Factors Controlling the Regional Distribution of Vanadium in Groundwater

Although the ingestion of vanadium (V) in drinking water may have possible adverse health effects, there have been relatively few studies of V in groundwater. Given the importance of groundwater as a source of drinking water in many areas of the world, this study examines the potential sources and geochemical processes that control the distribution of V in groundwater on a regional scale. Potential sources of V to groundwater include dissolution of V rich rocks, and waste streams from industrial processes. Geochemical processes such as adsorption/desorption, precipitation/dissolution, and chemical transformations control V concentrations in groundwater. Based on thermodynamic data and laboratory studies, V concentrations are expected to be highest in samples collected from oxic and alkaline groundwater. However, the extent to which thermodynamic data and laboratory results apply to the actual distribution of V in groundwater is not well understood. More than 8400 groundwater samples collected in California were used in this study. Of these samples, high (≥50 µg/L) and moderate (25 to 49 µg/L) V concentrations were most frequently detected in regions where both source rock and favorable geochemical conditions occurred. The distribution of V concentrations in groundwater samples suggests that significant sources of V are mafic and andesitic rock. Anthropogenic activities do not appear to be a significant contributor of V to groundwater in this study. High V concentrations in groundwater samples analyzed in this study were almost always associated with oxic and alkaline groundwater conditions, which is consistent with predictions based on thermodynamic data.     

Iron in the southeastern Bering Sea: Elevated leachable particulate Fe in shelf bottom waters as an important source for surface waters

Surface transects and vertical profiles of total and leachable particulate Fe, Mn, Al and P, along with dissolved and soluble Fe were obtained during August 2003 in the southeastern Bering Sea. High concentrations of leachable particulate Fe were observed in the bottom waters over the Bering Sea shelf with an unusually high percentage of the suspended particulate Fe being leachable. Leachable particulate Fe averaged 81% of total particulate Fe, and existed at elevated concentrations that averaged 23 times greater than dissolved Fe in the isolated cool pool waters over the mid shelf where substantial influence of sedimentary denitrification was apparent. The elevated leachable particulate Fe is suggested to be a result of sedimentary Fe reduction in surficial sediments, diffusion of Fe(II) from the sediments to the bottom waters, and subsequent oxidation and precipitation of reduced Fe in the overlying bottom waters. Eddies and meanders of the Bering Slope Current can mix this Fe-rich water into the Green Belt at the outer shelf-break front. Elevated levels of leachable particulate Fe were observed in surface waters near the Pribilof Islands where enhanced vertical mixing exists. Storm events and/or cooling during fall/winter with the resultant destruction of the thermally stratified two-layer system can also mix the subsurface water into surface waters where the elevated leachable particulate Fe is a substantial source of biologically available Fe.     

Cartoblography: Experiments in Using and Organising the Spatial Context of Micro‐blogging

Blogs, micro‐blogs and online forums underpin a more interconnected world. People communicate ever more and are increasingly keen to explain and illustrate their lives; showing where they are and what they are doing. Desktop, online and mobile mapping landscapes have never been as rich or diverse yet this challenges cartography to adapt and remain relevant in the modern mapping world. We explore the spatial expression and potential value of micro‐blogging and Twitter as a social networking tool. Examples of “twitter maps” are reviewed that leverage the Twitter API and online map services to locate some component of the “tweet”. Scope, function and design are illustrated through development of two proof‐of‐concept map mashups that support collaborative real‐time mapping and the organisation and display of information for mass user events. Through the experiments in using and organising data in this way we demonstrate the value of “cartoblography”– a framework for mapping the spatial context of micro‐blogging.     

The context of policy design for existing community-based fisheries management systems in the Pacific Islands

Community-based fisheries management is being widely promoted as an alternative to centralized systems based on the familiar bioeconomic models that have manifestly failed to prevent a near catastrophic overexploitation of fish stocks worldwide. The Pacific Island Region probably contains the world’s greatest concentration of still-functioning traditional community-based systems for managing coastal-marine fisheries and other resources.It has been frequently asserted that many such traditional systems provide both a firm foundation for future coastal fisheries management in the Pacific Islands Region, as well as a conceptual framework for managing fisheries elsewhere. Although now seemingly self-evident to fisheries development “experts”, such assertions remain largely unverified.Whereas it is a relatively straightforward task to distil basic “design principles” from a sample of systems, it is far more complex to analyze the multi-sectoral national environment in which they function, especially when their history is taken into account. In other words, it is far less widely appreciated that many contemporary community-based fisheries management systems are the end products of a long process of change and adaptation to external pressures and constraints.In this article I address some of the broader contextual issues that should be appreciated in policymaking with respect to a potential modern role for traditional management systems in general, and in the analysis of a future role for any given system. First, the principal external factors that have caused change in systems are described and exemplified. The recognition of the potential role of existing community-based fisheries systems, and attempts to act on it, is summarized for some Pacific Island nations, with a focus on the complex problem of reconciling customary and statutory legal systems. In the final section I examine three principal national policy alternatives regarding the potential role of existing local fisheries management systems, together with three main criteria for determining whether or not a system can be adapted to fulfill modern requirements.     

Early Miocene sequence development across the New Jersey margin

Sequence stratigraphy provides an understanding of the interplay between eustasy, sediment supply and accommodation in the sedimentary construction of passive margins. We used this approach to follow the early to middle Miocene growth of the New Jersey margin and analyse the connection between relative changes of sea level and variable sediment supply. Eleven candidate sequence boundaries were traced in high-resolution multi-channel seismic profiles across the inner margin and matched to geophysical log signatures and lithologic changes in ODP Leg 150X onshore coreholes. Chronologies at these drill sites were then used to assign ages to the intervening seismic sequences. We conclude that the regional and global correlation of early Miocene sequences suggests a dominant role of global sea-level change but margin progradation was controlled by localized sediment contribution and that local conditions played a large role in sequence formation and preservation. Lowstand deposits were regionally restricted and their locations point to both single and multiple sediment sources. The distribution of highstand deposits, by contrast, documents redistribution by along shelf currents. We find no evidence that sea level fell below the elevation of the clinoform rollover, and the existence of extensive lowstand deposits seaward of this inflection point indicates efficient cross-shelf sediment transport mechanisms despite the apparent lack of well-developed fluvial drainage.     

Flume tank studies to elucidate the fate and behavior of diluted bitumen spilled at sea

An economical alternative to conventional crudes, Canadian bitumen, harvested as a semi-liquid, is diluted with condensate to make it viable to transport by pipeline to coastal areas where it would be shipped by tankers to global markets. Not much is known about the fate of diluted bitumen (dilbit) when spilled at sea. For this purpose, we conducted dilbit (Access Western Blend; AWB and Cold Lake Blend; CLB) weathering studies for 13 days in a flume tank containing seawater. After six days of weathering, droplets detached from the AWB slick and were dense enough to sink in seawater. The density of CLB also increased, but at a slower rate compared to AWB, which was attributed to the high concentration of alkylated polycyclic aromatic hydrocarbons in it, which are more resistant to weathering. An empirical, Monod-type model was introduced and was found to closely simulate the increase in oil density with time. Such a model could be used within oil spill models.     

A study of anthropogenic and climatic disturbance of the New River Estuary using a Bayesian belief network

The present paper utilizes a Bayesian Belief Network (BBN) approach to intuitively present and quantify our current understanding of the complex physical, chemical, and biological processes that lead to eutrophication in an estuarine ecosystem (New River Estuary, North Carolina, USA). The model is further used to explore the effects of plausible future climatic and nutrient pollution management scenarios on water quality indicators. The BBN, through visualizing the structure of the network, facilitates knowledge communication with managers/stakeholders who might not be experts in the underlying scientific disciplines. Moreover, the developed structure of the BBN is transferable to other comparable estuaries. The BBN nodes are discretized exploring a new approach called moment matching method. The conditional probability tables of the variables are driven by a large dataset (four years). Our results show interaction among various predictors and their impact on water quality indicators. The synergistic effects caution future management actions.     

Evaluation of past,present and future tools for radar-based flash-flood prediction in the USA

Abstract

The societal impacts of flash floods are more significant than any other weather-related hazard. They are often manifested in the form of damage to infrastructure, flooding of roadways and bridges, creating deadly hazards to motorists and inundation of crops and pasture. Some of these hazards can be anticipated and thus mitigated given effective warning systems. This study describes the tools proposed over recent decades in the USA to predict flash flooding and evaluates them using a common observational data set. Design recommendations for flash-flood forecasting systems are provided, taking into account today's availability of high-resolution rainfall data at scales commensurate with flash flooding, their archives, spatial data sets to describe physiographic properties, and ever-increasing computational resources.

Editor D. Koutsoyiannis; Guest editor R.J. Moore

Citation Gourley, J.J., Flamig, Z.L., Hong, Y., and Howard, K.W., 2014. Evaluation of past, present and future tools for radar-based flash-flood prediction in the USA. Hydrological Sciences Journal, 59 (7), 1377–1389. http://dx.doi.org/10.1080/02626667.2014.919391