A procedure for automated analysis of brief pumping tests of domestic wells

A new computer program has been developed to automate analysis of brief single-well pumping tests. Adapted from a procedure developed by Picking (1994) that does not require measurement of the pumping rate, this new program is menu-driven and eliminates one significant source of imprecision in Picking's original method, namely, selection of "well function of u" values by interpolation in a lookup table. This new program has been applied to tests of 25 domestic wells penetrating bedrock, each pumped for <2 min.     

On the politics of recognition in critical urban scholarship

In this response to Ananya Roy’s plenary talk at the Association of American Geographers annual meeting in 2015, “What’s urban about critical urban theory,” I engage the work of Nancy Fraser and feminist epistemologists to argue for the necessity of a robust critical politics of recognition in knowledge projects with emancipatory aims. I question the political utility and empirical accuracy of the increasingly popular assertion that there is no analytical outside to the category “urban,” and argue, like many feminist, post-colonial, and anti-racist scholars before me, that attempts to construct a totalizing political subject have the effect of reproducing cultural misrecognition and are thus incompatible with emancipatory politics.     

High‐Precision Mass‐Dependent Molybdenum Isotope Variations in Magmatic Rocks Determined by Double‐Spike MC‐ICP‐MS

Small mass‐dependent variations of molybdenum isotope ratios in oceanic and island arc rocks are expected as a result of recycling altered oceanic crust and sediments into the mantle at convergent plate margins over geological timescales. However, the determination of molybdenum isotope data precise and accurate enough to identify these subtle isotopic differences remains challenging. Large sample sizes – in excess of 200 mg – need to be chemically processed to isolate enough molybdenum in order to allow sufficiently high‐precision isotope analyses using double‐spike MC‐ICP‐MS techniques. Established methods are either unable to process such large amounts of silicate material or require several distinct chemical processing steps, making the analyses very time‐consuming. Here, we present a new and efficient single‐pass chromatographic exchange technique for the chemical isolation of molybdenum from silicate and metal matrices. To test our new method, we analysed USGS reference materials BHVO‐2 and BIR‐1. Our new data are consistent with those derived from more involved and time‐consuming methods for these two reference materials previously published. We also provide the first molybdenum isotope data for USGS reference materials AGV‐2, the GSJ reference material JB‐2 as well as metal NIST SRM 361.     

Do 2-amino-3,8-dimethylimidazo[4,5-f] quinoxaline data support the conclusion of threshold carcinogenic effects?

The objectives of this paper are to (1) reexamine the data that were used to support the conclusion of a threshold effect for 2-amino-3,8-dimethylimidazo[4,5-f] quinoxaline (MeIQx)-induced initiation and carcinogenicity at low doses in the rat liver, and (2) discuss issues and uncertainties about assessing cancer risk at low doses. Our analysis is part of an effort to understand proper interpretation and modeling of data related to cancer mechanisms and is not an effort to develop a risk assessment for this compound. The data reanalysis presented herein shows that the low-dose initiation activity of MeIQx, which can be found in cooked meat, cannot be dismissed. It is argued that the threshold effect for carcinogenic agents cannot be determined by statistical non-significance alone; more relevant biological information is required. A biologically motivated procedure is proposed for data analyses. The concept and procedure that are appropriate for analyzing MeIQx data are equally applicable to other compounds with comparable data. The ideas and approaches in this presentation are those of the authors and do not necessarily represent the positions or policies of the USEPA.     

Water use strategies of two co‐occurring tree species in a semi‐arid karst environment

The flow of precipitation from the surface through to groundwater in karst systems is a complex process involving storage in the unsaturated zone and diffuse and preferential recharge pathways. The processes associated with this behaviour are not well understood, despite the prevalence of karst aquifers being used as freshwater supplies. As a result, uncertainty regarding the ecohydrological processes in this geological setting remains large. In response to the need to better understand the impact of woody vegetation on groundwater recharge, annual evapotranspiration (ET) rates and tree water sources were measured for two years above a shallow, fresh karst aquifer. Water use strategies of the co‐occurring Eucalyptus diversifolia subsp. diversifolia Bonpl. and Allocasuarina verticillata (Lam.) L. Johnson were investigated using a monthly water balance approach, in conjunction with measurement of the stable isotopes of water, leaf water potentials and soil matric potentials. The results suggest that it is unlikely groundwater resources are required to sustain tree transpiration, despite its shallow proximity to the soil surface, and that similarities exist between ET losses and the estimated long‐term average rainfall for this area. Irrespective of stand and morphological differences, E. diversifolia and A. verticillata ET rates showed remarkable convergence, demonstrating the ability of these co‐occurring species to maximise their use of the available precipitation, which avoids the requirement to differentiate between these species when estimating ET at a landscape scale. We conclude that the water holding capacity of porous geological substrates, such as those associated with karst systems, will play an important role in equilibrating annual rainfall variability and should be considered when assessing ecohydrological links associated with karst systems. Copyright © 2013 John Wiley & Sons, Ltd.     

Millennial-scale variability in Southern Hemisphere westerly wind activity over the last 5000 years in SW Patagonia

Here we report results from a high-resolution palynological record and stratigraphic/geochronologic data related to a Neoglacial event in Torres del Paine National Park, southern Chile (51°S, 71°W), to investigate climatic variations in Southwest Patagonia during the last 5000 years. The record reveals a stepwise expansion of Nothofagus-dominated woodlands and forests with discrete pulses at 4400, 2900, 1300, and 570 cal yr BP. Superimposed upon this trend we identify a relative opening of the woodlands between 4100–2900 and 2300–1300 cal yr BP. Closed-canopy forests dominated the landscape between 570–60 cal yr BP, followed by a rapid decline at the end of the 19th century that coincided with intense fire activity and the appearance of Rumex cf. acetocella, an exotic species introduced by European settlers. We interpret these changes as variations in the intensity and/or position of the southern margin of the westerly winds, which culminated with a net eastward shift of the forest–steppe ecotone during the Little Ice Age. We propose that millennial-scale changes in either the latitudinal position and/or the overall strength of the southern westerlies may be responsible for vegetation changes, fire occurrence, and the dynamic behavior of Patagonian glaciers during the last 5000 years. Because the modern maximum in near-surface wind velocities and precipitation is located between 48° and 50°S, we suggest that the core of the southern westerlies may have achieved this modern position ～570 years ago.     

The effects of Martian near surface conditions on the photochemistry of amino acids

In order to understand the complex multi-parameter system of destruction of organic material on the surface of Mars, step-by-step laboratory simulations of processes occurring on the surface of Mars are necessary. This paper describes the measured effects of two parameters, a CO₂ atmosphere and low temperature, on the destruction rate of amino acids when irradiated with Mars-like ultraviolet light (UV). The results show that the presence of a 7 mbar CO₂ atmosphere does not affect the destruction rate of glycine, and that cooling the sample to 210 K (average Mars temperature) lowers the destruction rate by a factor of 7. The decrease in the destruction rate of glycine by cooling the sample is thought to be predominantly caused by the slower reaction kinetics. When these results are scaled to Martian lighting conditions, cold thin films of glycine are assumed to have half-lives of 250 h under noontime peak illumination. It has been hypothesised that the absence of detectable native organic material in the Martian regolith points to the presence of oxidising agents. Some of these agents might form via the interaction of UV with compounds in the atmosphere. Water, although a trace component of Mars’ atmosphere, is suggested to be a significant source of oxidising species. However, gaseous CO₂ or adsorbed H₂O layers do not influence the photodestruction of amino acids significantly in the absence of reactive soil. Other mechanisms such as chemical processes in the Martian regolith need to be effective for rapid organic destruction.