‘Copernicus’ observations of extragalactic X-ray sources

The MSSL X-ray detectors onCopernicus have been used to study a number of extragalactic objects. At least three classes of unresolved sources are found and we suggest that accretion may be the dominant mechanism. The mass of the accreting object then determines the X-ray emission properties.Paper presented at the COSPAR Symposium on Fast Transients in X- and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

ADAPTATION TO GLOBAL ENVIRONMENTAL CHANGE *

Atmospheric carbon dioxide is expected to double by A.D. 2050, raising global temperatures 2 to 3°C. A model for climatic deviations is presented, based upon paleoclimatic experience 5,000 to 8,000 years ago, when midlatitude temperatures were 1.5 to 2.5°C higher. The economic prognosis includes a United States barely able to meet its own agricultural needs and a substantial overall reduction of world food supplies. The revolutionary implications for contemporary sociopolitical alignments suggest an urgent need for long-range planning and more, historically oriented research.     

The record of impact cratering on the great volcanic shields of the Tharsis region of Mars

Mariner 9 images of the four great volcanic shields of the Tharsis region of Mars show many circular craters ranging in diameter from 100mm to 20 km. Previous attempts to date the volcanoes from their apparent impact crater densities yielded a range of results. The principal difficulty is sorting volcanic from impact craters for diameters $\text{?1}\text{km}$. Many of the observed craters are aligned in prominent linear and concentric patterns suggestive of volcanic origin. In this paper an attempt is made to date areas of shield surface, covered with high resolution images using only scattered small (?1 km) craters of probable impact origin. Craters of apparent volcanic origin are systematically excluded from the dating counts.The common measure of age, deduced for all surfaces studied, is a calculated “crater age” F′ defined as the number of craters equal to or larger than 1 km in diameter per 10⁶km². The conclusions reached from comparing surface ages and their geological settings are: (1) Lava flow terrain surfaces with ages, F′, from 180 to 490 are seen on the four great volcanoes. Summit surfaces of similar ages, F′ = 360 to 420, occur on the rims of calderas of Arsia Mons, Pavonis Mons, and Olympus Mons. The summit of Ascraeus Mons is possibly younger; F′ is calculated to be 180 for the single area which could be dated. (2) One considerably younger surface, F′ < 110, is seen on the floor of Arsia Mon's summit caldera. (3) Nearly crater free lava flow terrain surfaces seen on Olympus Mons are estimated to be less than half the age of a summit surface. The summit caldera floor is similarly young. (4) The pattern of surface ages on the volcanoes suggests that their eruption patterns are similar to those of Hawaiian basaltic shields. The youngest surfaces seem concentrated on the mid-to-lower flanks and within the summit calderas. (5) The presently imaged sample of shield surface, though incomplete, clearly shows a broad range of ages on three volcanoes—Olympus, Arsia, and Pavonis Mons.Estimated absolute ages of impact dated surfaces are obtained from two previously published estimates of the history of flux of impacting bodies on Mars. The estimated ranges of age for the observed crater populations are 0.5 to 1.2b.y. and 0.07 to 0.2b.y. Areas which are almost certainly younger, less than 0.5 or 0.07b.y., are also seen. The spans of surface age derived for the great shields are minimum estimates of their active lifetimes, apparently very long compared to those of terrestrial volcanoes.     

Zur Vergleichbarkeit der magmatischen Gesteine aus dem Adamello mit den Tonalitgraniten aus den Hohen Tauern

Ohne ZusammenfassungMit 15 Textabbildungen     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Remineralization Ratios in the Subtropical North Pacific Gyre

Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/C_org - O₂ = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/C_org/–O₂ = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as ₁₃₅H₂₈₀O₁₀₅N₁₃P or C₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄). Oxidation of this formula results inC₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄) + 170O₂ 135CO₂ + 132H₂O + 13NO₃ ^- + H₂PO₄ ^- + 14H⁺.For comparison, remineralization using Redfield's formula gives:(CH₂O)₁₀₆(NH₃)₁₆(H₃PO₄) + 138O₂ 106CO₂ + 122H₂O + 16NO₃ ^-+ H₂PO₄ ^- + 17H⁺     

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.     

The future of industrial cities and regions in central and eastern Europe

Economic transition in central and eastern Europe (CEE) has had a particularly strong impact on industrial cities and regions. Following their economic collapse, most of them are now confronted with serious problems such as high unemployment and vast ecological damage. The paper presents findings from a pan European research project that investigated the problems of these cities and regions as well as the strategies being adopted to cope with structural change. It examines the differences in approaches and addresses the question whether existing EU policy is suitable for supporting the redevelopment of old industrial cities and regions in CEE countries. The paper concludes with recommendations for future directions in policy making.     

The behavior of natural and anthropogenic osmium in the Hudson River-Long Island Sound estuarine system

The extent to which riverine Os is trapped in a temperate estuary was the aim of this study. The behavior of Os through the Hudson River, East River and the Long Island Sound (LIS) system is addressed using both natural Os and anthropogenically mobilized Os. The Os concentration ([Os]) and isotopic composition (¹⁸⁷Os/¹⁸⁸Os) of the Mid-Atlantic Bight as inferred from the analysis of a water sample of 31‰ salinity (S) at Vineyard Sound, MA are 46 fM and 1.070, respectively. In comparison, the Hudson River at Newburgh, NY has [Os] = 68 fM and ¹⁸⁷Os/¹⁸⁸Os = 1.265. The Os concentration of the East River at the Whitestone Bridge is 51 fM and remains essentially constant proceeding eastward in the LIS despite the increase of salinity from 20‰ towards the higher value of the Mid-Atlantic Bight. The ¹⁸⁷Os/¹⁸⁸Os ratio of water at Whitestone Bridge is 0.945 and increases eastward through the Sound to 0.979 at 7 km and then to 1.019 at 39.6 km. The behavior of Os through LIS appears to be conservative at S > 20‰. On the basis of Os concentration and isotopic composition we infer that anthropogenic Os is being added to the East River through sewers with the likely isotopic ratio of ∼0.13 and that about 24% of riverine Os must be removed at S ? 20‰. There is a net transport of about 0.4-1 mole of anthropogenic Os per year from the East River into the LIS. The residence time of Os in the ocean at present must be about 39,000 years, unless an independent source of supply of Os can be identified.