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61.
Jenni E. Sherriff Keith N. Wilkinson Poppy Harding Hayley Hawkins Rhys G. O. Timms Daniel S. Adler Emily J. Beverly Simon P. E. Blockley Boris Gasparyan Christina J. Manning Darren Mark Samvel Nahapetyan Katie J. Preece 《第四纪科学杂志》2022,37(1):6-27
The significance of the southern Caucasus in understanding Pleistocene hominin expansions is well established. However, the palaeoenvironments in which Palaeolithic occupation of the region took place are presently poorly defined. The Hrazdan river valley, Armenian Highlands, contains a rich Palaeolithic record alongside Middle Pleistocene volcanic, fluvial and lacustrine strata, and thus offer exciting potential for palaeoenvironmental reconstruction. We present the first results of sedimentological, geochemical, tephrostratigraphical and biological (diatoms) study of the sequence of Bird Farm 1, located in the central part of the valley. These data show six phases of landscape development during the interval 440–200 ka. The sequence represents the first quantitative Pleistocene diatom record from the Armenian Highlands and the southern Caucasus, and indicates the persistence of a deep, stratified lacustrine system, with evidence for changing lake productivity that is tentatively linked to climate. Furthermore, major element chemical characterization of visible and crypto-tephra horizons in the sequence enables the first stages of the development of a regional tephrostratigraphy. Together, the evidence from Bird Farm 1 demonstrates the importance of lacustrine archives in the region for palaeoenvironmental reconstruction and highlights the potential for linkages between archives on both a local and regional scale. 相似文献
62.
A vertical profile of maximum horizontal principal stress, SHmax, orientation to 5 km depth was obtained beneath the Swiss
city of Basel from observations of wellbore failure derived from ultrasonic televiewer images obtained in two 1 km distant
near-vertical boreholes: a 2755 m exploration well (OT2) imaged from 2550 m to 2753 m across the granitic basement-sediment
interface at 2649 m; and a 5 km deep borehole (BS1) imaged entirely within the granite from 2569 m to 4992 m. Stress-related
wellbore failure in the form of breakouts or drilling-induced tension fractures (DITFs) occurs throughout the depth range
of the logs with breakouts predominant. Within the granite, DITFs are intermittently present, and breakouts more or less continuously
present over all but the uppermost 100 m where they are sparse. The mean SHmax orientations from DITFs is 151 ± 13° whereas
breakouts yield 143 ± 14°, the combined value weighted for frequency of occurrence being N144°E ± 14°. No marked depth dependence
in mean SHmax orientation averaged over several hundred meters depth intervals is evident. This mean SHmax orientation for
the granite is consistent with the results of the inversion of populations of focal mechanism solutions of earthquakes occurring
between depths of 10–15 km within regions immediately to the north and south of Basel, and with the T-axis of events occurring
within the reservoir (Deichmann and Ernst, this volume). DITFs and breakouts identified in OT2 above and below the sediment-basement
interface suggest that a change in SHmax orientation to N115°E ± 12° within the Rotliegendes sandstone occurs near its interface
with the basement. The origin of the 20–30° change is uncertain, as is its lateral extent. The logs do not extend higher than
80 m above the interface, and so the data do not define whether a further change in stress orientation occurs at the evaporites.
Near-surface measurements taken within 50 km of Basel suggest a mean orientation of N–S, albeit with large variability, as
do the orientation of hydrofractures at depths up to 850 m within and above the evaporite layers and an active salt diapir,
also within 50 km of Basel. Thus, the available evidence supports the notion that the orientation of SHmax above the evaporites
is on average more N–S oriented and thus differs from the NW–SE inferred for the basement from the BS1/OS2 wellbore failure
data and the earthquake data. Changes in stress orientation with depth can have significant practical consequences for the
development of an EGS reservoir, and serve to emphasise the importance of obtaining estimates from within the target rock
mass. 相似文献
63.
Neutron activation determination of La, Ce, Sm, Eu, Tb, Yb, Lu, Ta, Hf, Sc, Co and Th in potassic lavas from the Birunga and Toro-Ankole regions show that the rocks are characterized by high rare earth element (REE) contents (161–754 ppm) and form two groups based upon differing La/Yb ratios. One group is made up of katungite, ugandite and mafurite with La/Yb =146–312, and the other of rocks of the leucitite and phonolitic tephrite series, La/Yb =30–56. The trace element content of the ugandite group is similar to that of kimberlites. The data do not indicate any trends of differentiation or simple relationships between the two groups of rocks, although katungite is unlikely to be parental to rocks of lower La/Yb ratios. It is unlikely that in terms of La/Yb ratios that partial melting of mica-garnet-lherzolite mantle can form katungite because of the very small amounts of partial melting required (0.2%), although the La/Yb ratios of 150–200 (ugandites, mafurites) and 30–60 (leucitites, phonolitic tephrites) can be accounted for by 0.3–1.5% and 1–9% melting respectively, if the REE are then concentrated without further La and Yb fractionation. Partial melting of mantle which has been metasomatized by alkaline earths and REE bearing fluids or mixing of carbonatite and nephelenite are also compatable with the observed geochemistry of the lavas. It is considered that gas transfer processes which selectively enrich the light REE may have obscured REE evidence pertaining to early partial melting and/or differentiation processes and therefore that REE geochemistry is of little use in determining the petrogenetic processes involved in the formation of potassic lavas. 相似文献
64.
Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization. 相似文献
65.
Farid Juillot Delphine Jouvin Philipe Telouk Philippe Ildefonse Steve Sutton Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308
Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ66Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ66Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ66Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe2O4)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ66Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ66Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ66Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments. 相似文献
66.
Keith A. W. Crook 《Australian Journal of Earth Sciences》2013,60(7-8):353-361
Complex contact relations between thin sills of the Adelaidean Cooee Dolerite and the enclosing flysch sediments (Burnie Formation) indicate emplacement of the sills into substantially uncompacted quasi‐liquid sediments very shortly after deposition. The sills are consequently coeval with the sediments rather than synchronous with the first phase of folding of the sediments (the Penguin Orogeny). The K/Ar date on the Cooee Dolerite, here revised as 725 ± 35 m.y. (J. Richards, pers. comm.), very probably provides an estimate of the age of the sediments, rather than the age of the orogeny. Age relationships of the Cooee Dolerite, its host sediments and their deformation proposed hitherto can no longer be regarded as settled. The Burnie Formation may be part of a passive continental margin to the Rocky Cape Block, which was deformed during the Cambrian as a result of subduction beneath the active margin of the Tyennan Block. 相似文献
67.
68.
69.
Sedimentary and igneous rocks of the Swaziland Sequence of South Africa (>3,200 my. old) contain total carbon (0.09–8.28%), organic carbon (0.04–1.95%) and sulfur (9–53,000 ppm). Amounts of organic carbon are generally high in the lower part of the Sequence (based on two samples from the Theespruit Formation). Sulfur content varies widely with no obvious correlations or trends. These rocks may contain clues to the early carbon and sulfur cycles on earth. 相似文献
70.
Two types of noise afflict strain and tilt measurement. They may be categorized as “active” noise, which is due to atmospheric pressure variations, temperature variations, water-table variations and so forth; and “passive” or signal-generated noise which is a consequence of the interaction of the strain field of interest with inhomogeneities of material properties local to the measurement site.The reason why both types of noise are normally reduced by the use of long base line instruments is explained and a simple, practical long base line tiltmeter is described. 相似文献