Organic geochemistry of late Cenozoic sediments from the subtropical South Atlantic Ocean

Organic matter has been characterized in samples of Pleistocene, Pliocene, and Miocene sediments from seven Deep Sea Drilling Project sites in the subtropical South Atlantic Ocean. Organic carbon concentrations average 0.3% for most samples, and n-alkanoic acid, n-alkanol, and alkane biomarkers indicate extensive microbial reworking of organic matter in these organic-carbon-lean sediments. Samples from the easternmost parts of the South Atlantic contain an average of 4.1% organic carbon and reflect the high productivity associated with the Benguela Current. Lipid biomarkers show less microbial reworking in these sediments. Eolian transport of land-derived hydrocarbons is evident at most of these oceanic locations.     

Validation of a decadal OGCM simulation for the tropical Pacific

An ocean general circulation model is forced with NCEP reanalysis over the 1948–1999 period. The simulated dynamic height and sea level are compared respectively to the dynamic height computed from hydrological data and to the sea level measured by tide gauges in the tropical Pacific. The model is shown to capture important features of the temporal structure of variability in the tide gauge data over the last several decades. However, the comparison reveals a largely artificial trend in the simulation, which consists of a decreasing dynamic height and sea level in the southwest and northwest of the tropical Pacific. Model sensitivity experiments show this trend is controlled by the NCEP surface wind stresses and more precisely by a weakening in the trade winds and a trend in the off-equatorial wind curl, with this trend existing mainly before the mid 1970s. For studies of decadal variability, the simple removal of a linear trend is an inadequate way to solve the problem, due to the inhomogeneities in the data used in reanalysis products and the non-linearity of models.     

Evaluation of conditions along the grounding line of temperate marine glaciers: an example from Muir Inlet, Glacier Bay, Alaska

In the marine environment, stability of the glacier terminus and the location of subglacial streams are the dominant controls on the distribution of grounding-line deposits within morainal banks. A morainal bank complex in Muir Inlet, Glacier Bay, SE Alaska, is used to develop a model of terminus stability and location of subglacial streams along the grounding line of temperate marine glaciers. This model can be used to interpret former grounding-line conditions in other glacimarine settings from the facies architecture within morainal bank deposits.The Muir Inlet morainal bank complex was deposited between 1860 A.D. and 1899 A.D., and historical observations provide a record of terminus positions, glacial retreat rates and sedimentary sources. These data are used to reconstruct the depositional environment and to develop a correlation between sedimentary facies and conditions along the grounding line.Four seismic facies identified on the high-resolution seismic-reflection profiles are used to interpret sedimentary facies within the morainal bank complex. Terminus stability is interpreted from the distribution of sedimentary facies within three distinct submarine geomorphic features, a grounding-line fan, stratified ridges, and a field of push ridges. The grounding-line fan was deposited along a stable terminus and is represented on seismic-reflection profiles by two distinct seismic facies, a proximal and a distal fan facies. The proximal fan facies was deposited at the efflux of subglacial streams and indicates the location of former glacifluvial discharges into the sea. Stratified ridges formed as a result of the influence of a quasi-stable terminus on the distribution of sedimentary facies along the grounding line. A field of push ridges formed along the grounding line of an unstable terminus that completely reworked the grounding-line deposits through glacitectonic deformation.Between 1860 A.D. and 1899 A.D. (39 years),

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m³ of sediment were deposited within the Muir Inlet morainal bank complex at an average annual sediment accumulation rate of

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m³/a. This rate represents the annual sediment production capacity of the glacier when the Muir Inlet drainage basin is filled with glacial ice.     

From oblique subduction to intra-continental transpression: Structures of the southern Kermadec-Hikurangi margin from multibeam bathymetry,side-scan sonar and seismic reflection

The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone.     

Transport of stable isotopes,kinetics, dispersive advection,and the ‘isotopic fronts’ of Baumgartner and Rumble (1988)

Baumgartner and Rumble (1988) apply a kinetic continuum theory for stable isotope transport to unidimensional infiltration of fluid into rock. Their numerical applications are restricted to the simplified case of rapid isotope exchange between phases, where the sharp isotope fronts of pure advection are distended by dispersive mechanisms only. However, kinetic limitations of isotope exchange are potentially an equally important distending mechanism, and it will only rarely be possible to ascribe front gradients to diffusion/dispersion alone. Abrupt isotopic changes at vein boundaries are more often a secondary signal of lithologic change than the expression of a retarded advective front. At such boundaries, diffusion and dispersion play a role that is comparable to, or greater than, that of advection, so that the detailed shapes of isotope fronts depend upon boundary conditions for the infiltration process. Zerodimensional box models have legitimate, if limited, uses in the modelling of fluid-rock interaction, and are reexamined.     

Historical seismicity of the southeastern Caribbean and tectonic implications

We have relocated the twenty-eight largest magnitude (4.3M _s 7.3) historical (1922–1963) earthquakes of the southeastern Caribbean. We also present new focal mechanisms for seven of these events. The relocations are based on reported ISSP andS arrival times that we analyzed using generalized linear inversion techniques. The new focal mechanisms were constrained by first motionP polarities as reported by the ISS and as picked by us where records were available, and by the polarities and ratios ofSH andsSH, andSV andsSV arrivals that we determined from seismograms. The results of the relocations are commensurate with the distribution of seismicity observed in the recent era: hypocenters are shallow and intermediate in depth (0–200 km), and the events occur almost exclusively in areas known to be currently seismic. The frequent seismic activity in the vicinity of the Paria Peninsula, Venezuela, is clearly a persistent feature of the regional earthquake pattern; intermediate depth earthquakes indicative of subduction beneath the Caribbean plate occur here and along the Lesser Antilles arc. The Grenadines seismic gap is confirmed as an area of low seismic moment release throughout the historical era. Trinidad and the eastern Gulf of Paria were also largely quiescent.The new focal mechanisms, despite being a sparse data set, give significant insight into both subduction processes along the Lesser Antilles arc and into the shallow deformation of the Caribbean-South America plate boundary zone. The largest earthquake to have occurred in this region, the 19 March 1953 event (M _m =7.01), is a Lesser Antilles slab deformation event, and another earthquake in this region of the Lesser Antilles is probably a rarely-observed interplate thrust event. Shallow deformation in the plate boundary zone is complex and, near the Paria Penninsula, involves mixed southeastward thrusting and dextral strike-slip on east-striking faults, and secondarily, normal faulting. Bending of the subducting Atlantic-South American plate also seems to generate seisms. The rather high ratio of intraplate deformation to interplate deformation observed along the Lesser Antilles subduction zone in the more recent era seems to have been operative in the historical era as well.     

Evidence for high water levels in the Erie basin during the Younger Dryas chronozone

A high water phase in the Lake Erie basin is identified from a variety of evidence for the period 11.0 ka to 10.5 ka. It is believed to correspond to the first Agassiz inflow to the upper Great Lakes (Main Lake Algonquin phase) when Agassiz waters discharged in both catastrophic and equilibrium modes to Lake Superior. After allowing for differential isostatic rebound, a computational model is used to estimate the lake levels in the Erie basin needed to generate Agassiz-equivalent discharges out of the basin into Lake Ontario. Computations suggest that Lake Tonawanda spillways would be re-activated by the high lake levels needed to sustain Agassiz-equivalent discharges. Existing published evidence from the Erie basin, Niagara River, and western New York (including ¹⁴C dates), is consistent with this interpretation. Additional evidence from the Niagara Peninsula (pollen spectra and geomorphology) supports the inference that extensive flooding of the southern Niagara Peninsula (Lake Wainfleet) occurred due to high water levels in the Erie basin. In the Niagara Peninsula, very shallow washover spillways would only operate when standard hydrologic variations of lake level in the Erie basin coincided with short term high levels driven by catastrophic inflows to the Great Lakes from Lake Agassiz. We support the view of Lewis & Anderson (1992) that a meltwater flux from Agassiz inflows reached Lake Erie.     

A GIS-based groundwater travel time model to evaluate stream nitrate concentration reductions from land use change

Excessive nitrate-nitrogen (nitrate) loss from agricultural watersheds is an environmental concern. A common conservation practice to improve stream water quality is to retire vulnerable row croplands to grass. In this paper, a groundwater travel time model based on a geographic information system (GIS) analysis of readily available soil and topographic variables was used to evaluate the time needed to observe stream nitrate concentration reductions from conversion of row crop land to native prairie in Walnut Creek watershed, Iowa. Average linear groundwater velocity in 5-m cells was estimated by overlaying GIS layers of soil permeability, land slope (surrogates for hydraulic conductivity and gradient, respectively) and porosity. Cells were summed backwards from the stream network to watershed divide to develop a travel time distribution map. Results suggested that groundwater from half of the land planted in prairie has reached the stream network during the 10 years of ongoing water quality monitoring. The mean travel time for the watershed was estimated to be 10.1 years, consistent with results from a simple analytical model. The proportion of land in the watershed and subbasins with prairie groundwater reaching the stream (10–22%) was similar to the measured reduction of stream nitrate (11–36%). Results provide encouragement that additional nitrate reductions in Walnut Creek are probable in the future as reduced nitrate groundwater from distal locations discharges to the stream network in the coming years. The high spatial resolution of the model (5-m cells) and its simplicity may make it potentially applicable for land managers interested in communicating lag time issues to the public, particularly related to nitrate concentration reductions over time.     

Occurrence of Kelvin-Helmholtz Billows in Sea-breeze Circulations

Centred at the interface between the sea-breeze and the return flow aloft, Kelvin-Helmholtz billows (KHB) are an important feature of the turbulent structure of some sea-breeze circulations (SBCs). In other SBCs, there are no prominent KHBs observed. Factors governing the appearance of billows are determined from a database of 139 sea breezes, constructed from two years of summertime surface observations at a site on the south coast of England. Post-frontal oscillations occur in the surface data for some SBCs and are interpreted as indicating possible KHBs aloft. The SBCs are formed under a wide range of synoptic conditions, enabling various measures of possible billow occurrence to be related to properties of the large-scale, ambient flow. Consistent with laboratory experiments of density currents, KHBs are suppressed for propagation into a head wind and enhanced with a tail wind. They are also found to be enhanced for stronger ambient wind speeds, while large-scale coast-parallel flow is effective in suppressing the billows.     

Comparison of COSPEC and two miniature ultraviolet spectrometer systems for SO2 measurements using scattered sunlight

The correlation spectrometer (COSPEC), the principal tool for remote measurements of volcanic SO₂, is rapidly being replaced by low-cost, miniature, ultraviolet (UV) spectrometers. We compared two of these new systems with a COSPEC by measuring SO₂ column amounts at Kīlauea Volcano, Hawaii. The two systems, one calibrated using in-situ SO₂ cells, and the other using a calibrated laboratory reference spectrum, employ similar spectrometer hardware, but different foreoptics and spectral retrieval algorithms. Accuracy, signal-to-noise, retrieval parameters, and precision were investigated for the two configurations of new miniature spectrometer. Measurements included traverses beneath the plumes from the summit and east rift zone of Kīlauea, and testing with calibration cells of known SO₂ concentration. The results obtained from the different methods were consistent with each other, with <8% difference in estimated SO₂ column amounts up to 800 ppm m. A further comparison between the COSPEC and one of the miniature spectrometer configurations, the ‘FLYSPEC’, spans an eight month period and showed agreement of measured emission rates to within 10% for SO₂ column amounts up to 1,600 ppm m. The topic of measuring high SO₂ burdens accurately is addressed for the Kīlauea measurements. In comparing the foreoptics, retrieval methods, and resultant implications for data quality, we aim to consolidate the various experiences to date, and improve the application and development of miniature spectrometer systems.