Paleolimnology of McNearney lake: an acidic lake in northern Michigan

McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L^-1) and high SO _inf4 ^sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO _inf4 ^sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical     

In situ arsenic removal in an alkaline clastic aquifer

In situ removal of As from ground water used for water supply has been accomplished elsewhere in circum-neutral ground water containing high dissolved Fe(II) concentrations. The objective of this study was to evaluate in situ As ground-water treatment approaches in alkaline ground-water (pH > 8) that contains low dissolved Fe (<a few tens of μg/L). The low dissolved Fe content limits development of significant Fe-oxide and the high-pH limits As adsorption onto Fe-oxide. The chemistries of ground water in the two aquifers studied are similar except for the inorganic As species. Although total inorganic As concentrations were similar, one aquifer has dominantly aqueous As(III) and the other has mostly As(V). Dissolved O₂, Fe(II), and HCl were added to water and injected into the two aquifers to form Fe-oxide and lower the pH to remove As. Cycles of injection and withdrawal involved varying Fe(II) concentrations in the injectate. The As concentrations in water withdrawn from the two aquifers were as low as 1 and 6 μg/L, with greater As removal from the aquifer containing As(V). However, Fe and Mn concentrations increased to levels greater than US drinking water standards during some of the withdrawal periods. A balance between As removal and maintenance of low Fe and Mn concentrations may be a design consideration if this approach is used for public-supply systems. The ability to lower As concentrations in situ in high-pH ground water should have broad applicability because similar high-As ground water is present in many parts of the world.     

The relative importance of biotic and abiotic vectors in nutrient transport

The mass of nutrients (nitrogen, phosphorus, potassium, and calcium) imported during 1984 and 1985 to the North. Inlet Estuary, Georgetown County, South Carolina, by precipitation and runoff was compared with that imported by a colonial-nesting wading bird, the white ibis (Eudocimus albus). From late March through late June of both years, breeding ibises imported nutrients to the North Inlet Estuary study site from freshwater bottomland forest swamps, where they fed on crayfishes (Procambaridae). Although 1984 was a relatively wet year, in 1985 the ibis breeding season was preceded by a severe winter-spring drought. In 1984 ibises nested in higher numbers, had higher per-pair breeding success, and imported 11 times more nutrients than in 1985. Nutrient input from atmospheric sources was substantially lower in 1984 than in 1985. The 1984 ibises imported 9% as much nitrogen, 33% as much phosphorus, 0.4% as much potassium, and 0.3% as much calcium to the estuary as did atmospheric sources. In 1985 nutrient input from ibises amounted to only 0.2% of the nitrogen, 2.9% of the phosphorus, and ?1% of the potassium and calcium imported by atmospheric sources. Our results show that nutrient inputs to estuaries from colonial-nesting wading birds can be substantial when compared, with those from atmospheric sources and can vary considerably among years. They also suggest that nutrient regimes in estuaries with large assemblages of wading birds may differ significantly from those lacking such colonies. *** DIRECT SUPPORT *** A01BY058 00006     

12 600 years of lake level changes, changing sills, ephemeral lakes and Niagara Gorge erosion in the Niagara Peninsula and Eastern Lake Erie basin

Over the last 12600 years, lake levels in the eastern Lake Erie basin have fluctuated dramatically, causing major changes in drainage patterns, flooding and draining ephemeral Lake Wainfleet several times and widening and narrowing the Niagara Gorge as the erosive effects of Niagara Falls waxed and waned. The control sill for Lake Erie levels was at first the Fort Erie/Buffalo sill, before the Lyell/Johnson sill in Niagara Falls took over due to isostatic rebound. This sill, in time, was eventually eroded by the recession of Niagara Falls and the Fort Erie/Buffalo sill regained control. The environmental picture is complicated by catastrophic outbursts from glacial Lake Agassiz and Lake Barlow-Ojibway, changes in outlet routes, isostatic rebound and climatic changes over the Great Lakes basins. Today, the flow of water into Lake Erie from the streams and rivers surrounding it only accounts for about 13% of the flow out of it, therefore, the importance of flow from the Upper Great Lakes, specifically the flow from Lake Huron, has a great effect on Lake Erie levels. While the changing control sills, Lyell/Johnson and Buffalo/Fort Erie would affect Lake Erie levels, overall they are mostly input driven by the amount of waters received from the Upper Great Lakes. Since Lake Erie's water level changes are so closely tied to Lake Huron's water level changes we have decided to use names assigned to Lake Huron such as the two Mattawa highstands and three Stanley lowstands rather than inflict a whole new set of names on the public. While the duration of each high and lowstand in Erie and Huron may not always be the same, they always happen within the same time frame. The datum elevations used for Lake Huron (175.8 m) and Lake Erie (173.3 m) are historically recorded averages. The Lake Erie levels proposed in this paper reflect Lake Hurons effects on Lake Erie and the levels occuring at the eastern end of the Erie Basin throughout the last 12600 years. All dates in this paper are uncorrected ¹⁴ C dates unless the date was obtained from shells, then the date has been corrected for hard-water effects. Also, all heights are given as modern day elevations and are not adjusted for isostatic rebound.     

Data Assimilation Modeling of the Barotropic Tides in the Korea/Tsushima Strait

During 1999–2000, 13 bottom mounted acoustic Doppler current profilers (ADCPs) and 12 wave/tide gauges were deployed along two lines across the Korea/Tsushima Strait, providing long-term measurements of currents and bottom pressure. Tidally analyzed velocity and pressure data from the moorings are used in conjunction with other moored ADCPs, coastal tide gauge measurements, and altimeter measurements in a linear barotropic data assimilation model. The model fits the vertically averaged data to the linear shallow water equations in a least-squares sense by only adjusting the incoming gravity waves along the boundaries. Model predictions are made for the O₁, P₁, K₁, μ₂, N₂, M₂, S₂, and K₂ tides. An extensive analysis of the accuracy of the M₂ surface-height predictions suggests that for broad regions near the mooring lines and in the Jeju Strait the amplitude prediction errors are less than 0.5 cm. Elsewhere, the analysis suggests that errors range from 1 to 4 cm with the exception of small regions where the tides are not well determined by the dataset. The errors in the model predictions are primarily caused by bias error in the model’s physics, numerics, and/or parameterization as opposed to random errors in the observational data. In the model predictions, the highest ranges in sea level height occur for tidal constituents M₂, S₂, K₁, O₁, and N₂, with the highest magnitudes of tidal velocities occurring for M₂, K₁, S₂, and O₁. The tides exhibit a complex structure in which diurnal constituents have higher currents relative to their sea level height ranges than semi-diurnal constituents.