DOAS observations of formaldehyde and its impact on the HO<Subscript>x</Subscript> balance in the tropical Atlantic marine boundary layer

Measurements of formaldehyde (HCHO) were made at the Cape Verde Atmospheric Observatory between November 2006 and June 2007 using the Long-Path Differential Optical Absorption Spectroscopy (LP-DOAS) technique. Observations show that typical HCHO mixing ratios ranged between 350 and 550 pptv (with typical 2-σ uncertainties of ~110 pptv), with several events of high HCHO, the maximum being 1,885?±?149 pptv. The observations indicate a lack of strong seasonal or diurnal variations, within the uncertainty of the measurements. A box model is employed to test whether the observations can be explained using known hydrocarbon photochemistry; the model replicates well the typical diurnal profile and monthly mean values. The model results indicate that on average 20% of HO₂ production and 10% of OH destruction can be attributed to the mean HCHO levels, suggesting that even at these low average mixing ratios HCHO plays an important role in determining the HO_x (HO₂+OH) balance of the remote marine boundary layer.     

Effects of temperature and chemical formulation on the acute toxicity of pentachlorophenol to Simocephalus vetulus (Schoedler, 1858) (Crustacea: Cladocera)

Abstract

The influence of temperature on the acute toxicity of a technical formulation (86%) and pure formulation (99%) of pentachlorophenol (PCP) to less than 24‐h‐old Simocephalus vetulus neonates was determined with 48‐h static toxicity tests. The technical grade PCP was significantly more toxic to S. vetulus than the pure PCP (P < 0.05). Sensitivity of S. vetulus to technical PCP also significantly increased with temperature (P < 0.05), but a significant temperature effect was not found with the pure PCP. The mean 48‐h LC₅₀ values for neonates exposed to technical PCP were 140 and 199 μg l^?1 at 22°C and 16°C, respectively, and for those exposed to pure PCP were 262 and 304 μg l^?1, respectively.     

Variation in sunscreen compounds (mycosporine‐like amino acids) for marine species along a gradient of ultraviolet radiation transmission within doubtful sound,New Zealand

We examined the response of four species of New Zealand marine algae (Ecklonia radiata, Apophlaea lyallii, Rhodymenia spp., Ulva lactuca) and a sea urchin (Evechinus chloroticus) to spatial variation in ultraviolet radiation (UV‐R) by examining the concentration of UV‐R absorbing compounds known as mycosporine‐like amino acids (MAAs). The purpose was to understand how, and the degree to which, local marine species could potentially respond to any future increases in incident UV‐R in the New Zealand marine environment. The research was undertaken in Doubtful Sound, where we observed a gradient of water column UV‐R transmission along the 40 km length of the fiord. We examined spatial differences in MAAs along the UV‐B gradient in the macrophytes and temporal changes in MAAs in sea urchin gonads. Among the algae, thallus MAA concentrations (nmol mg^–1 protein) ranged from 12.5 to 87.8 in E. radiata, from 433.1 to 1446.4 in A. lyallii, 12.7 to 103.4 in Rhodymenia spp., but were not detected in U. lactuca. For E. chloroticus, gonadal MAA concentrations ranged from 83.9 to 224.3 nmol mg^–1 protein spatially, and over the year from 1.85 to 14.12 nmol mg^–1 dry weight (DW) depending on site and gametogenic cycle. Laboratory manipulations indicated that concentrations of MAAs in E. chloroticus gonads and eggs are influenced by diet. MAA concentration could be correlated with UV‐B intensities in two of the algal species. E. chloroticus MAA concentrations could also be correlated with UV‐B transmission, which we concluded was a reflection of the greater ingestion and accumulation of MAA‐rich macrophytes at those sites where higher ambient UV‐R induced greater MAA concentrations to occur in the algae. Given this, we suggest that one response of marine species to increases in UV‐B would be an increase in the synthesis and/or accumulation of MAAs for photoautotrophs and a dietary accumulation of those MAAs in E. chloroticus, an important herbivore in this system.     

Methodology for comparing two carrier phase tracking techniques

The carrier phase tracking loop is the primary focus of the current work. In particular, two carrier phase tracking techniques are compared, the standard phase tracking loop, i.e., the phase lock loop (PLL), and the extended Kalman filter (EKF) tracking loop. In order to compare these two different techniques and taking into consideration the different models adopted in each, it is important to bring them to one common ground. In order to accomplish this, the equivalent PLL for a given EKF has to be determined in terms of steady-state response to both thermal noise and signal dynamics. A novel method for experimentally calculating the equivalent bandwidth of the EKF is presented and used to evaluate the performance of the equivalent PLL. Results are shown for both the L1 and L5 signals. Even though the two loops are designed to track equivalent dynamics and to have equivalent carrier phase standard deviations, the EKF outperforms the equivalent PLL in terms of both the transient response and sensitivity.     

Priorities in policy and management when existing biodiversity stressors interact with climate-change

There are three key drivers of the biodiversity crisis: (1) the well known existing threats to biodiversity such as habitat loss, invasive pest species and resource exploitation; (2) direct effects of climate-change, such as on coastal and high elevation communities and coral reefs; and (3) the interaction between existing threats and climate-change. The third driver is set to accelerate the biodiversity crisis beyond the impacts of the first and second drivers in isolation. In this review we assess these interactions, and suggest the policy and management responses that are needed to minimise their impacts. Renewed management and policy action that address known threats to biodiversity could substantially diminish the impacts of future climate-change. An appropriate response to climate-change will include a reduction of land clearing, increased habitat restoration using indigenous species, a reduction in the number of exotic species transported between continents or between major regions of endemism, and a reduction in the unsustainable use of natural resources. Achieving these measures requires substantial reform of international, national and regional policy, and the development of new or more effective alliances between scientists, government agencies, non-government organisations and land managers. Furthermore, new management practices and policy are needed that consider shifts in the geographic range of species, and that are responsive to new information acquired from improved research and monitoring programs. The interactions of climate-change with existing threats to biodiversity have the potential to drive many species to extinction, but there is much that can be done now to reduce this risk.     

Calculations on the energetics of water dissolution in wadsleyite

Physics and Chemistry of Minerals - Computer simulation techniques are used to investigate the energetics and mechanisms of dissolution of water in the upper mantle mineral wadsleyite (β(Mg,...     

Stratigraphic and structural expression of the lateral growth of thrust fault-propagation folds: results and implications from kinematic modelling

In order to better understand the development of thrust fault‐related folds, a 3D forward numerical model has been developed to investigate the effects that lateral slip distribution and propagation rate have on the fold geometry of pre‐ and syn‐tectonic strata. We consider a fault‐propagation fold in which the fault propagates upwards from a basal decollement and along‐strike normal to transport direction. Over a 1 Ma runtime, the fault reaches a maximum length of 10 km and accumulates a maximum displacement of 1 km. Deformation ahead of the propagating fault tip is modelled using trishear kinematics while backlimb deformation is modelled using kink‐band migration. The applicability of two different lateral slip distributions, namely linear‐taper and block‐taper, are firstly tested using a constant lateral propagation rate. A block‐taper slip distribution replicates the geometry of natural fold‐thrusts better and is then used to test the sensitivity of thrust‐fold morphology to varied propagation rates in a set of fault‐propagation folds that have identical final displacement to length (D_max/L_max) ratios. Two stratigraphic settings are considered: a model in which background sedimentation rates are high and no topography develops, and a model in which a topographic high develops above the growing fold and local erosion, transport and deposition occur. If the lateral propagation rate is rapid (or geologically instantaneous), the fault tips quickly become pinned as the fault reaches its maximum lateral extent (10 km), after which displacement accumulates. In both stratigraphic settings, this leads to strike‐parallel rotation of the syn‐tectonic strata near the fault tips; high sedimentation rates relative to rates of uplift result in along‐strike thinning over the structural high, while low sedimentation rates result in pinchout against it. In contrast, slower lateral propagation rates (i.e. up to one order of magnitude greater than slip rate) lead to the development of along‐strike growth triangles when sedimentation rates are high, whereas when sedimentation rates are low, offflap geometries result. Overall we find that the most rapid lateral propagation rates produce the most realistic geometries. In both settings, time‐equivalent units display both nongrowth and growth stratal geometries along‐strike and the transition from growth to nongrowth has the potential to delineate the time of fault/fold growth at a given location. This work highlights the importance of lateral fault‐propagation and fault tip pinning on fault and fold growth in three dimensions and the complex syn‐tectonic geometries that can result.     

Wastage of the Klutlan ice-cored moraines,Yukon Territory,Canada

A series of ice-cored Neoglacial moraines at the terminus of the Klutlan Glacier covers an area of 90 km². Studies were made to determine empirically how long ice persisted in the Klutlan moraines and to develop models that can accurately predict wastage rates under current climatic conditions. A meltout curve based on climatological data reflects the sum of three melting processes: surficial melting, melting by lake water, and melting by geothermal heat. About 950 yr are required to melt 180 m of ice with a debris concentration of 1%, or about 1200 yr for a 1.5% debris load. Another meltout curve, based on seismic data, suggests total meltout in about 875 yr. When all geologic factors are considered, the empirical meltout curve is remarkably similar to that derived by considering the major heat-flux parameters. Meltout rates can be predicted if (1) the fundamental climatic parameters can be ascertained, and (2) the sediment concentration in the ice is known.     

A computer simulation study of (OH) defects in olivine

Recent experiments (Miller et al. 1987; Bell and Rossman 1992; Bai and Kohlstedt 1992) have shown that olivine, the dominant mineral in the Earth's upper mantle, can contain substantial amounts of water in the form of OH. There is uncertainty, however, as to the mechanisms by which water dissolves into the mineral structure and as to the site it occupies in the host lattice. We have therefore used atomistic computer simulation techniques based on the Born model of solids, to investigate the structures and energies of OH defects in olivine. Our calculations suggest that the most favourable route for incorporation of OH into olivine involves reactions with water accompanied by the reduction of ferric iron for which we obtain a solution energy of 0.46 eV. We propose therefore that the OH content will be largely controlled by the concentration of Fe³⁺.     

Celebrating a Nation’s heritage on music stamps: Constructing an international community

Stamps convey important visible messages about a state’s heritage and worldview. They are images or official visible products seen by those living within the state’s borders and those beyond. They also can be considered as “imagined communities,” as like festivals, holidays, or WWW pages, they represent attachments to and images of place. We investigate stamps as elements of visual culture by examining salient music themes and topics from several countries and then focus on the music stamps of Brazil, Hungary, and Senegal. In each case, we examine the number and variety of issues, the importance they place on musical instruments, composers and performers, and musical events.