A wavelet for predicting the time-domain response of vertically tethered systems

The response wavelets for tether tension and the displacement of a package on the end of a tether are derived from a linear, frequency-domain model of vertically tethered systems using inverse fourier transform techniques. These wavelets are convolved with a record of ship displacement to predict the instantaneous tension and displacement to an accuracy of better than 20% for a typical system. Although snap loads are non-linear and the response cannot be calculated while the tether is slack, the onset of zero tension — a precursor to snap loads — is predicted by the wavelet. Thus, extreme and potentially hazardous conditions are foreseeable with the wavelet and this information can be used in real-time to guide operations at sea.     

Etiologies, observations and reporting of estuarine finfish lesions.

Lesions in estuarine finfish are associated with a variety of organisms including parasites and bacterial, viral, and fungal infectious agents. In addition, trauma, suboptimal water quality, and other abiotic stress factors may result in the loss of homeostasis. We have observed solitary ulcerative lesions on menhaden sampled from the Chesapeake Bay, Maryland, the Pimlico River, North Carolina, and the St. Johns River, Florida. Histologically, the lesions demonstrated a marked chronic inflammatory infiltrate and granulomas in response to fungal hyphae throughout large areas of exposed necrotic muscle. Gram-negative rod-shaped bacteria were also observed in the lesions, a common finding in ulcers of aquatic organisms. Similar observations in menhaden and other species have been described previously in the literature as ulcerative mycosis, mycotic granulomatosis, red spot disease, and epizootic ulcerative syndrome. Despite the many different known causes of fish lesions, the popular press and the scientific literature have recently emphasized Pfiesteria piscicida and other Pfiesteria-like dinoflagellates (and their bioactive compounds) as the primary causative agent for finfish lesions, particularly mycotic granulomatous ulcers in Atlantic menhaden. While some laboratory data suggest that Pfiesteria may play a role in field-observed lesions, much more cause-and-effect evidence is needed to determine the importance of other risk factors, both alone or and in combination with Pfiesteria. In order to better understand the etiology of lesion initiation and progression in estuarine finfish, accurate assessments of environmental conditions collected on appropriate temporal and spatial scales, and fish morphological indicators consistent with gross and histological pathologic terminology, should be used for reporting fish lesion observations and kills. Further, this outlook will help to avoid bias and may foster a broader perspective for examining the health of estuarine systems in general.     

Interpreting What is Rural and Urban for Western U.S. Counties

The paper examines how rural and urban are interpreted and applied to counties in eleven states in the western United States. After reviewing various conceptual approaches, we turn to a three‐part analysis of county commissioners' perceptions and census data to identify characteristics associated with urban‐ness and rurality. The analysis involves comparing qualitative and quantitative survey and interview data, using a multiple regression analysis to correlate census variables with commissioners' perceptions of their home counties, and using cluster analysis techniques on census variables to identify patterns and unevenness in rurality and urbanness. Three characteristics mentioned by the widest range of commissioners and found to be statistically significant in the regression analysis were population concentration, total population, and the agricultural land base. Population concentration, in particular, was identified most frequently by interviewees as the single most important variable in characterizing an urban county and had the most meaningful contribution to predicting commissioners' perceptions of their home counties in the regression analysis. The cluster analysis identified five county types: largest urban centers, growing regional hubs, high growth rural, dispersed rural, and stable rural agriculture. These county types were widely distributed, reflecting the spatial unevenness of macroscale processes operating across eleven western states.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

The development and application of a mass balance model for mercury (total,elemental and methyl) using data from a remote lake (Big Dam West,Nova Scotia,Canada) and the multi-species multiplier method

Big Dam West, located in Kejimkujik Park, Nova Scotia, Canada, is a remote lake with elevated Hg concentrations in fish due in part to low pH and high dissolved organic carbon (DOC) concentrations. These features reflect the poor buffering capacity of peat lands in the flat drainage basin. To address the multiple species of Hg, a model was developed by coupling the “multiplier method” for multi-species chemicals with average concentration ratios to the Quantitative Water Air Sediment Interaction (QWASI) model. Elemental Hg was the “key species” modeled. Total Hg fluxes and concentrations were computed using concentration ratios. Many of the concentrations and Hg flux processes within the Big Dam West catchment had been previously measured with concentration ratios that were either computed or taken from the literature when measured data were not available. Measured values for total Hg concentration in each compartment (air, water, sediment) and Hg fluxes (e.g., precipitation, sediment deposition) enable verification of model concentration and flux estimates for total Hg in each environmental compartment. The model was also run with and without the inclusion of upward Hg fluxes from the underlying sediment to determine the significance of this controversial flux. The Hg QWASI model presented in this paper could be a valuable screening tool, especially for remote lakes, due to its ability to provide reasonable Hg estimates with a limited amount of data (water inflow rate, suspended particulate matter, sediment deposition velocity, and concentration of Hg in atmosphere and inflow water).     

Pairing paleolimnological inference models with mechanistic water column models enhances assessment of lake water quality

Reconciliation of paleolimnology inference models with hindcasts from mechanistic water column models aided the reconstruction of past relationships for total phosphorus/dissolved oxygen and acid neutralizing capacity/pH in highly polluted lake ecosystems in New York State. Pre-disturbance Onondaga Lake, Syracuse, NY, was shown to have experienced seasonal hypolimnetic anoxia even under oligotrophic (<10 ug l^?1) phosphorus levels. In the Adirondack Mountains of New York State the paired modeling confirmed that, while many lakes have the potential to eventually recover from acidification by atmospheric deposition, approximately 30% likely experienced naturally acidic conditions (pH < 6) prior to increases in industrial emissions. Comparison between the model results illuminated areas of individual model inadequacy, improved understanding of lake ecology, and increased confidence in the ability of predictive water column models to accurately develop restoration scenarios representing improved conditions. The work presented here is the first such comparison modeling for total phosphorus, dissolved oxygen, and acid neutralizing capacity. The technique remains to be more widely applied geographically and extended to less heavily stressed lake systems. Because a fossil inference and mechanistic hindcast should independently lead to similar results, comparison modeling is a potentially powerful tool for examining past interactions between ecosystem structure and ecosystem functioning.     

Information infrastructure for Australia’s Integrated Marine Observing System

Australia’s Integrated Marine Observing System (IMOS, imos.org.au) is research infrastructure to establish an enduring observing program for Australian oceanic waters and shelf seas. The observations cover physical, biological, and chemical variables to address themes of multi-decadal ocean change, climate variability and weather extremes, boundary currents and inter-basin flows, continental shelf processes and ecosystem responses.IMOS observations are collected by national facilities based on various platform types and operated by partner institutions around the country. In this paper we describe the infrastructure and workflows developed to manage and distribute the data to the public. We highlight the existing standards and open-source software we have adopted, and the contributions we have made. To demonstrate the value of this infrastructure we provide some illustrations of use and uptake.All IMOS data are freely and openly available to the public via the Ocean Portal (https://imos.aodn.org.au). All IMOS-developed software is open-source and accessible at https://github.com/aodn.     

Voice Under Scrutiny: Feminist Methods,Anticolonial Responses,and New Methodological Tools

“Giving voice” to participants has been an important element of qualitative feminist research projects in geography. In this article, I explore scholarship that has questioned qualitative research's reliance on voice, arguing that implicit connections between voice, authenticity, and empowerment are beginning to be unpacked, particularly by scholars engaged in anticolonial work. I draw on anticolonial scholarship to build on and extend feminist debates centered on voice and participation. Feminist attention to voice must be situated within the colonial frameworks and histories of social science research. Scholarship focused on ongoing settler colonial relationships highlights methods both for cautiously proceeding with and consciously refusing incorporating voice within qualitative research. I draw on anticolonial approaches to frame research decisions, voice, and the ethical and methodological dilemmas of its use.     

Tectonic significance of syn-rift sediment packages across the Gabon-Cabinda continental margin

The tectonic development of a continental margin is recorded in the stratigraphic successions preserved along and across the margin in terms of stratal relationships (e.g., onlap, downlap, truncation), lithofacies, biostratigraphy, and paleo-water depths. By using these observations coupled to a kinematic and flexural model for the deformation of the lithosphere, we have elucidated the tectonic significance of the preserved stratigraphy that comprises the Gabon-Cabinda margin of west Africa. Two hinge zones, an Eastern and Atlantic, formed along the Gabon-Cabinda margin in response to three discrete extensional events occuring from Berriasian to Aptian time. The Eastern hinge zone demarcates the eastern limit of a broadly distributed Berriasian extension that resulted in the formation of deep anoxic, lacustrine systems as evidenced by the silts and shales of the Sialivakou and lower Djeno Formations and the regressive packages of the upper Djeno Formation. Approximately 1.5 to 2 km of asymmetric footwall uplift was induced across the Eastern hinge zone in response to the mechanical unloading of the lithosphere during this first phase of rifting. In contrast, the Atlantic hinge, located approximately 90 km west of the Eastern hinge, marks the eastern limit of a second phase of extension that began in the Hauterivian. Footwall uplift and rotation exposed earlier syn-rift and pre-rift sediments to at least wavebase causing varying amounts of erosional truncation across the Atlantic hinge zone along much of the Gabon-Cabinda margins. We interpret the thickness variations of reworked clastic sediment of this age (e.g. the Melania Formation) between the hinge zones as indicative of variations in the degree of uplift and erosional truncation of the Atlantic hinge. For example, the absence of Melania Formation across the Congo margin implies that uplift of the Atlantic hinge was relatively minor compared to that across the Cabinda and Gabon margins, the latter being characterized by significant thicknesses of Melania Formation (or equivalent). Material eroded from the Cabinda and Gabon Atlantic hinge zone may in part account for the thick wedge of sediment deposited seaward of the Gabon-Cabinda Atlantic hinge (the Erva Formation). Our modelling suggests that this wedge of reworked elastics represents deposition by along-axis gravity flows within a deep water (≈2 km) environment. A third and final phase of extension in the late Barremian-early Aptian was responsible for breaching the continental lithosphere to form the ocean/continent boundary and thus the installation of open marine conditions. Elsewhere, the environments will tend to be marginal marine to brackish, depending on the efficiency of the Atlantic hinge zone to act as a barrier to marine enchroachment. This third rift phase reactivated both the Eastern and Atlantic hinge0zones thereby creating accomodation for the Marnes Noires Formation (and equivalent) source rock deposition between the hinges and the Falcão source rock equivalent seaward of the Atlantic hinge. Two possible scenarios exist for the lateral distribution of the Marnes Noires Formation. If the reactivated rift flank topography across the Atlantic hinge was significant, then sedimentation would be restricted between the hinge zones within discrete lacustrine settings (e.g., Congo margin). Alternatively, if hinge zone uplift was relatively minor, then a coral-rimmed archipelago may have developed parallel to the margin with restricted communication across the Atlantic hinge zone (e.g., Cabinda margin). In this latter scenario, dilution of the Marnes Noires source rocks by terrigenous input from the eroding Atlantic hinge zone should be relatively minor thereby enhancing source rock quality. Furthermore, potential marine upwelling outboard of the Atlantic hinge zone is likely the cause for the production and accumulation of organic-rich material associated with the Falcão source rock of the Kwanza basin. By late Aptian time, the remaining accomodation between the hinge zones was partially filled by across- and along-axis prograding deltaic systems of the Argilles Vertes and Tchibota Formations. The progradation and interaction of the Argilles Vertes depositional lobes resulted in the formation of residual paleo-relief. Subsequent marine incursions and flooding of this paleo-relief led to the development of basal conglomerates (the Chela ‘lag’ unconformity) grading upward into fine-grained sands and evaporites. Consequently, an inverse relationship should exist betweeb evaporite thickness (in particular, the lower members) and the thickness of the underlying Argilles Vertes and Tchibota Formations. Variations in Loeme evaporite thickness is a consequence of stratigraphic and structural control with salt instability influencing local variability.Our modelling suggests the occurrence of two distinct evaporite sequences on the Congo margin, an earlier evaporite deposited seaward (west) of the Atlantic hinge during the second and third rift phases and the late Aptian Loeme Formation deposited between the hinge zones. An evaporite sequence seaward of the Atlantic hinge is inferred on the basis of extensive diapirs and salt tectonic structures observed in seismic data. In order to match the distribution and thickness of the observed post-salt stratigraphy across the basin, however, we require large paleowater depths west of the Atlantic hinge during the later Aptian. The existence of large paleowater depths precludes the formation of thick evaporite sequences within the outer basin. Consequently, we propose that the evaporites seaward of the Atlantic hinge were formed during the syn-rift development of the margin and are not contemporaneous with the post-rift Loeme salts deposited between the hinge zones. This double salt hypothesis is consistent with observations from the conjugate Brazilian margin.