The evolution from Miocene potassic to Quaternary sodic magmatism in western Turkey: implications for enrichment processes in the lithospheric mantle

New K-Ar dating and major- and trace-element analyses from the U ak-Selendi-Emet (USE) area constrain the timing of changes in the nature of volcanism in the Miocene in western Turkey. The data reveal a change from dominantly calc-alkaline and silicic in the Early Miocene to largely alkaline and more mafic volcanism in the Middle Miocene. This probably reflects a decreasing amount of crustal contamination with time, a result of extensional tectonics. High levels of various incompatible elements (including K) in the more mafic members, suggest an enriched subcontinental lithospheric source region for the Middle Miocene USE lavas. Highly variable Nb/Y, Ti/Y and Th/Nb ratios suggest a lithospheric mantle heterogeneously enriched by two processes: (1) enrichment by subduction-related processes producing high Th/Nb but low Nb/Y and Ti/Y; and (2) enrichment by small degree melts of depleted upper mantle producing low Th/Nb but high Nb/Y and Ti/Y. Both of these enrichment processes have variably contributed to Middle Miocene K-rich lavas in the USE area. The mechanism which initiated the melting of the enriched lithosphere is considered to be extension which produced decompression melting. Comparisons with the nearby Kula lavas reveals that by the Pliocene to Quaternary, volcanism, although still enriched in incompatible elements, had become sodic. It seems likely that continued extension up to this time thinned the lithosphere to such an extent that asthenospheric melts were produced which ascended and mixed with previously enriched lithosphere.     

The nature and fate of natural resins in the geosphere--VIII. NMR and Py-GC-MS characterization of soluble labdanoid polymers, isolated from Holocene class I resins

Soluble polylabdanoids isolated by sequential solvent extraction have been characterized by liquid-state ¹³C- and ¹H NMR and ¹³C-¹H HMQC (heteronuclear correlation) NMR spectroscopy in addition to solid-state NMR and Py-GC-MS techniques. Two Holocene resins originating from Santander, Colombia and Mombasa, Kenya were analyzed. Soluble polymers were isolated by extraction with a 1:1 (v/v) methylene chloride-methanol mixture following sequential extractions with methylene chloride and methanol. The molecular weight of polymer extracts was shown by GPC analyses to exceed that of non-polymeric occluded terpenoids. Py-GC-MS, solid-state ¹³C CP/MAS and ¹³C cross-polarization/depolarization NMR spectroscopy results indicated that chemical compositions of soluble polymers isolated from immature resins are highly representative of the structure of corresponding insoluble polymers, i.e. polylabdatrienes. These data provide evidence for cross-linking or cyclization of side-chain olefinic carbons during or shortly after polymerization. Generally, the characterization of soluble resin polymers by liquid-state NMR spectroscopy has proven to be an excellent means for investigating the maturation mechanism of polylabdanoid resinites, and has potential for furthering the application of Class I resinites as geothermal indicators.     

The operational environment

With the changing nature of what can be defined as security and the more widely ranging role of the military, the concept of the operational environment has been vastly enhanced. At the same time, the focus with regard to conflict has moved from a potential global nuclear war to conventional regional or local encounters. As a result, considerations of the fundamental environments in which the three armed services operate have become more prominent. In response to these changes, the aim of the paper is to review the various bases for the study of the military operational environment, while placing the emphasis upon conflict and the physical environment.     

Santa Bárbara Formation (Early Paleozoic, Caçapava do Sul, southern Brazil): Petrographic and Sm–Nd isotopic provenance parameters

Integrated petrographic and Sm–Nd isotopic data were applied in order to constrain the provenance of the Early Paleozoic Santa Bárbara Formation, Sul-rio-grandense Shield, southern Brazil. This unit comprises continental sandstones, conglomerates and siltstones deposited under semi-arid climate in a rift or pull-apart basin. Samples were collected within a stratigraphic framework composed of three sequences, in which the two basal ones present northeastwards paleoflow, and the third one marks the inversion of basin filling. Samples from sequence I show, in the south, a strong influence of intermediate volcanic (Hilário Formation) sources, and a significant increase in quartz and metamorphic fragments upsection. In the northern deposits, there is a possible influence of juvenile units (Cambaí/Vacacaí), and a more significant input of Paleoproterozoic-sourced sedimentary rocks (e.g. Maricá Formation) upsection. Samples collected from the topmost deposits of sequence II present a clear increase in the amount of volcanic fragments (mostly acidic), reflecting denudation of the “Caçapava high”. Data obtained in sequence III (Pedra do Segredo) show a progressive decrease in quartz content and a significant increase in feldspathic, plutonic fragments. A more evolved phase of denudation of the “Caçapava high”, exposing leucogranitoids of the Caçapava do Sul complex, is proposed for this interval.     

The nature and fate of natural resins in the geosphere XIII: a probable pinaceous resin from the early Cretaceous (Barremian), Isle of Wight

Terpenoid resin is produced by all families and most genera of the order Coniferales (the conifers), and the distribution of terpenes present in most conifer resins is characteristic of the originating family. Analyses of early Cretaceous (Barremian) amber (fossil resin) from the English Wealden, Isle of Wight, southern England, by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), indicate a terpene distribution dominated by abietane- and labdane-type terpenes. Similar distributions are observed in some species of the extant family Pinaceae. The Pinaceae are well represented within the Wealden deposits of southern England, by only one (known) species, Pityites solmsii (Seward) Seward, whereas the macro-fossil record of these deposits is dominated by the extinct conifer family Cheirolepidiaceae, for which no resin chemistry has been reported. By analogy with modern materials, it is probable that the ambers found in these deposits are derived from an extinct member of the Pinaceae, but given the absence of evidence concerning the chemotaxonomy of the Cheirolepidiaceae, this family cannot be excluded a priori as a possible paleobotanical source. These ambers may therefore be assigned to either the Pinaceae or to the Cheirolepidiaceae. These samples are the oldest ambers to date to yield useful chemotaxonomic data.     

Examining the Variability of Crossing Times for Canadian Trucks at the Three Major Canada–U.S. Border Crossings

Land borders connecting Canada and the United States are vital transportation facilities for the two countries. Truck crossing times at these facilities can have a significant impact on the performance of the economy. To date, knowledge about border crossing times has been limited due to lack of detailed data on the Canadian border. This article explores and models the patterns of crossing times at the three major land crossings connecting Canada to the United States: Ambassador Bridge, Blue Water Bridge, and Peace Bridge. The analysis is based on 387,775 border crossing truck trips that were generated between Canada and the United States over a course of twelve months. Seemingly unrelated regression (SUR) models are estimated to evaluate the seasonal and hourly crossing times of Canada- and U.S.-bound trips on each border crossing, controlling for traffic intensity in the models. The SUR modeling approach is chosen to control for potential cross-model correlations. The results suggest that crossing times at the border vary by season and hour of the day. Crossing times also vary by direction of traffic and by type of day (i.e., weekday vs. weekend). Traffic intensity has a significant influence on crossing times at two of the crossings but not the Blue Water Bridge. Finally, crossing times are more variable during the summer season and tend to be higher during the late evening hours and past midnight.     

What if negative emission technologies fail at scale? Implications of the Paris Agreement for big emitting nations

A cumulative emissions approach is increasingly used to inform mitigation policy. However, there are different interpretations of what ‘2°C’ implies. Here it is argued that cost-optimization models, commonly used to inform policy, typically underplay the urgency of 2°C mitigation. The alignment within many scenarios of optimistic assumptions on negative emissions technologies (NETs), with implausibly early peak emission dates and incremental short-term mitigation, delivers outcomes commensurate with 2°C commitments. In contrast, considering equity and socio-technical barriers to change, suggests a more challenging short-term agenda. To understand these different interpretations, short-term CO₂ trends of the largest CO₂ emitters, are assessed in relation to a constrained CO₂ budget, coupled with a ‘what if’ assumption that negative emissions technologies fail at scale. The outcomes raise profound questions around high-level framings of mitigation policy. The article concludes that applying even weak equity criteria, challenges the feasibility of maintaining a 50% chance of avoiding 2°C without urgent mitigation efforts in the short-term. This highlights a need for greater engagement with: (1) the equity dimension of the Paris Agreement, (2) the sensitivity of constrained carbon budgets to short-term trends and (3) the climate risks for society posed by an almost ubiquitous inclusion of NETs within 2°C scenarios.

POLICY RELEVANCE

Since the Paris meeting, there is increased awareness that most policy ‘solutions’ commensurate with 2°C include widespread deployment of negative emissions technologies (NETs). Yet much less is understood about that option’s feasibility, compared with near-term efforts to curb energy demand. Moreover, the many different ways in which key information is synthesized for policy makers, clouds the ability of policy makers to make informed decisions. This article presents an alternative approach to consider what the Paris Agreement implies, if NETs are unable to deliver more carbon sinks than sources. It illustrates the scale of the climate challenge for policy makers, particularly if the Agreement’s aim to address ‘equity’ is accounted for. Here it is argued that much more attention needs to be paid to what CO₂ reductions can be achieved in the short-term, rather than taking a risk that could render the Paris Agreement’s policy goals unachievable.     

Unusual carbon and oxygen isotopic ratios of ostracodal calcite from last interglacial (Sangamon episode) lacustrine sediment in Raymond Basin, Illinois, USA

The stable isotopic records of ostracode valves deposited during the last interglaciation in Raymond Basin, Illinois, have ¹³C and ¹⁸O values as high as +16.5 and +9.2 respectively, the highest values yet reported from continental ostracodal calcite. Located in south-central Illinois, Raymond, Pittsburg, Bald Knob, and Hopwood Farm basins collectively have yielded important long pollen and ostracode records that date from about 130000 years ago to the present. Although fossils from the present-day interglaciation are not well preserved, these records constitute the only described, conformable, fossiliferous successions of this age from the interior of glaciated North America.The high ¹³C values from Raymond Basin are attributed to the residual effects of methane loss either by ebullition or by emission through the stems of senescent emergent aquatic vegetation. A mass balance model suggests that an increase in ¹³C of dissolved inorganic carbon on the order of +15 is possible within a few hours given modest rates of methanogenesis of about 0.02 mol m^-2 d^-1. The ¹³C records from other studies of ostracode valves have values approaching, but not exceeding about +14 suggesting a limiting value to ¹³C enrichment due to simultaneous inputs and outputs of dissolved inorganic carbon.Values of ¹⁸O in ostracodal calcite are quite variable (–4 to +9) in sediment from the late Sangamon subepisode. A model of isotopic enrichment in a desiccating water body implies that a reduction in reservoir volume of 20% could produce this range of isotopic values. High humidity and evaporation probably account for most of the ¹⁸O variability.