Age estimations based on amino acid racemization: Reply to comments of J.F. Wehmiller

Determining geologic ages of fossils by amino acid racemization techniques is often difficult because of the uncertainties in assumptions about diagenetic temperatures. Two kinetic model methods have been employed. Method 1, used by us, assumes that racemization of amino acids in the bivalve mollusk Saxidomus giganteus from Willapa Bay, Washington, follows linear kinetics. Ages are calculated by means of first-order kinetic equations. Method 2, used by Wehmiller, involves an empirical non-linear kinetic model Method 1 is simpler in concept and more easily applied. Wehmiller claims that ambiguities in paleotemperature arise when method 1 is used and that these ambiguities can be reconciled by the use of method 2. We show that application of method 1 can also provide reasonable temperature histories and leads to age estimates that are consistent with the geologic history of the sedimentary deposits at Willapa Bay.     

Torsional instability in structures

Torsional instability under harmonic excitation was detected in structures with cubic softening member stiffness. A variational procedure was introduced to perform the analysis for the general problem formulation. Single-storey structures with zero eccentricity were studied first; previous findings were checked and corrected, and the behaviour was examined in greater detail. Two-storey structures with large eccentricity were also examined, and further regions of torsional instability were detected. Time history analysis was then employed to quantify the behaviour of various typical structures. An unbounded growth in rotation or column displacement was not observed. Rather, the instability appeared to be related to the jump in response which exists in single degree-of-freedom softening oscillators subjected to harmonic excitation. The practical significance of torsional instability is therefore rather weak, although prudent practice would recommend its avoidance.     

Stability of composite river banks

The stability of a river bank depends on the balance of forces, motive and resistive, associated with the most critical mechanism of failure. Many mechanisms are possible and the likelihood of failure occurring by any particular one depends on the size, geometry and structure of the bank, the engineering properties of the bank material, the hydraulics of flow in the adjacent channel and climatic conditions. Rivers flowing through alluvial deposits often have a composite structure of cohesionless sand and gravel overlain by cohesive silt/clay. Bank erosion occurs by fluvial entrainment of material from the lower, cohesionless bank at a much higher rate than material from the upper, cohesive bank. This leads to undermining that produces cantilevers of cohesive material. Upper bank retreat takes place predominantly by the failure of these cantilevers. Three mechanisms of failure have been identified: shear, beam and tensile failure. The stability of a cantilever may be analysed using static equilibrium and beam theory, and dimensionless charts for cantilever stability constructed. Application of the charts requires only a few simple measurements of cantilever geometry and soil properties. In this analysis the effects of cracks and fissures in the soil must be taken into account. These cracks seriously weaken the soil and can invalidate a stability analysis by affecting the shape of the failure surface. Following mechanical failure, blocks of soil must be removed from the basal area by fluvial entrainment if rapid undermining and cantilever generation are to continue. Hence, the rate of bank retreat is fluvially controlled, even though the mechanism of failure of the upper bank is not directly fluvial in nature. This cycle of bank erosion: undermining, cantilever failure and fluvial scour of the toe, operates over several flood events and has important implications for river engineering, channel changes, and the movement of sediment through fluvial systems.     

Hydrocarbon gas in sediment from the shelf,slope, and basin of the Bering Sea

Hydrocarbon gases (methane, ethane, ethene, propane, propene, isobutane and n-butane) are present in low concentrations in the top two meters of sediment from the shelf, slope and basin of the Bering Sea. Methane is most abundant and its concentration increases with depth in the sediment. Average concentrations of methane recovered from these sediments are between about 4000 and 5000 nl per 1 of interstitial water. Ethane, ethene, propane and propene are present in almost all samples, but the concentrations of these gases are about two orders of magnitude lower than the concentration of methane. The average ratios of ethane to ethene are usually greater than one in shelf sediment, about one in slope sediment, and usually less than one in basin sediments. These hydrocarbon gases are probably derived from low-temperature chemical and biochemical processes operating at or near the sea-floor. At one location on the shelf, hydrocarbon gases suggest the possibility of petroleum at depth.     

Dynamic interaction of seismic activity along rising and sinking edges of plate boundaries

Cumulative and differential cumulative seismic strain release of shallow earthquakes during 1964 through 1972 show significant time-delayed correlation for many of the rises and/or sinks of tectonic plate boundaries for the Atlantic, Indian and Pacific oceans. For the Pacific, time delays are almost exclusively from areas of higher to areas of lower strain release, and could imply viscous stress relaxation along or near the lithosphere—asthenosphere boundary. Seismically determined slip rates for many of the subduction zones during 1964–1972 are lower than those of the preceding part of the century by a factor of 5. The significant correlation between many rises and sinks suggests worldwide interaction and coupling of plate motion.     

St. John's Island (Red Sea): a new geophysical model and its implications for the emplacement of ultramafic rocks in fracture zones and at continental margins

New gravity and magnetic data from the northern Red Sea reveal the extent of the large gravity anomaly (164 mgal) and the presence of significant magnetic anomalies over St. John's Island. Spectral transformation and three-dimensional potential-field modelling delineate the surface configuration and vertical extent of the causative body and the enormous density contrast required (1.2 g/cm³) suggests that it is composed of unserpentinised peridotite (density 3.4 g/cm³) to a depth of at least 8 km.St. John's Island is uniquely located, not only at a passive continental margin but also within a fracture zone at the transition from plate separation by seafloor spreading to extension by lithospheric attenuation. This precludes several suggested mechanisms for the emplacement of ultramafic bodies in fracture zones.Thermal contraction, serpentinite diapirism and changes in the poles of rotation do not seem possible mechanisms in this tectonic environment and the emplacement is most probably related to the spreading readjustment necessary to create a continent-to-continent fracture zone. A post-Mesozoic age of emplacement, associated with the onset of continental rifting and the rejuvenation of a pre-existing continental fracture, seems most probable.     

Amino acid geochemistry of fossil bones from the Rancho La Brea asphalt deposit,California

Low aspartic acid d:l ratios and modern collagenlike concentration values indicate that amino acids in bones from the Rancho La Brea asphalt deposit, Los Angeles, California are better preserved than amino acids in bones of equivalent age that have not been preserved in asphalt. Amino acids were recovered from 10 Rancho La Brea bone samples which range in age from less than 200 to greater than 36,000 yr. The calibrated rates of aspartic acid racemization range from 2.1 to 5.0 × 10^?6yr^?1. Although this wide range of rate constants decreases the level of confidence for age estimates, use of the larger rate constant of 5.0 × 10^?6yr^?1 provides minimum age estimates which fit the known stratigraphic and chronologic records of the Rancho La Brea deposits.