Vulnerability of a public supply well in a karstic aquifer to contamination

To assess the vulnerability of ground water to contamination in the karstic Upper Floridan aquifer (UFA), age-dating tracers and selected anthropogenic and naturally occurring compounds were analyzed in multiple water samples from a public supply well (PSW) near Tampa, Florida. Samples also were collected from 28 monitoring wells in the UFA and the overlying surficial aquifer system (SAS) and intermediate confining unit located within the contributing recharge area to the PSW. Age tracer and geochemical data from the earlier stage of the study (2003 through 2005) were combined with new data (2006) on concentrations of sulfur hexafluoride (SF₆), tritium (³H), and helium-3, which were consistent with binary mixtures of water for the PSW dominated by young water (less than 7 years). Water samples from the SAS also indicated mostly young water (less than 7 years); however, most water samples from monitoring wells in the UFA had lower SF₆ and ³H concentrations than the PSW and SAS, indicating mixtures containing high proportions of older water (more than 60 years). Vulnerability of the PSW to contamination was indicated by predominantly young water and elevated nitrate-N and volatile organic compound concentrations that were similar to those in the SAS. Elevated arsenic (As) concentrations (3 to 19 μg/L) and higher As(V)/As(III) ratios in the PSW than in water from UFA monitoring wells indicate that oxic water from the SAS likely mobilizes As from pyrite in the UFA matrix. Young water found in the PSW also was present in UFA monitoring wells that tap a highly transmissive zone (43- to 53-m depth) in the UFA.     

Must magmatic intrusion in the lower crust produce reflectivity?

The Færoe–Iceland Ridge (FIR) provides a laboratory in which to investigate the reflectivity and velocity structure of thick crust generated above a mantle plume in order to constrain models of underplating and the origins of lower-crustal layering in an environment dominated by young igneous processes. Over 600 km of common midpoint (cmp) data were collected along and across the FIR using a large airgun array with a 240-channel streamer. The interpretation of these data has been integrated with a velocity model of the crust and upper mantle along the FIR obtained from wide-angle seismic arrivals into ocean bottom and land seismometers. Due to the intermediate water depths and the presence of basalt near the water bottom, specialized processing steps were required for the cmp data. A wave equation-based multiple attenuation scheme was applied to the prestack data, which used a forward model of the multiple series to predict and attenuate multiple energy. Array simulations were applied in the shot and receiver domains in order to minimize spatial aliasing and reduce low apparent-velocity noise. Most of the sections over the central (oceanic) portion of the FIR show no pronounced reflectivity, although occasional Moho and/or lower-crustal reflections are observed. We believe that the poor reflectivity results largely from a lack of physical property contrasts rather than being an effect of acquisition or processing, although we also conclude that residual energy from strong multiple reflection remains in the final sections. Amplitude decay and reflection strength vary along the FIR, but there is good signal-to-noise ratio to travel times of at least 9 s (i.e., into the lower crust), implying that the reduced reflectivity beneath the main part of the FIR is not an artifact of signal penetration loss. We conclude that the addition of melt to the lower crust along the trace of the plume apparently did not produce strong physical property contrasts in the lower crust, where little reflectivity is apparent. Perhaps this was because the entire crust was hot at the time of formation. In contrast, igneous intrusion into preexisting continental crust (at the Færoe Islands end of the FIR) and into older igneous crust (at the Iceland end of the FIR) produces significant lower-crustal reflectivity. Strong lower-crustal reflectivity elsewhere beneath the northwestern European continental margins may have a similar intrusive origin.     

Results of recent COCORP profiling in the southeastern United States

Summary. Recently acquired COCORP profiles in the southeastern United States show that: 1) Reflections associated with the Appalachian detachment are prominent beneath the Inner Piedmont of western Georgia, but do not extend further southeast beneath the Pine Mountain belt. 2) The Brunswick magnetic low is associated with a broad zone of crustal-penetrating dipping reflections that probably marks the Alleghanian suture in the southeastern U.S. 3) The South Georgia basin is a composite feature consisting of several half-graben, locally containing >5 km of Triassic - E. Jurassic basin fill. These basins occur within the interior of the Alleghanian orogen, but are not specifically associated with Alleghanian suture. 4) Across-strike crustal thickness variation, and distribution and character of lower-crust and Moho reflections in the Southern Appalachians is grossly similar to that observed in other parts of the Appalachian/Hercynian orogenic belt. Global comparisons suggest that these regional variations are a consequence of post-collisional extensional tectonics, rather than a primary (Palaeozoic or older) feature of the orogenic belt.     

Near-infrared spectra of 12 Near-Earth Objects

We present a number of spectra of Near-Earth Objects taken in the period 1998-2003 with two different instruments (CGS4 and UIST) on the UKIRT telescope. Since observations with CGS4 require multiple spectral fragments to be observed sequentially and then spliced together we assess the reliability of this technique using comparisons between multiple observations of the same object, between observations of the same object with both instruments and with independent spectra of common objects. We conclude that while problems in the spectral splicing can occur, they are usually intuitively obvious and that overall our dataset is sound. The objects for which we present new spectral data are: 1627 Ivar, 4179 Toutatis, 5381 Sekhmet, (5587) 1990 SB, 6489 Golevka, (11405) 1999 CV₃, (14402) 1991 DB, 25143 Itokawa, (25330) 1999 KV₄, (52760) 1998 ML₁₄, (66391) 1999 KW₄, and (101955) 1999 RQ₃₆. Our results, together with albedo data from the literature, suggest carbonaceous compositions for 25330 and 101955. The available data for 14402 suggest it may belong to the relatively rare M class. Our analysis suggests an S or Sq classification for 52760 and a V classification for 5381 Sekhmet. For all remaining objects the UKIRT data are consistent with published spectral classifications. We find that only 3 of the 12 objects are not S/Q/V-class, which is roughly consistent with the results of Binzel et al. [Binzel, R.P., Rivkin, A.S., Stuart, J.S., Harris, A.W., Bus, S.J., Burbine, T.H., 2004. Icarus 170, 259-294]. Four spectra of Toutatis taken over a range of solar phase angles between 0.7°-81° and at intervals of several weeks are indistinguishable within the uncertainties and therefore do not reveal any evidence for phase reddening or surface variegation.     

Pseudofaults resulting from compartmentalized Liesegang bands: update

Abstract Liesegang bands with apparent offset along fractures are common in some calcisiltite beds. Thin sections show, however, that primary laminations are not offset along the fractures. Following the development of fracture sets in the calcisiltite, the fractures were cemented by calcite. This formed polyhedral compartments of low‐permeability calcisiltite bounded by impermeable walls of calcite. Liesegang bands formed when oxygen in ground water diffused into polyhedra containing soluble ferrous iron in pore water. Each joint‐bounded polyhedral compartment behaved as an independent diffusion cell. Liesegang bands with nearly the same pattern and thickness tended to develop in adjacent compartments, but not at the same stratigraphic level; this resulted in the formation of pseudofaults.     

太湖1989—1993年富营养化资料的分析

The water quality of Lake Taihu has declined markedly in the past two or three decades. We used modern non-parametric statistical methods to analyse the water quality record for 1989-1993 (samples collected at 2-monthly intervals). Phytoplankton blooms have been a particular problem, as the very high peak chlorophyll a concentrations in the Meiliang (up to 0.4 g·m^-3) and the coastal regions (up to 0.5 g·m^-3) indicate. However, over a large area of the middle of the lake, peak chlorophyll a concentrations were much lower (0.01-0.03 g·m^-3). In this deeper, turbid part of the lake there may often be insufficient underwater light to support rapid phytoplankton growth; grazing by the abundant benthic bivalves may also be important. Total phosphorus (P) concentrations in the coastal waters increased significantly (p < 5%). Suspended solids concentrations also increased significantly, and as a result transparency decreased. However, phytoplankton probably usually only account for a small proportion of the suspended material, so the parallel increase in total P and suspended solids may be coincidental. Significant increases in chlorophyll a were not observed, but phytoplankton blooms are often short-lived (e.g. days to weeks), and thus may not always be detected by the 2-monthly sampling.