Titanium- and water-rich metamorphic olivine in high-pressure serpentinites from the Voltri Massif (Ligurian Alps,Italy): evidence for deep subduction of high-field strength and fluid-mobile elements

Titanium- and water-rich metamorphic olivine (Fo 86–88) is reported from partially dehydrated serpentinites from the Voltri complex, Ligurian Alps. The rocks are composed of mostly antigorite and olivine in addition to magnetite, chlorite, clinopyroxene and Ti-clinohumite. In situ secondary ion mass spectrometry (SIMS) data show that metamorphic olivine has very high and strongly correlated H₂O (up to 0.7 wt%) and TiO₂ contents (up to 0.85 wt%). Ti-rich olivine shows colourless to yellow pleochroism. Olivine associated with Ti-clinohumite contains low Ti, suggesting that Ti-rich olivine is not the breakdown product of Ti-clinohumite. Fourier transform infrared spectroscopy (FTIR) absorption spectra show peaks of serpentine, Ti-clinohumite and OH-related Si vacancies. Combining FTIR and SIMS data, we suggest the presence of clustered planar defects or nanoscale exsolutions of Ti-clinohumite in olivine. These defects or exsolutions contain more H₂O (x ~ 0.1 in the formula 4Mg₂SiO₄·(1?x)Mg(OH,F)₂·xTiO₂) than Ti-clinohumite in the sample matrix (x = 0.34–0.46). In addition to TiO₂ and H₂O, secondary olivine contains significant Li (2–60 ppm), B (10–20 ppm), F (10–130 ppm) and Zr (0.9–2.1 ppm). It is enriched in ¹¹B (δ¹¹B = +17 to +23 ‰). Our data indicate that secondary olivine may play a significant role in transporting water, high-field strength and fluid-mobile elements into the deeper mantle as well as introduce significant B isotope anomalies. Release of hydrogen from H₂O-rich olivine subducted into the deep mantle may result in strongly reduced mantle domains.     

Variability of surface characteristics and energy flux patterns of sunn hemp (Crotalaria juncea L.) under well-watered conditions

There is not much information in the literature about the energy partitioning and micrometeorological features of sunn hemp. Therefore, in this study, the variations in the energy-balance components and plant characteristics such as aerodynamic and surface conductance, crop coefficient, albedo, short- and long wave down- and upward radiation have been measured and estimated for the time period from August to October 2004 over an irrigated sand field at the Arid Land Research Center in Tottori, Japan. The Bowen ratio energy-balance method was used to calculate the partitioning of heat fluxes of sunn hemp. The Bowen ratio values at the first growing stages in August were found to be higher than the Bowen ratio values at the latest growing stages in September and October because of the heavy rain and high soil-water content. The daytime averaged Bowen ratio was 0.19. During the measurement period, the daytime average net radiation, and soil, latent and sensible heat fluxes were approximately 231, 28, 164, and 39 W m^–2, respectively. The net radiation and soil heat flux showed decreasing trends from the beginning to the end of the experiment period due to the atmospheric and crop growth conditions. The daytime averages of aerodynamic and surface conductance for sunn hemp were around 31 and 17 mm s^–1, respectively. Also, the daytime average albedo of sunn hemp was around 19%. Finally, the high precipitation amount due to typhoons, high soil-water content, low available energy and low vapor-pressure deficit lead to decreasing trend of the energy fluxes during the generative phase of sunn hemp.     

Redox Evolution of the Lithospheric Mantle beneath the North China Craton

正Objective The North China Craton(NCC)is a large Archean craton with a long geological history,yet very few studies have been carried out on the evolution of the redox conditions of its underlying mantle.Oxidation state of the mantle is critical in controlling the formation of metallic mineral deposits because metals can be readily released from the mantle to partial melt under oxidized conditions.     

Phosphorus and nitrogen cyclings in the pelagic system of hiroshima bay: Results of numerical model simulation

A numerical ecosystem model expressing both phosphorus and nitrogen cyclings in the pelagic system of Hiroshima Bay, Japan, was developed in order to investigate the seasonal variations of these elements and their annual budgets. Based on the geophysical and chemical structures of the bay, Hiroshima Bay was divided into northern and southern boxes, themselves divided into two layers of an upper 5 m and a lower layer according to the stratification of the water column. The model consists of equations representing all relevant physical and biological processes. The results revealed that the internal regeneration of materials was an important source of bioavailable nutrients for phytoplankton growth in the water column. The incorporation of phytoplankton aggregation improved the accuracy of the outputs in comparison to the observed data, especially during the stratified summer season. The results also indicated that phosphorus limitation of phytoplankton growth occurs in the upper layer during summer while light limitation occurs in the lower layer. In addition, physical processes such as diffusion and advection were also important as they ensured that most of regenerated nutrients in the lower layer were transported to the upper layer. Thus, these processes might support the high primary production and the production of oysters that are extensively cultured in this bay. Considering the informative results obtained, the model used in this study provides a sound basis and tool to describe the dynamics of phosphorus and nitrogen cyclings in Hiroshima Bay.     

Obliquity evolution of extrasolar terrestrial planets

We have investigated the obliquity evolution of terrestrial planets in habitable zones (at ∼1 AU) in extrasolar planetary systems, due to tidal interactions with their satellite and host star with wide varieties of satellite-to-planet mass ratio (m/Mp) and initial obliquity (γ₀), through numerical calculations and analytical arguments. The obliquity, the angle between planetary spin axis and its orbit normal, of a terrestrial planet is one of the key factors in determining the planetary surface environments. A recent scenario of terrestrial planet accretion implies that giant impacts of Mars-sized or larger bodies determine the planetary spin and form satellites. Since the giant impacts would be isotropic, tilted spins (sinγ₀∼1) are more likely to be produced than straight ones (sinγ₀∼0). The ratio m/Mp is dependent on the impact parameters and impactors' mass. However, most of previous studies on tidal evolution of the planet-satellite systems have focused on a particular case of the Earth-Moon systems in which m/Mp?0.0125 and γ₀∼10° or the two-body planar problem in which γ₀=0° and stellar torque is neglected. We numerically integrated the evolution of planetary spin and a satellite orbit with various m/Mp (from 0.0025 to 0.05) and γ₀ (from 0° to 180°), taking into account the stellar torques and precessional motions of the spin and the orbit. We start with the spin axis that almost coincides with the satellite orbit normal, assuming that the spin and the satellite are formed by one dominant impact. With initially straight spins, the evolution is similar to that of the Earth-Moon system. The satellite monotonically recedes from the planet until synchronous state between the spin period and the satellite orbital period is realized. The obliquity gradually increases initially but it starts decreasing down to zero as approaching the synchronous state. However, we have found that the evolution with initially tiled spins is completely different. The satellite's orbit migrates outward with almost constant obliquity until the orbit reaches the critical radius ∼10-20 planetary radii, but then the migration is reversed to inward one. At the reversal, the obliquity starts oscillation with large amplitude. The oscillation gradually ceases and the obliquity is reduced to ∼0° during the inward migration. The satellite eventually falls onto the planetary surface or it is captured at the synchronous state at several planetary radii. We found that the character change of precession about total angular momentum vector into that about the planetary orbit normal is responsible for the oscillation with large amplitude and the reversal of migration. With the results of numerical integration and analytical arguments, we divided the m/Mp-γ₀ space into the regions of the qualitatively different evolution. The peculiar tidal evolution with initially tiled spins give deep insights into dynamics of extrasolar planet-satellite systems and discussions of surface environments of the planets.     

Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.     

Cosmic-ray-produced40K and50V in the metal phase of chondrites

Cosmic-ray-produced⁴⁰K in the metal phase of six chondrites and⁵⁰V in that of one chondrite were determined using a surface ionization mass spectrometer. The²²Ne_total/⁴⁰K_metal ratios of the chondrites are explained in part by shielding effects during cosmic-ray irradiation. The wide variation of this ratio in some groups of meteorites is explained in terms of partial loss of rare-gas nuclides. Radiation ages for the chondrites were determined using⁴⁰K measurements and production-rate estimates from thick target calculations.     

Surface Heat Balance and Spatially Distributed Ablation Modelling at Koryto Glacier, Kamchatka Peninsula, Russia

To investigate the characteristics of ablation at Koryto Glacier, a mountain glacier under maritime climate in Kamchatka Peninsula, Russia, we made field observations from August to early September 2000. At a site near the equilibrium line, the 31‐day average net radiation, sensible heat flux, and latent heat flux were 43, 59 and 31 W^?2, respectively. We developed a new distributed ablation model, which only needs measurements of air temperature and global radiation at one site. Hourly ablation rates at this site obtained by the energy balance method are related to measured air temperature and global radiation by linear multiple regression. A different set of multiple regression coefficients is fitted for snow and ice surfaces. Better estimates of ablation rate can be obtained by this approach than by other temperature index models. These equations are then applied to each grid cell of a digital elevation model to estimate spatially distributed hourly melt. Air temperature is extrapolated using a constant temperature lapse rate and global radiation is distributed considering topographic effects. The model enables us to calculate the hourly spatial distribution of ablation rates within the glacier area and could well provide a realistic simulation of ablation over the whole glacier.     

Groundmass pargasite in the 1991–1995 dacite of Unzen volcano: phase stability experiments and volcanological implications

Pargasite commonly occurs in the dacitic groundmass of the 1991–1995 eruption products of Unzen volcano. We described the occurrence and chemical compositions of amphibole in the dacite, and also carried out melting experiments to determine the low-pressure stability limit of amphibole in the dacite. The 1991–1995 ejecta of the Unzen volcano show petrographic evidence of magma mixing, such as reverse compositional zoning of plagioclase and amphibole phenocrysts, and we used a groundmass separate as a starting material for the experiments. Reversed experiments show that the maximum temperature for the crystallization of amphibole is 930°C at 196 MPa, 900°C at 98 MPa, and 820°C at 49 MPa. Compared with the experimental results on the Mount St. Helens dacite, present experiments on the Unzen dacitic groundmass show that amphibole is stable to pressures ca. 50 MPa lower at 850°C. Available Fe–Ti oxide thermometry indicates the crystallization temperature of the groundmass of the Unzen dacite to be 880±30°C, suggesting that the groundmass pargasite crystallized at >70 MPa, corresponding to a depth of more than 3 km in the conduit. The chlorine content of the groundmass pargasite is much lower than that of phenocrystic magnesiohornblende in the 1991–1995 dacite of Unzen volcano, indicating that vesiculation/degassing of magma took place before the crystallization of the groundmass pargasite. The present study shows that the magma was water oversaturated and that the degassing of magma along with magma mixing caused crystallization of the groundmass amphibole at depths of more than 3 km in the conduit.     

Short‐term flood inundation prediction using hydrologic‐hydraulic models forced with downscaled rainfall from global NWP

A short‐term flood inundation prediction model has been formulated based on the combination of the super‐tank model, forced with downscaled rainfall from a global numerical weather prediction model, and a one‐dimensional (1D) hydraulic model. Different statistical methods for downscaled rainfall have been explored, taking into account the availability of historical data. It has been found that the full implementation of a statistical downscaling model considering physically‐based corrections to the numerical weather prediction model output for rainfall prediction performs better compared with an altitudinal correction method. The integration of the super‐tank model into the 1D hydraulic model demonstrates a minimal requirement for the calibration of rainfall–runoff and flood propagation models. Updating the model with antecedent rainfall and regular forecast renewal has enhanced the model's capabilities as a result of the data assimilation processes of the runoff and numerical weather prediction models. The results show that the predicted water levels demonstrate acceptable agreement with those measured by stream gauges and comparable to those reproduced using the actual rainfall. Moreover, the predicted flood inundation depth and extent exhibit reasonably similar tendencies to those observed in the field. However, large uncertainties are observed in the prediction results in lower, flat portions of the river basin where the hydraulic conditions are not properly analysed by the 1D flood propagation model. Copyright © 2013 John Wiley & Sons, Ltd.