Anthropogenic contributions to atmospheric Hg, Pb and As accumulation recorded by peat cores from southern Greenland and Denmark dated using the C “bomb pulse curve”

Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using ¹⁴C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m²/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m²/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m²/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m²/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m²/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m²/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m²/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (²⁰⁶Pb/²⁰⁷Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for ²⁰⁶Pb/²⁰⁷Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Progradational and backstepping shoreface deposits in the Ladinian to Early Norian Snadd Formation of the Barents Sea

Shoreface sandstone deposits within the Early Carnian part of the Snadd Formation of the Norwegian Barents Sea can be traced for hundreds of kilometres in the depositional strike direction and for tens of kilometres in the depositional‐dip direction. This study uses three‐dimensional seismic attribute mapping and two‐dimensional regional seismic profiles to visualize the seismic facies of these shoreface deposits and to map their internal stratigraphic architecture at a regional scale. The shoreface deposits are generally elongate but show variable width from north‐east to south‐west, which corresponds to a sediment source in the northern part of the basin and a southward decrease in longshore sediment transport. The Snadd Formation presents an example of how large‐scale progradational shoreface deposits develop. The linear nature of its shoreface deposits contrasts with more irregular, cuspate wave‐dominated deltaic shorelines that contain river outlets, and instead implies longshore drift as the main sediment source. In map view, discrete sets of linear features bounded by truncation surfaces scale directly to beach ridge sets in modern counterparts. The shoreface deposits studied here are characteristic in terms of scale and basin‐wide continuity, and offer insight into the contrast between shallow marine deposition under stable Triassic Greenhouse and fluctuating Holocene Icehouse climates. Findings presented herein are also important for hydrocarbon exploration in the Barents Sea, because they describe a hitherto poorly understood reservoir play in the Triassic interval, wherein the most prominent reservoir plays have so far been considered to be found in channelized deposits in net‐progradational delta‐plain strata that form the topsets to shelf‐edge clinoforms. The documented presence of widespread wave‐dominated shoreface deposits also has implications for how the relative importance of different sedimentary processes is considered within the basin during this period.     

Bitumen Prices and Structural Changes in North American Crude Oil Markets

In an earlier report, changes in bitumen prices at Hardesty, Alberta, Canada, were modeled as the responses to changes in monthly prices of Hardesty light/medium crude oil for the period 2000–2006 with a simple error correction econometric model. This note re-examines that price relationship for the period 2009–2014. Over the period 2006–2014, there was also rapid growth in North American light oil production from low-permeability carbonate, sandstone, and shale reservoirs. During that period, Canadian raw bitumen production grew by more than 12% per year and there was significant geographical diversification in its markets. Results of the statistical analysis showed that the change in the dynamic relationships between bitumen prices and Hardesty light oil prices probably reflected, in part, the maturation of bitumen markets and closer integration with North American light oil markets. The analysis also examines the dynamic relationships between bitumen prices and West Texas Intermediate and Brent international benchmark crude oil prices. Ideally, if bitumen prices are found to be closely related to a widely traded benchmark crude oil, the benchmark crude oil price forecasts could be used as a basis for predicting bitumen prices. However, neither of international benchmark crude oils tested had high explanatory power.     

Outdoor recreation monitoring in coastal and marine areas – an overview of Nordic experiences and knowledge

This paper involves a collection and communication of important knowledge about and experiences with outdoor recreation monitoring in Nordic coastal and marine areas. This is a topic that so far has received little attention, especially among researchers and practitioners working with outdoor recreation monitoring in Nordic coastal and marine areas, who are in need of knowledge on the topic in order to advance monitoring activities and procedures. To remedy this situation, the purpose of this paper is to provide a knowledge base by listing and describing central literature contributions with important insight into outdoor recreation monitoring in Nordic coastal and marine areas. More specifically, this includes information about: (a) where important knowledge about outdoor recreation monitoring in Nordic coastal and marine areas can be found, (b) who the main contributors are and (c) what monitoring knowledge that has been reported so far. The paper also examines what tasks lie ahead for researchers and area managers in order to improve knowledge about outdoor recreation monitoring in Nordic coastal and marine areas. The paper is a central contribution and addition to manuals on outdoor recreation monitoring that are currently available in the Nordic countries.     

Vibrant Centers as Locations for High-Growth Firms: An Analysis of Thirty U.S. Metropolitan Areas

What kinds of places have high entrepreneurial activities? There has been an emerging body of studies about so-called entrepreneurship ecosystems, but virtually all of the past studies have examined this question from a perspective of which metropolitan areas have higher entrepreneurial activities. In this article, we examine the intrametropolitan scale at the Census tract level. By analyzing thirty metropolitan areas to extend external validity, we demonstrate the concentration of high-growth firms in specific employment nodes in both urban and suburban parts of each metropolitan area. Significant correlations exist between place-based vibrancy indicators and high-growth firm concentrations.     

The Natural Resource Management Planning Portal: Perspectives for NRM Planning and Reporting

Natural Resource Management (NRM) is often conducted as a partnership between government and citizens. In Australia, government agencies formulate policy and fund implementation that may be delivered on-ground by community groups (such as Landcare). Since the late 1980s, over AUS$8b of Commonwealth investment has been made in NRM. However, quantitative evidence of environmental improvements is lacking. The NRM Planning Portal has been developed to (1) provide an online spatial information system for sharing Landcare and agency data; and (2) to facilitate NRM priority setting at local and regional planning scales. While the project successfully federates Landcare NRM activity data, challenges included (1) unstructured, non-standardized data, meaning that quantitative reporting against strategic objectives is not currently possible, and (2) a lack of common understanding about the value proposition for adopting the portal approach. Demonstrating the benefit of technology adoption is a key lesson for digital NRM planning.     

Transitional impact craters on the Moon: Insight into the effect of target lithology on the impact cratering process

We studied a data set of 28 well‐preserved lunar craters in the transitional (simple‐to‐complex) regime with the aim of investigating the underlying cause(s) for morphological differences of these craters in mare versus highland terrains. These transitional craters range from 15 to 42 km in diameter, demonstrating that the transition from simple to complex craters is not abrupt and occurs over a broad diameter range. We examined and measured the following crater attributes: depth (d), diameter (D), floor diameter (D_f), rim height (h), and wall width (w), as well as the number and onset of terraces and rock slides. The number of terraces increases with increasing crater size and, in general, mare craters possess more terraces than highland craters of the same diameter. There are also clear differences in the d/D ratio of mare versus highland craters, with transitional craters in mare targets being noticeably shallower than similarly sized highland craters. We propose that layering in mare targets is a major driver for these differences. Layering provides pre‐existing planes of weakness that facilitate crater collapse, thus explaining the overall shallower depths of mare craters and the onset of crater collapse (i.e., the transition from simple to complex crater morphology) at smaller diameters as compared to highland craters. This suggests that layering and its interplay with target strength and porosity may play a more significant role than previously considered.