X-ray absorption spectroscopy identifies calcium-uranyl-carbonate complexes at environmental concentrations

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO₂-CO₃ complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO₂-CO₃ complex. Such a complex might exist even at high calcium concentrations, as some UO₂-CO₃ complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 μM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO₂-CO₃ complex to approximately 0.6 and enables spectroscopic identification of the Na-UO₂-CO₃ complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.     

Renewable energy strategies in England, Australia and New Zealand

The development of renewable energy sources is of prime interest to many countries seeking to pursue greenhouse gas emission reduction obligations. The increased use of renewables offers the possibility of not only contributing to emission reduction, but at the same time improving energy supply diversity and security, and developing employment and business in related supply industries. Two main mechanisms are in common use, one a quota (quantity) instrument often associated with tradable certificates, and the other a prescribed pricing mechanism. This paper considers the renewable energy development strategies of three countries (the UK, Australia, and New Zealand) all using a variant of the quota/certificate approach as the central instrument in their programs. The regulatory frameworks defining the application of the certificate systems differ notably, and the likely differing outcomes suggest that these regulatory settings may be at least as important as the selection of the basic policy instrument, in determining the overall success of programs of this nature.     

Improved seasonal climate forecasts for the Caribbean region using the Florida State University Synthetic Superensemble

Summary Climate variations in the Caribbean, largely manifest in rainfall activity, have important consequences for the large-scale water budget, natural vegetation, and land use in the region. The wet and dry seasons will be defined, and the important roles played by the El Ni?o-Southern Oscillation (ENSO) and the North Atlantic Oscillation (NAO) in modulating the rainfall during these seasons will be discussed. The seasonal climate forecasts in this paper are made by 13 state of the art coupled atmosphere-ocean general circulation models (CGCMs) and by the Florida State University Synthetic Superensemble (FSUSSE), whose forecasts are obtained by a weighted combination of the individual CGCM forecasts based on a training period. The success of the models in simulating the observed 1989–2001 climatology of the various forecast parameters will be examined and linked to the models’ success in predicting the seasonal climate for individual years. Seasonal forecasts will be examined for precipitation, sea-surface temperature (SST), 2-meter air temperature, and 850 hPa u- and v-wind components during the period 1989–2001. Evaluation metrics include root mean square (RMS) error and Brier skill score. It will be shown that the FSUSSE is superior to the individual CGCMs and their ensemble mean both in simulating the 1989–2001 climatology for the various parameters and in predicting the seasonal climate of the various parameters for individual years. The seasonal climate forecasts of the FSUSSE and of the ensemble mean of the 13 state of the art CGCMs will be evaluated for years (during the period 1989–2001) that have particular ENSO and NAO signals that are known to influence Caribbean weather, particularly the rainfall. It will be shown that the FSUSSE provides superior forecasts of rainfall, SST, 2-meter air temperature, and 850 hPa u- and v-wind components during dry summers that are modulated by negative SOI and/or positive NAO indices. Such summers have become a feature of a twenty-year pattern of drought in the Caribbean region. The results presented in this paper will show that the FSUSSE is a valuable tool for forecasting rainfall and other atmospheric and oceanic variables during such periods of drought.     

Economic consequences of consideration of permanence, leakage and additionality for soil carbon sequestration projects

This paper introduces, explains, and describes methods for addressing the issues of permanence, leakage, and additionality (PLA) of agricultural soil carbon sequestration (ASCS) activities at the project level. It is important to cast these as project-level issues, because they relate to the integrity and consistency of using location-specific ASCS projects as an offset against GHG emissions generated in other sectors (e.g., energy). The underlying objective is to understand and quantify what the net carbon benefits of an ASCS project are once we account for the fact that (1) the sequestered carbon may be stored impermanently, (2) the project may displace emissions outside the project boundaries (leakage), and (3) the project’s carbon sequestration may not be entirely additional to what would have occurred anyway under business-as-usual (no project) conditions. This article evaluates methods for identifying and estimating PLA and gauges the potential magnitude of these effects on the economic returns to a project. This work reflects ongoing collaborative efforts of the authors and Bruce McCarl (Texas A&M University), Allan Sommer, Jui-Chen Yang, and Laurel Clayton (RTI International), Sandra Brown (Winrock International), Ken Andrasko and Ben DeAngelo (US EPA), and various participants in the World Resources Institute/World Business Council workgroup to develop GHG project reporting protocols. All opinions, errors and omissions are those of the authors only.     

High pressure study of ScAlO3 perovskite

The crystal structure of orthorhombic (Pbnm) ScAlO₃ perovskite has been refined to 5 GPa using single-crystal X-ray diffraction. The compression of the structure if anisotropic with β _a =1.39(3)×10⁻³ GPa⁻¹, β _b =1.14(3)×10⁻³ GPa⁻¹ and β _c =1.84(3)×10⁻³ GPa⁻¹. The isothermal bulk modulus of ScAlO₃, K _T , determined from fitting a Birch-Murnaghan equation of state (K ^′ _T =4) to the volume compression data is 218(1) GPa. The interoctahedral angles to not vary significantly with pressure, and the compression of the structure is entirely attributable to compression of the AlO₆ octahedra. The compressibilities of the constituent AlO₆ and ScO₁₂ are well matched: β_Al−O=1.6×10⁻³ GPa⁻¹ and β_Sc−O=1.5×10⁻³ GPa⁻¹. Therefore the distortion of the structure shows no significant change with increasing pressure. Received: 18 August 1997 / Revised, accepted: 11 November 1997     

The use of infauna by juvenile Penaeus aztecus Ives and Penaeus setiferus (Linnaeus)

Penaeus aztecus Ives, the brown shrimp, and Penaeus setiferus (Linnaeus), the white shrimp, co-occur in Texas salt marshes as juveniles. Although their life cycles are similar, evidence indicates that the species utilize different resources for the primary faunal element of their diets. Prey selection and growth studies have shown that brown shrimp successfully remove infauna from natural sediment. Further, a diet of polychaetes, whether alone or in combination with algae, produced growth in the species. Brown shrimp appear to be trophically linked to infaunal populations, thus the structure and dynamics of the benthic community may directly affect local brown shrimp productivity. Areas dominated by surface-dwelling polychaetes as opposed to deep burrowers may provide more accessible foraging opportunities for juvenile brown shrimp. By contrast, white shrimp neither removed infauna nor grew to a significant degree when provided polychaetes or amphipods as food. White shrimp are omnivorous but do not rely on infaunal material to the same extent as brown shrimp. The primary faunal element in the diet of white shrimp has not yet been identified. The dietary differences between the two species may play a role in determining which species dominates in regions with varying marsh accessibility. Although not the only factors influencing penaeid survival and growth, prey choice and availability may greatly affect production and local success of penaeid populations. *** DIRECT SUPPORT *** A01BY081 00013     

Effects of menhaden predation of plankton populations in Narragansett Bay, Rhode Island

The Atlantic menhaden,Brevoortia tyrannus, is an abundant plankton-feeding fish that undertakes extensive seasonal migrations, moving from overwintering locations offshore south of Cape Hatteras to the mid-Atlantic Bight and New England inshore waters during spring and summer. A bioenergetic model, based on field and laboratory studies, shows that when large numbers of menhaden enter Narragansett Bay, Rhode Island, during spring and early summer, they significantly influence plankton populations through size-selective grazing and nutrient regeneration. A population biomass of 9.1×10⁶ kg of menhaden feeding for 12 h each day in the upper bay would result, in a substantial reduction of the instantaneous growth rate of the >20-μm phytoplankton. Instantaneous growth rates of zooplankton would be negative if the same population of menhaden was present, resulting in a reduction in the biomass of zooplankton. Given the ambient phytoplankton and zooplankton populations, menhaden could achieve the seasonal growth measured in Narragansett Bay during 1976 by feeding on average about 5 h d^?1. Daily nitrogen excretion rates of the 9.1×10⁶ kg menhaden population were 56.4% of the mean standing stock of ammonia-N in the upper bay. Because menhaden travel in schools their effects are likely to be intense but strongly localized, increasing spatial heterogeneity in the ecosystem. When the fish migrate southward in the fall they transfer between 3.3% and 6.2% of the nitrogen exported annually from the bay.     

The C/CO ratio in B335 and the decaying dark matter neutrino hypothesis

C¹⁸O J  = 2–1, C¹⁷O J  = 2–1 and [C  I ] ³P₁–³P₀ emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.     

Iron line profiles including emission from within the innermost stable orbit of a black hole accretion disc

We propose a model for the source of the X-ray background (XRB) in which low-luminosity active nuclei ( L  ∼ 10⁴³ erg s⁻¹) are obscured ( N  ∼ 10²³ cm⁻²) by nuclear starbursts within the inner ∼ 100 pc. The obscuring material covers most of the sky as seen from the central source, rather than being distributed in a toroidal structure, and hardens the averaged X-ray spectrum by photoelectric absorption. The gas is turbulent with velocity dispersion ∼ few × 100 km s⁻¹ and cloud–cloud collisions lead to copious star formation. Although supernovae tend to produce outflows, most of the gas is trapped in the gravity field of the star-forming cluster itself and the central black hole. A hot ( T  ∼ 10⁶ − 10⁷ K) virialized phase of this gas, comprising a few per cent of the total obscuring material, feeds the central engine of ∼ 10⁷ M⊙ through Bondi accretion, at a sub-Eddington rate appropriate for the luminosity of these objects. If starburst-obscured objects give rise to the residual XRB, then only 10 per cent of the accretion in active galaxies occurs close to the Eddington limit in unabsorbed objects.