Geology and Exploration of the Manteo Prospect off North Carolina

The Manteo Prospect is located about 45 mi northeast of Cape Hatteras, North Carolina. It is a high-risk prospect with world-class potential. The 21-lease unit was approved by the Minerals Management Service (MMS) in May 1990. A suspension of operations (SOO) was issued in October 1992 by the MMS. Chevron was approved for an exploration permit for Block 510 while Mobil's plan for Block 467 was under appeal. The Baltimore Canyon Trough and the Carolina Trough are the two large and deep sedimentary basins of the Atlantic Continental Margin. The Manteo unit is at the juncture of these two sedimentary basins. The Manteo Prospect is interpreted as a reef with its overlying structural high on the seaward edge of a carbonate platform. The structure is approximately30 mi long and 3-5 mi wide. The initial exploration well will be located at the highest point on the structure. Potential source rocks for the prospect are euxinic basinal shales and black micrite as well as interior lagoonal shales associated with the reef. The geothermal gradient projected from wells in the Baltimore Canyon Trough indicates that thermally mature sediments would be encountered below 12,000 ft in the vicinity of the Manteo Prospect. Mobil estimated that the Manteo Prospect may contain as much as 5 trillion ft3 of dry natural gas. A meeting was held between the State of North Carolina, MMS, and Chevron in February 1997 to discuss the proposal for the Manteo Prospect. An additional meeting held in September concentrated on drilling technology. A well could be drilled on Block 467 or Block 510 during the year 2000. Chevron has not decided which type of drilling vessel will be employed. The potential shorebase for operations is Morehead City, North Carolina.     

Bonemapping: a LiDAR processing and visualization technique in support of archaeology under the canopy

For the past decade, archaeologists have been using LiDAR or Airborne Laser Scanning (ALS)-based methods to uncover trace signatures of human civilization in the landscape. A new technique called bonemapping involves processing the ALS data to create a map-like representation of the landscape, which aids in the detection and interpretation of traces of human settlement. The technique is a combination of two methods – the Simple Morphological Filter (SMRF) for ALS processing and the Perceptually Shaded Slope Map (PSSM) for ALS representation – and is used to represent subtle changes in the terrain that are often indicative of previous human settlement. The SMRF algorithm adds value by retaining more “feature” cells than comparable terrain-finding algorithms, and is easy to tune through the use of two intuitive parameters – a slope threshold and a window size. The PSSM visualization is then used to apply a vertical exaggeration-based slope shading, which has proven useful as an aid to rapid feature detection, identification, and interpretation. The findings of two years of field use of bonemapping by archaeologists at El Pilar demonstrate the ways in which the bonemap offers a value-added perspective to archaeology under the canopy.     

Temporal trends of mercury in marine biota of west and northwest Greenland

Temporal trends in mercury concentrations ([Hg]) during the last two to three decades were determined in liver of shorthorn sculpin, ringed seal and Atlantic walrus from northwest Greenland (NWG, 77 degrees N) and in liver of shorthorn sculpin and ringed seal from central west Greenland (CWG, 69 degrees N) during the last decade. Stable-nitrogen (delta(15)N) and carbon (delta(13)C) isotope values were determined in muscle of ringed seals to provide insight into potential trophic level changes through time. Log-linear regressions on annual median [Hg] did not reveal any temporal trend in shorthorn sculpin from CWG and NWG and walrus from NWG. In ringed seals from NWG, an increase in [Hg] of 7.8% per year was observed. When based on delta(15)N-adjusted [Hg] this rate increased to 8.5% but was still non-significant. In ringed seal from CWG no trend was found in [Hg] during the period 1994-2004. However, during the last part of the period (1999-2004) the [Hg] increased significantly. Including tissue delta(15)N values as a covariate had a marked effect on these results. The annual changes in delta(15)N-adjusted [Hg] was estimated to -5.0% for the whole period and 2.2% during the last 5 years compared to -1.3% and 12.4%, respectively, for the non-adjusted [Hg].     

Surface magnetic fields on two accreting T Tauri stars: CV Cha and CR Cha

We have produced brightness and magnetic field maps of the surfaces of CV Cha and CR Cha: two actively accreting G- and K-type T Tauri stars in the Chamaeleon I star-forming cloud with ages of 3–5 Myr. Our magnetic field maps show evidence for strong, complex multipolar fields similar to those obtained for young rapidly rotating main-sequence stars. Brightness maps indicate the presence of dark polar caps and low-latitude spots – these brightness maps are very similar to those obtained for other pre-main-sequence and rapidly rotating main-sequence stars.
Only two other classical T Tauri stars have been studied using similar techniques so far: V2129 Oph and BP Tau. CV Cha and CR Cha show magnetic field patterns that are significantly more complex than those recovered for BP Tau, a fully convective T Tauri star.
We discuss possible reasons for this difference and suggest that the complexity of the stellar magnetic field is related to the convection zone; with more complex fields being found in T Tauri stars with radiative cores (V2129 Oph, CV Cha and CR Cha). However, it is clearly necessary to conduct magnetic field studies of T Tauri star systems, exploring a wide range of stellar parameters in order to establish how they affect magnetic field generation, and thus how these magnetic fields are likely to affect the evolution of T Tauri star systems as they approach the main sequence.     

Improving the way we think about projecting future energy use and emissions of carbon dioxide

A variety of decision makers need projections of future energy demand, CO₂ emissions and similar factors that extend many decades into the future. The past performance of such projections has been systematically overconfident. Analysts have often used scenarios based on detailed story lines that spell out “plausible alternative futures” as a central tool for evaluating uncertainty. No probabilities are typically assigned to such scenarios. We argue that this practice is often ineffective. Rather than expanding people’s judgment about the range of uncertainty about the future, scenario-based analysis is more likely to lead to systematic overconfidence, to an underestimate of the range of possible future outcomes. We review relevant findings from the literature on human judgment under uncertainty and discuss their relevance to the task of making probabilistic projections. The more detail that one adds to the story line of a scenario, the more probable it will appear to most people, and the greater the difficulty they likely will have in imagining other, equally or more likely, ways in which the same outcome could be reached. We suggest that scenario based approaches make analysts particularly prone to such cognitive biases, and then outline a strategy by which improved projections, tailored to the needs of specific decision makers, might be developed.     

Surface complexation of Pb(II) by hexagonal birnessite nanoparticles

Natural hexagonal birnessite is a poorly crystalline layer type Mn(IV) oxide precipitated by bacteria and fungi which has a particularly high adsorption affinity for Pb(II). X-ray spectroscopic studies have shown that Pb(II) forms strong inner-sphere surface complexes mainly at two sites on hexagonal birnessite nanoparticles: triple corner-sharing (TCS) complexes on Mn(IV) vacancies in the interlayers and double edge-sharing (DES) complexes on lateral edge surfaces. Although the TCS surface complex has been well characterized by spectroscopy, some important questions remain about the structure and stability of the complexes occurring on the edge surfaces. First-principles simulation techniques such as density functional theory (DFT) offer a useful way to address these questions by providing complementary information that is difficult to obtain by spectroscopy. Following this computational approach, we used spin-polarized DFT to perform total-energy-minimization geometry optimizations of several possible Pb(II) surface complexes on model birnessite nanoparticles similar to those that have been studied experimentally. We first validated our DFT calculations by geometry optimizations of (1) the Pb-Mn oxyhydroxide mineral, quenselite (PbMnO₂OH), and (2) the TCS surface complex, finding good agreement with experimental structural data while uncovering new information about bonding and stability. Our geometry optimizations of several protonated variants of the DES surface complex led us to conclude that the observed edge-surface species is very likely to be this complex if the singly coordinated terminal O that binds to Pb(II) is protonated. Our geometry optimizations also revealed that an unhydrated double corner-sharing (DCS) species that has been proposed as an alternative to the DES complex is intrinsically unstable on nanoparticle edge surfaces, but could become stabilized if the local coordination environment is well-hydrated. A significant similarity exists in the structural parameters for the TCS complex and those for a DCS edge-surface complex that is protonated in the same manner as the optimal DES complex, which could complicate detecting the DCS complex in X-ray absorption spectra.     

Silver in the subarctic northeast Pacific Ocean: Explaining the basin scale distribution of silver

Five vertical profiles of silver (Ag) in the subarctic northeast Pacific are presented. Dissolved (< 0.2 μm) Ag concentrations within the surface mixed layer range from 6–25 pM, with the highest observed values at the most coastal site. Elevated Ag concentrations at this station are most likely attributable to the estuarine circulation in the Juan de Fuca Strait. One open-ocean station (P20) exhibited a strong surface Ag maximum. The station was located at the edge of a Haida eddy which raises the possibility that such eddies transport Ag seaward from the coastal zone. Ag concentrations in the deep waters ranged from 60–80 pM. These measurements are consistent with other recent Ag data collected in the Pacific. Ag profiles throughout the Pacific Ocean yield a strong positive correlation between Ag concentration and dissolved silicic acid concentration. However, Ag is depleted relative to silicic acid at intermediate depths where dissolved O₂ concentrations are low, implying a possible removal of Ag from oxygen-depleted waters by scavenging and/or precipitation.