Seeing the trees for the carbon: agroforestry for development and carbon mitigation

Land-use, land-use change and forestry (LULUCF) activities will play an important role in global climate change mitigation. Many carbon schemes require the delivery of both climate and rural development benefits by mitigation activities conducted in developing countries. Agroforestry is a LULUCF activity that is gaining attention because of its potential to deliver climate benefits as well as rural development benefits to smallholders. There is hope that agroforestry can deliver co-benefits for climate and development; however experience with early projects suggests co-benefits are difficult to achieve in practice. We review the literature on agroforestry, participatory rural development, tree-based carbon projects and co-benefit carbon projects to look at how recommended project characteristics align when trying to generate different types of benefits. We conclude that there is considerable tension inherent in designing co-benefit smallholder agroforestry projects. We suggest that designing projects to seek ancillary benefits rather than co-benefits may help to reduce this tension.     

Holocene environmental change in southern Spain deduced from the isotopic record of a high-elevation wetland in Sierra Nevada

Small lakes and wetlands from high elevation within the Sierra Nevada Range (southern Spain) preserve a complete post-glacial Holocene record. Isotopic, TOC and C/N analyses, carried out on a sediment core, show various stages in the evolution of the Borreguiles de la Virgen, which today constitute a small bog at about 2,950?m above sea level. Glacial erosion generated a cirque depression, which became a small lake during the first phase of infilling (from?8,200 to 5,100?cal?yr BP), as suggested by sedimentary evidence, including an atomic C/N ratio generally below 20, low TOC values and the highest ??¹³C and ??¹⁵N values of the record. These results imply significant algal productivity, which is confirmed by the microscopic algal remains. Drier conditions became established progressively in this area from?5,100 to 3,700?cal?yr BP. Subsequently, the lake evolved into a bog as shown by geochemical evidence (C/N ratios above 20, high TOC content and low ??¹³C values). Unstable conditions prevailed from?3,600 to 700?cal?yr BP; an extremely low sedimentation rate and scarcity of data from this period do not allow us to make a coherent interpretation. Fluctuating conditions were recorded during the last?~700?cal?yr BP, with wetter conditions prevailing during the first part of the interval (with C/N rate below 20) up to 350?years ago. In general, a gradual trend toward more arid conditions occurred since?~6,900?cal?yr BP, with a further increase in aridity since?~5,100?cal?yr BP. This evidence is consistent with other contemporaneous peri-Mediterranean records.     

Industrial agglomeration and transport accessibility in metropolitan Seoul

This study aims to reveal the relationship between industrial agglomeration and transport accessibility in the Seoul metropolitan area. Our study suggests that in spite of the rapid expansion of the Seoul metropolitan area, central business districts still function as centers of the industry and transportation system; the agglomeration of most industrial subsectors are occurring in central areas and only primary and manufacturing sectors’ clusters are located out of these areas; both of subway and road networks show higher level of accessibility in central Seoul and big cities. This implies a strong relationship between the industrial agglomeration and the transport accessibility, and such hypothetical relationship is tested for every industrial subsector using logit analysis. Our findings indicate that although there are industrial variations in the magnitude of impacts and the significance level, transport networks are, in general, positively associated with industrial agglomeration and this is especially true for service sectors.     

Particle-tracking simulation for the drift/diffusion of spilled oils in the Sea of Okhotsk with a three-dimensional, high-resolution model

To conduct the simulation of oil spills in the Sea of Okhotsk, we developed a three-dimensional, high-resolution ocean circulation model. The model particularly improved the reproducibility of velocity field during the strong stratification period. Particle-tracking experiments with the effects of evaporation and biodegradation were performed using the combined data of daily ocean currents from the present model and the hourly diurnal tidal currents from the tidal model. The results are shown by the relative concentration of the particles averaged over the 8 years of 1998–2005 based on the ensemble forecast idea. For the case of particles released from the Sakhalin II oil field, the particles deployed in September–January are carried southward by the East Sakhalin Current, finally arriving at the Hokkaido coast, after 60–90 days. The particles deployed in March–August are diffused offshore by the synoptic wind drift, and hardly transported to regions south of Sakhalin. For the case of particles released from the region off Prigorodnoye, the oil export terminal, after the diffusion by the synoptic wind drift, a part of them are carried offshore of Hokkaido by the Soya Warm Current. The particles released in November–April flow out to the Japan Sea through the Soya Strait, mainly by the synoptic wind drift and secondly by the diffusion due to strong tidal currents around the Soya Strait. By considering the effects of evaporation and biodegradation, the relative concentration of the particles is considerably decreased before arriving at the Hokkaido coast, particularly in the case of drift from the Sakhalin II oil field.     

The influence of multivariate analysis methods and target grain size on the accuracy of remote quantitative chemical analysis of rocks using laser induced breakdown spectroscopy

Laser-induced breakdown spectroscopy (LIBS) was used to quantitatively analyze 195 rock slab samples with known bulk chemical compositions, 90 pressed-powder samples derived from a subset of those rocks, and 31 pressed-powder geostandards under conditions that simulate the ChemCam instrument on the Mars Science Laboratory Rover (MSL), Curiosity. The low-volatile (<2 wt.%) silicate samples (90 rock slabs, corresponding powders, and 22 geostandards) were split into training, validation, and test sets. The LIBS spectra and chemical compositions of the training set were used with three multivariate methods to predict the chemical compositions of the test set. The methods were partial least squares (PLS), multilayer perceptron artificial neural networks (MLP ANNs) and cascade correlation (CC) ANNs. Both the full LIBS spectrum and the intensity at five pre-selected spectral channels per major element (feature selection) were used as input data for the multivariate calculations. The training spectra were supplied to the algorithms without averaging (i.e. five spectra per target) and with averaging (i.e. all spectra from the same target averaged and treated as one spectrum). In most cases neural networks did not perform better than PLS for our samples. PLS2 without spectral averaging outperformed all other procedures on the basis of lowest quadrature root mean squared error (RMSE) for both the full test set and the igneous rocks test set. The RMSE for PLS2 using the igneous rock slab test set is: 3.07 wt.% SiO₂, 0.87 wt.% TiO₂, 2.36 wt.% Al₂O₃, 2.20 wt.% Fe₂O₃, 0.08 wt.% MnO, 1.74 wt.% MgO, 1.14 wt.% CaO, 0.85 wt.% Na₂O, 0.81 wt.% K₂O. PLS1 with feature selection and averaging had a higher quadrature RMSE than PLS2, but merits further investigation as a method of reducing data volume and computation time and potentially improving prediction accuracy, particularly for samples that differ significantly from the training set. Precision and accuracy were influenced by the ratio of laser beam diameter (∼490 μm) to grain size, with coarse-grained rocks often resulting in lower accuracy and precision than analyses of fine-grained rocks and powders. The number of analysis spots that were normally required to produce a chemical analysis within one standard deviation of the true bulk composition ranged from ∼10 for fine-grained rocks to >20 for some coarse-grained rocks.     

Reconstruction of propagating Kelvin–Helmholtz vortices at Mercury's magnetopause

A series of quasi-periodic magnetopause crossings were recorded by the MESSENGER spacecraft during its third flyby of Mercury on 29 September 2009, likely caused by a train of propagating Kelvin–Helmholtz (KH) vortices. We here revisit the observations to study the internal structure of the waves. Exploiting MESSENGER's rapid traversal of the magnetopause, we show that the observations permit a reconstruction of the structure of a rolled-up KH vortex directly from the spacecraft's magnetic field measurements. The derived geometry is consistent with all large-scale fluctuations in the magnetic field data, establishes the non-linear nature of the waves, and shows their vortex-like structure. In several of the wave passages, a reduction in magnetic field strength is observed in the middle of the wave, which is characteristic of rolled-up vortices and is related to the increase in magnetic pressure required to balance the centrifugal force on the plasma in the outer regions of a vortex, previously reported in computer simulations. As the KH wave starts to roll up, the reconstructed geometry suggests that the vortices develop two gradual transition regions in the magnetic field, possibly related to the mixing of magnetosheath and magnetospheric plasma, situated at the leading edges from the perspectives of both the magnetosphere and the magnetosheath.     

Shallow ocean overturning and the heat and carbon content of the Glacial Tropical Ocean

Mechanisms affecting the heat and carbon content of the Glacial Tropical Ocean (21,000 years BP) remain controversial. Exchange with the deep ocean via vertical mixing and the overturning circulation is one aspect that is clearly relevant to greenhouse gas concentrations and future climate change. We examined evidence of the possible role of the shallow overturning contribution on the Glacial Tropical Ocean temperature and carbonate ion concentration. Compared to the present, we find that the Glacial tropical upper ocean (0–1000 m) had enhanced vertical gradients in temperature and carbonate ion concentration, reduced turbulent diffusivity (vertical mixing rate) (by 20% or more), and weakened Ekman pumping in middle-latitudes, all consistent with reduced shallow overturning. The weakened property exchanges between the tropical upper ocean and the ocean below (cold with high total dissolved carbon-dioxide concentration) provide a unified explanation for both the unexpectedly-small sea surface cooling and the lower carbon-dioxide content in the Glacial tropical upper ocean and the atmosphere.     

Current assessment of the Red Rectangle band problem

In this paper we discuss our insights into several key problems in the identification of the Red Rectangle Bands (RRBs). We have combined three independent sets of observations in order to try to define the constraints guiding the bands. We provide a summary of the general behavior of the bands and review the evidence for a molecular origin of the bands. The extent, composition, and possible absorption effects of the bands are discussed. Comparison spectra of the strongest band obtained at three different spectral resolutions suggests that an intrinsic line width of individual rotational lines can be deduced. Spectroscopic models of several relatively simple molecules were examined in order to investigate where the current data are weak. Suggestions are made for future studies to enhance our understanding of these enigmatic bands.