Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.     

Scoria cone formation through a violent Strombolian eruption: Irao Volcano, SW Japan

Scoria cones are common volcanic features and are thought to most commonly develop through the deposition of ballistics produced by gentle Strombolian eruptions and the outward sliding of talus. However, some historic scoria cones have been observed to form with phases of more energetic violent Strombolian eruptions (e.g., the 1943–1952 eruption of Parícutin, central Mexico; the 1975 eruption of Tolbachik, Kamchatka), maintaining volcanic plumes several kilometers in height, sometimes simultaneous with active effusive lava flows. Geologic evidence shows that violent Strombolian eruptions during cone formation may be more common than is generally perceived, and therefore it is important to obtain additional insights about such eruptions to better assess volcanic hazards. We studied Irao Volcano, the largest basaltic monogenetic volcano in the Abu Monogenetic Volcano Group, SW Japan. The geologic features of this volcano are consistent with a violent Strombolian eruption, including voluminous ash and fine lapilli beds (on order of 10^?1 km³ DRE) with simultaneous scoria cone formation and lava effusion from the base of the cone. The characteristics of the volcanic products suggest that the rate of magma ascent decreased gradually throughout the eruption and that less explosive Strombolian eruptions increased in frequency during the later stages of activity. During the eruption sequence, the chemical composition of the magma became more differentiated. A new K–Ar age determination for phlogopite crystallized within basalt dates the formation of Irao Volcano at 0.4?±?0.05 Ma.     

An analysis of the radar backscatter from oil-covered sea surfaces using moment method and Monte-Carlo simulation: preliminary results

An analysis of the radar backscattering from the ocean surface covered by oil spill is presented using a microwave scattering model and Monte-Carlo simulation. In the analysis, a one-dimensional rough sea surface is numerically generated with an ocean waveheight spectrum for a given wind velocity. A two-layered medium is then generated by adding a thin oil layer on the simulated rough sea surface. The electric fields backscattered from the sea surface with two-layered medium are computed with the method of moments (MoM), and the backscattering coefficients are statistically obtained with N independent samples for each oil-spilled surface using the Monte-Carlo technique for various conditions of surface roughness, oil-layer thickness, frequency, polarization and incidence angle. The numerical simulation results are compared with theoretical models for clean sea surfaces and SAR images of an oil-spilled sea surface caused by the Hebei (Hebei province, China) Spirit oil tanker in 2007. Further, conditions for better oil spill extraction are sought by the numerical simulation on the effects of wind speed and oil-layer thickness at different incidence angles on the backscattering coefficients.     

Global distributions of storm-time ionospheric currents as seen in geomagnetic field variations

To investigate temporal and spatial evolution of global geomagnetic field variations from high-latitude to the equator during geomagnetic storms, we analyzed ground geomagnetic field disturbances from high latitudes to the magnetic equator. The daytime ionospheric equivalent current during the storm main phase showed that twin-vortex ionospheric currents driven by the Region 1 field-aligned currents （R1 FACs） are intensified significantly and expand to the low-latitude region of-30~ magnetic latitude. Centers of the currents were located around 70~ and 65~ in the morning and afternoon, respectively. Corresponding to intensification of the R1 FACs, an enhancement of the eastward/westward equatorial electrojet occurred at the daytime/nighttime dip equator. This signature suggests that the enhanced convection electric field penetrates to both the daytime and nighttime equa- tor. During the recovery phase, the daytime equivalent current showed that two new pairs of twin vortices, which are different from two-cell ionospheric currents driven by the R1 FACs, appear in the polar cap and mid latitude. The former led to enhanced north- ward Bz （NBZ） FACs driven by lobe reconnection tailward of the cusps, owing to the northward interplanetary magnetic field （IMF）. The latter was generated by enhanced Region 2 field-aligned currents （R2 FACs）. Associated with these magnetic field variations in the mid-latitudes and polar cap, the equatorial magnetic field variation showed a strongly negative signature, produced by the westward equatorial electrojet current caused by the dusk-to-dawn electric field.     

Year-round accumulation of particulate organic matter in the estuarine turbidity maximum: comparative observations in three macrotidal estuaries (Chikugo, Midori, and Kuma Rivers), southwestern Japan

The inner part of the Ariake Sea is one of the most productive estuarine systems in Japan. To examine potential food items for estuarine organisms, we conducted monthly observations of the dynamics of particulate organic matter along the macrotidal Chikugo River estuary in 2005 and 2006. In the neighboring macrotidal Midori and Kuma River estuaries, comparative observations were made. High turbidity and strong vertical mixing were observed only at low salinities (<10) in the Chikugo River estuary. In contrast, the Midori and Kuma River estuaries were characterized by less turbid and less mixed waters. Concentrations of particulate organic carbon often exceeded 5?mg?l^?1 in or close to the estuarine turbidity maximum (ETM) of the Chikugo River estuary. However, such high concentrations were rarely observed in the other two estuaries. The observed differences could be attributable to different hydrodynamic processes related to the different lengths of tidal reaches: 23, 8, and 6?km in the Chikugo, Midori, and Kuma Rivers, respectively. In the Chikugo River estuary, spatiotemporal changes of chlorophyll a suggested that phytoplankton occurred abundantly up- and/or downstream from the ETM especially during the warm season. In contrast, pheophytin (i.e., plant detritus) always accumulated in or close to the ETM. Carbon stable isotope ratios and carbon to nitrogen ratios indicated that the plant detritus was derived from phytoplankton and terrestrial plants. The Chikugo River estuary has a high potential to support the production of estuarine organisms through abundant plant detritus in the well-developed ETM all the year round.     

Atmospheric gravity waves identified by ground-based observations of the intensity and rotational temperature of OH airglow

Spectroscopic observations of OH airglow undertaken on May 2, 2006 at Uji, Japan reveal variations in intensity and rotational temperature related to the passage of an atmospheric gravity wave. The variations exhibit a period of approximately 1 h and magnitudes of 2–6% in intensity and 0.5–2% in rotational temperature. The vertical wavelength and intrinsic frequency of the atmospheric gravity wave were determined from the horizontal wavelength derived by an OH airglow imager, the background horizontal wind velocity obtained by the middle and upper atmosphere (MU) radar, and the dispersion relationship. The observed variations are consistent with the values calculated using the model of Liu, A.Z., Swenson, G.R. [2003. A modeling study of O₂ and OH airglow perturbations induced by atmospheric gravity waves. J. Geophys. Res. 108 (No. D4), 4151. doi:10.1029/2002JD002474].     

Relationships between volcano distribution, crustal structure, and P-wave tomography: an example from the Abu Monogenetic Volcano Group, SW Japan

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geophysical data. We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan, and compare these distributions to fault and seismic data in the brittle crust, and P-wave tomography of the crust and upper mantle. Essential characteristics of the volcano distribution are extracted by a nonparametric kernel method using an algorithm to estimate anisotropic bandwidth. Overall, E-W elongate smooth modes in spatial density are identified that are consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting the idea that the spatial density map of volcanic vents reflects the geometry of a mantle diapir. While the number of basalt eruptions decreased after 0.2 Ma, andesite eruptions increased and overall volume eruption rate is approximately steady-state. Estimated basalt supply to the lower crust is also constant. This observation and the spatial distribution of volcanic vents suggest stability of magma productivity and essentially constant two-dimensional size of the source mantle diapir since 0.46 Ma.     

Numerical study of surface water circulation around Sekisei Lagoon, southwest Japan

This paper discusses the variability of surface currents around Sekisei Lagoon using a nested grid ocean circulation model. We developed a triple-nested grid system that consists of a coarse-resolution (1/60° or ∼1.85 km) model off Taiwan, an intermediate-resolution (1/300° or ∼370 m) model around the Yaeyama Islands, and a fine-resolution (1/900° or ∼123 m) model of Sekisei Lagoon. The nested grid system was forced by wind and heat flux calculated from six-hourly atmospheric reanalysis data and integrated over the period from May to July 2003. The coarse-resolution model was driven by lateral boundary conditions calculated from daily ocean reanalysis data to include realistic variation of the Kuroshio and mesoscale eddies with spatial scales of ∼500–700 km in the open ocean. The tidal forcing was included in the intermediate-resolution model by interpolating sea level data obtained from a data-assimilative tidal model. The results were then used to drive the fine-resolution model to simulate the surface water circulation around Sekisei lagoon. Model results show that (1) currents inside the lagoon are mainly driven by tide and wind; (2) there exists a strong southwestward current along the bottom slope in the southeast portion of the lagoon; the current is mainly driven by remote mesoscale eddies and at times intensified by the local wind; (3) the flow relaxation scheme is effective in reducing biases along the open boundaries. The simulated currents were used to examine the retention and dispersion of passive particles in the surface layer. Results show that the surface dispersion in the strong open ocean current region is significantly higher than that inside the lagoon.     

An overview of Task 6 of the Äspö Task Force: modelling groundwater and solute transport: improved understanding of radionuclide transport in fractured rock

An overview is presented of a 4-year study by the Äspö Task Force on Modelling of Groundwater Flow and Transport of Solutes, whose primary aim was to build a bridge between the approaches used for site characterisation (SC) and performance assessment (PA) associated with nuclear waste repositories. Eleven modelling teams representing six national radioactive waste organisations participated in eight modelling exercises whose objectives were: to assess simplifications used in PA models; to determine how, and to what extent, experimental tracer and flow experiments can constrain the range of parameters used in PA models; to support the design of SC programmes to assure that the results have optimal value for PA calculations; and to improve the understanding of site-specific flow and transport behaviour at different scales using SC models. The modelling tasks were concerned with flow and transport through single and multiple near-planar features on SC and PA timescales, including the diffusion of solutes into multiple immobile zones adjacent to fracture surfaces. In general, tracer tests provide only limited quantitative constraints on retention parameter values relevant to PA but nevertheless provide insight about the flow and transport processes, which is a key element of the bridge between SC and PA.     

Stable carbon isotope behaviour of natural seepage of deep underground C-rich methane detected along a fault zone and adsorbed in mudstone: Tokyo Bay area,Japan

Gas was sampled regionally, including by drilling into faults, in the South Kanto gas-field around Tokyo Bay, Japan. Gas samples were collected from cores in a gas sampling container immediately after drilling. A value of δ¹³C₁ = −44.3‰ was obtained for gas in the container and δ¹³C₁ = −36.3‰ for seeping gas in a fault zone. However, typical CH₄ in this dissolved-in-water gas-field is mainly depleted in ¹³C, and δ¹³C₁ values range from −66‰ to −68‰ owing to microbial degradation of organic material. ¹³C-rich CH₄ is so far uncommon in the South Kanto gas-field. Seepages were observed from the surface along the north–south fault zone. The natural gas is stored below the sandstone layer by impermeable mudstone underlying the boundary at a depth of 30 m. Gas seepages were not observed below a depth of 40 m. Gas rises along the fault zone dissolved-in-groundwater up to the shallow region and then separates from the groundwater. ¹³C-rich CH₄ (adsorbed CH₄) was found to have desorbed from drilled mudstone core samples taken at depths of 1400–1900 m in the main gas-production strata. Similarly, ¹³C-rich CH₄ was found in black shale overlying the oceanic crust forming part of a sedimentary accretionary prism underling the Tokyo region. It also appears in the spring-water of spa wells, originating at a depth of 1200–1500 m along a tectonic line. Methane generated by microbial degradation of organic material through CO₂ reduction in the South Kanto gas-field mainly originates as biogenic gas mixed with a small amount of ¹³C-rich CH₄, derived from thermogenic gas without oil components in strata. It is assumed that ¹²C-rich CH₄ is easily detached from core or pore water through gas production, whereas ¹³C-rich CH₄ is strongly adsorbed on the surfaces of particles. The ¹³C-rich CH₄ rises along the major tectonic line or up the 50 m wide normal fault zone from relatively deep sources in the Kanto region.