Stratospheric temperature trends: impact of ozone variability and the QBO

In most climate simulations used by the Intergovernmental Panel on Climate Change 2007 fourth assessment report, stratospheric processes are only poorly represented. For example, climatological or simple specifications of time-varying ozone concentrations are imposed and the quasi-biennial oscillation (QBO) of equatorial stratospheric zonal wind is absent. Here we investigate the impact of an improved stratospheric representation using two sets of perturbed simulations with the Hadley Centre coupled ocean atmosphere model HadGEM1 with natural and anthropogenic forcings for the 1979–2003 period. In the first set of simulations, the usual zonal mean ozone climatology with superimposed trends is replaced with a time series of observed zonal mean ozone distributions that includes interannual variability associated with the solar cycle, QBO and volcanic eruptions. In addition to this, the second set of perturbed simulations includes a scheme in which the stratospheric zonal wind in the tropics is relaxed to appropriate zonal mean values obtained from the ERA-40 re-analysis, thus forcing a QBO. Both of these changes are applied strictly to the stratosphere only. The improved ozone field results in an improved simulation of the stepwise temperature transitions observed in the lower stratosphere in the aftermath of the two major recent volcanic eruptions. The contribution of the solar cycle signal in the ozone field to this improved representation of the stepwise cooling is discussed. The improved ozone field and also the QBO result in an improved simulation of observed trends, both globally and at tropical latitudes. The Eulerian upwelling in the lower stratosphere in the equatorial region is enhanced by the improved ozone field and is affected by the QBO relaxation, yet neither induces a significant change in the upwelling trend.     

The utilization of North sea hydrocarbons as raw materials for petro-chemical manufacture

The oil and gas reserves of the North Sea have principally been regarded as sources of energy and little attention has been paid to their potential as raw materials for chemical manufacture. This paper reviews the technical and economic possibilities presented by the North Sea hydrocarbons as petro-chemical feedstocks. In particular, an attempt is made to predict changes which may occur in the geography of petro-chemical production in North West Europe if full advantage is taken of these possibilities.     

Constraints on the formation of geochemically variable plagiogranite intrusions in the Troodos Ophiolite,Cyprus

The geochemistry and petrology of tonalitic to trondhjemitic samples (n = 85) from eight different plagiogranite intrusions at the gabbro/sheeted dyke transition of the Troodos Ophiolite were studied in order to determine their petrogenetic relationship to the mafic plutonic section and the lava pile. The plagiogranitic rocks have higher SiO₂ contents than the majority of the glasses of the Troodos lava pile, but lie on a continuation of the chemical trends defined by the extrusive rocks, indicating that the shallow intrusions generally represent crystallised magmas. We define three different groups of plagiogranites in the Troodos Ophiolite based on different incompatible element contents and ratios. The first and most common plagiogranite group has geochemical similarities to the tholeiitic lavas forming the lavas and sheeted dyke complex in the Troodos crust, implying that these magmas formed at a spreading axis. The second plagiogranite group occurs in one intrusion that is chemically related to late-stage and off-axis boninitic lavas and dykes. One intrusion next to the Arakapas fault zone consists of incompatible element-enriched plagiogranites which are unrelated to any known mafic crustal rocks. The similarities of incompatible element ratios between plagiogranites, lavas and mafic plutonic rocks, the continuous chemical trends defined by plagiogranites and mafic rocks, as well as incompatible element modelling results, all suggest that shallow fractional crystallisation is the dominant process responsible for formation of the felsic magmas.     

Quantifying the influence of sill intrusion on the thermal evolution of organic‐rich sedimentary rocks in nonvolcanic passive margins: an example from ODP 210‐1276, offshore Newfoundland,Canada

Intrusive magmatism is an integral and understudied component in both volcanic and nonvolcanic passive margins. Here, we investigate the thermal effects of widespread (ca. 20 000 km²) intrusive magmatism on the thermal evolution of organic‐rich sedimentary rocks on the nonvolcanic Newfoundland passive margin. ODP 210‐1276 (45.41°N, 44.79°W) intersects two sills: an older, upper sill and a younger, lower sill that are believed to correspond to the high amplitude ‘U‐reflector’ observed across the Newfoundland Basin. A compilation of previous work collectively provides; (1) emplacement depth constraints, (2) vitrinite reflectance data and (3) ⁴⁰Ar/³⁹Ar dates. Collectively, these data sets provide a unique opportunity to model the conductive cooling of the sills and how they affect thermal maturity of the sedimentary sequence. A finite differences method was used to model the cooling of the sills, with the model outputs then being entered into the EASY%R_o vitrinite reflectance model. The modelled maturation profile for ODP 210‐1276 shows a significant but localized effect on sediment maturity as a result of the intrusions. Our results suggest that even on nonvolcanic margins, intrusive magmatism can significantly influence the thermal evolution in the vicinity of igneous intrusions. In addition, the presence of widespread sills on nonvolcanic passive margins such as offshore Newfoundland may be indicative of regional‐scale thermal perturbations that should be considered in source rock maturation studies.     

Seismic body waves in anisotropic media: synthetic seismograms

Summary. Synthetic seismograms and particle motion diagrams are computed for simple, layered Earth models containing an anisotropic layer. The presence of anisotropy couples the P, SV and SH wave motion so that P waves incident on the anisotropic layer from below produce P, SV and small-amplitude SH waves at the surface both the P velocity and the amplitudes of the converted phases vary with azimuth. Significant SH amplitudes may be generated even when the wavelength of the P wave is much greater than the thickness of the anisotropic layer. Incident SV or SH waves may each generate large amplitudes of both SV and SH motion. This strong coupling is largely independent of the degree of velocity anisotropy of the medium. The arrivals from short-period S waves exhibit S-wave splitting, but arrivals from longer period S waves superpose into a modified waveform. This strong coupling does not allow the arrival of separate phases with pure SV and SH polarization except along directions of symmetry where the motion decouples.