the formation of colder types of 18 Degree Water at the eastern part of the Sargasso Sea, they were not incorporated in the subtropical gyre. Simultaneous current meter measurements indicated eastward flow within the “southern recirculation gyre” during spring that might have been responsible for the fact that these cold Mode Water types have not been entrained into the gyre. The meteorological forcing fields show considerable interannual variability that is, in part, mimicked by changes in the 18 Degree Water properties. Due to the strong influence of the advection field on the 18 Degree Water properties, the relationship between the surface forcing and 18 Degree Water properties remains qualitative. The continuing influence of further mild winters after 1989, however, is manifested in rising temperatures within the Mode Water range.     

Acquisition and Inversion of Dispersive Seismic Waves in Shallow Marine Environments

Two types of dispersive seismic waves have been acquired in different geological settings to investigate the potential to reveal the elastic parameters of the shallow marine subsurface. Scholte waves as well as acoustic guided waves are excited by a near-surface towed airgun, and recorded using two acquisition methods: (1) the towed-acquisition system using a hydrophone streamer towed close to the sea floor, and (2) the stationary-receiver method using Ocean-Bottom Seismometers and/or Hydrophones (OBS/OBH). Our diverse data sets reveal that the spatial sampling of the wavefield required to avoid aliasing may vary significantly for different geological settings. Scholte waves are characterised by a few distinct modes observed at low frequencies and low phase velocities. Their dispersion is mainly controlled by the depth profile of the shear-wave velocity. Acoustic guided waves show profound amplitude variations of numerous higher modes over a broad frequency range. These are sensitive to shear-wave velocity, but more sensitive to compressional-wave velocity than Scholte waves are. To avoid the identification of distinct modes we infer 1-D models of elastic parameters of the subsurface from the inversion of the full wavefield spectra of acoustic guided waves. In the Siberian Laptev Sea we infer the presence of a soft sediment layer (8–10 m) with a well resolved strong S-velocity gradient (150–450 m/s). In the Baltic Sea a low P-velocity layer with a strong vertical gradient (1250–1440 m/s) corresponding to a post-glacial gassy mud layer could be resolved, which agrees well with the sediment stratigraphy derived from a gravity core.     

Electron trapping in evolving coronal structures during a large gradual hard X-ray/radio burst

Gradual hard X-ray/radio bursts are characterized by their long duration, smooth time profile, time delays between peaks at different hard X-ray energies and microwaves, and radiation from extended sources in the low and middle corona. Their characteristic properties have been ascribed to the dynamic evolution of the accelerated electrons in coronal magnetic traps or to the separate acceleration of high-energy electrons in a second step process. The information available so far was drawn from qualitative considerations of time profiles or even only from the common occurrence of emissions in different spectral ranges. This paper presents model computations of the temporal evolution of hard X-ray and microwave spectra, together with a qualitative discussion of radio lightcurves over a wide spectral range, and metric imaging observations. The basic hypothesis investigated is that the peculiar gradual features can be related to the dynamical evolution of electrons injected over an extended time interval in a coronal trap, with electrons up to relativistic energies being injected simultaneously. The analyzed event (26 April, 1981) is particularly challenging to this hypothesis because of the long time delays between peaks at different X-ray energies and microwave frequencies. The observations are shown to be consistent with the hypothesis, provided that the electrons lose their energy by Coulomb collisions and possibly betatron deceleration. The access of the electrons to different coronal structures varies in the course of the event. The evolution and likely destabilisation of part of the coronal plasma-magnetic field configuration is of crucial influence in determining the access to these structures and possibly the dynamical evolution of the trapped electrons through betatron deceleration in the late phase of the event.     

HI observations ofHII-galaxies

High-resolution observations of the star forming dwarf galaxies Haro 21 and Markarian 314 are presented and are compared with a set of narrow band (H) CCD images. TheHi system related to Haro 21 measures about 12 kpc in diameter and is much more extended than the optical emission. The optical light follows that of an exponential disk and has a scale length of only 600 pc. TheHi distribution shows a lack of neutral gas near its centre where most of the H emission is found. The velocity field is regular and shows the characteristics of a disk in differential rotation. The rotation curve is rising out to the last measured point and the total mass is estimated to be about 1.5×10¹⁰ M . This implies that Haro 21 is a galaxy which is dominated by Dark Matter.Partly based on observations collected at the European Southern Observatory, La Silla, Chile.