A laboratory study of the biogeochemical cycling of Fe,Mn, Zn and Cu across the sediment-water interface of a productive lake

Laboratory incubation experiments were carried out on sediment cores collected from Esthwaite Water, U.K., during April 1987, when the sediments displayed a characteristic surface (1.5 to 2 cm) oxide floc. The experiments were undertaken at 10°C, in the dark, under variable redox and pH conditions for periods of ~ 720 h (30 d). In some cases, realistic amounts of decomposing lake algae were added to simulate the deposition of an algal bloom. Pore waters and overlying waters were obtained from the incubated sediment cores at various time intervals and the samples analysed for pH and dissolved Fe, Mn, Zn and Cu by AAS. The results demonstrated that trace metal concentrations at the sediment-water interface can show rapid, pulsed responses to episodic events associated with controlling factors such as algal deposition and mixing conditions. The variations in dissolved Fe and Mn concentrations could generally be explained by their well known redox behaviour. Appreciable loss of Mn from solution under conditions of well-developed anoxia was consistent with adsorption of Mn²⁺ by FeS. Cu and Zn were both rapidly (24 h) released into solution during incubation of sediment cores prior to the development of anoxia in the overlying waters. Their most likely sources were the reductive remobilization of Mn oxides and the decomposition of organic matter. The addition of decomposing algae to a series of cores resulted in even higher interfacial dissolved concentrations of Cu and Zn, probably through acting as a supplementary source of the metals and through increased oxide dissolution. Switching from anoxic to oxic conditions also rapidly increased dissolved Cu and Zn concentrations, possibly due to their release during the oxidation of metal sulphides. The enhanced releases of dissolved Cu and Zn were generally short-lived with removal being attributed to the formation of sulphides during anoxia and to adsorption by Fe and Mn oxides under oxic conditions.     

Paleolimnology of McNearney lake: an acidic lake in northern Michigan

McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L^-1) and high SO _inf4 ^sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO _inf4 ^sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical     

Distribution of thermal areas on an active lava flow field: Landsat observations of Kilauea,Hawaii, July 1991

A Landsat Thematic Mapper (TM) image acquired on 23 July 1991 recorded widespread activity associated with the Episode 48 of the Pu'u 'O'o-Kupaianaha eruption of Kilauea Volcano, Hawaii. The scene contains a very large number (>3500) of thermally elevated near infrared (0.8–2.35 m) pixels (each 900 m²), which enable the spatial distribution of volcanic activity to be identified. This activity includes a lava lake within Pu'u 'O'o cone, an active lava tube system (7.9 km in length) with skylights between the Kupaianaha lava shield and several ocean entry points, and extensive active surface flows (total area of 1.3 km²) within a much larger area of cooling flows (total16 km²). The production of an average flux density map from the TM data of the flow field, wherein the average flux density is defined in units of Wm^-2, allows for the chronology of emplacement of active and cooling flows to be determined. The flux density map reveals that there were at least three breakouts (>5000 Wm^-2) feeding active flows, but on the day that the data were collected the TM recorded a waning phase of surface activity in this area, based on the relatively large amount of intermediate power-emitting (cooling) flows compared to high power-emitting (active) flows. The production of a comparable flux density map for future eruptions would aid in the assessment of volcanic hazards if the data were available in near-real time.     

Environmental determinism in Holocene research: causality or coincidence?

The past decade has seen a revival of environmental determinism in palaeoenvironmental research, with palaeoclimatic shifts implicated in the collapse of many past civilizations. Implicit in these studies is a belief that the observed cultural transitions can be causally related to the magnitude of climatic change. However, examination of the processes of these declines suggests that many exhibit patterns characteristic of complexity cascading within self-organized systems. If so, the nonlinear nature of these systems' responses to external forcing means that the assumption of causality in many of these cases should be considered questionable.     

Evolution of boundary‐layer aerosol particles due to in‐cloud chemical reactions during the 2nd Lagrangian experiment of ACE‐2

The second Aerosol Characterisation Experiment (ACE‐2) was aimed at investigating the physical, chemical and radiative properties of aerosol and their evolution in the North Atlantic region. In the 2nd "Lagrangian" experiment, an air mass was tracked over a 30‐h period during conditions of extensive stratocumulus cover. Boundary‐layer measurements of the aerosol size distribution obtained with a passive cavity aerosol spectrometer probe (PCASP) during the experiment show a gradual growth in size of particles in the 0.1–0.2 μm diameter mode. Simultaneously, SO₂ concentrations were found to decrease sharply from 800 to 20 ppt. The fraction of sulphate in aerosol ionic mass increased from 0.68±0.07 to 0.82±0.09 for small particles (diameter below 1.7 μm) and from 0.21±0.04 to 0.34±0.03 for large particles (diameter above 1.7 μm). The measurements were compared with a multicyclic parcel model of gas phase diffusion into cloud droplets and aqueous phase chemical reactions. The model was able to broadly reproduce the observed transformation in the aerosol spectra and the timescale for the transformation of SO₂ to sulphate aerosol. The modelled SO₂ concentration in the boundary layer fell to below half its initial value over a 6.5‐h time period due to a combination of the entrainment of cleaner tropospheric air and cloud chemical reactions. NH₃ and HCl gas were also found to play an important rôle in cloud processing in the model.     

A provisional map of forest types for the British Isles 5000 years ago

The distributions of seven woodland types, plus unforested areas, are mapped for the British Isles at 5000 BP. The map was compiled using data of modern soil distribution, present-day ecological preferences of the tree taxa present, and the pollen record.     

Multiproxy late Holocene peat records from Ireland: towards a regional palaeoclimate curve

Two new peat‐based climate records from Ireland covering the late Holocene are presented. The sequences are dated by a strong chronological framework formed by AMS radiocarbon dates and SCPs. Three proxy indicators (testate amoebae, macrofossils and humification) have been determined allowing the limitations and strengths of each to be identified and utilised to provide a bog surface wetness (BSW) record for both sites. Age–depth models take into account the potential for accumulation rates to vary with bog vegetation. The records from each site have been used to derive a combined BSW record that displays changes to a wetter/cooler climate from ca. AD 30 (1920 BP), ca. AD 310 (1640 BP), ca. AD 805 (1145 BP), ca. AD 1040 (910 BP) and ca. AD 1300 (650 BP). Changes follow closely those identified in a northern Britain composite BSW record and largely correspond with lake‐level data in central France suggesting the main changes in water balance were coherent over a large region. Correspondence with increases in IRD and slower Iceland‐Scotland Overflow Water (ISOW) suggests that these changes were related to oceanic forcing influencing the track of dominant westerly air flow over Ireland. Copyright © 2007 John Wiley & Sons, Ltd.