四川会理天宝山矿床深部新发现铜矿与铅锌矿的成因关系探讨

天宝山矿床是川滇黔接壤铅锌矿集区内的代表性铅锌矿床之一,赋存于上震旦统灯影组白云岩中。近年来,该矿床深部发现了以铜为主的矿化,甚至形成铜矿体。目前,对铜矿成因及其与铅锌矿的关系尚不清晰。本文报道新发现铜矿的矿物学和同位素地球化学资料,以期揭示铜矿的成矿物质来源,结合铅锌矿的相关研究,探讨铜矿形成机制及其与铅锌矿的成因关系。镜下观察和扫描电镜分析显示,铜矿石中主要金属矿物为黄铜矿和银黝铜矿,其次为方铅矿和毒砂,含少量闪锌矿和黄铁矿;铅锌矿石中闪锌矿是主要金属矿物,方铅矿和黄铁矿次之,含少量黄铜矿和深红银矿。铜矿石中闪锌矿主要呈半自形-他形粒状,与黄铜矿共生或被其包裹,方铅矿主要呈细脉状充填在黄铜矿、银黝铜矿和毒砂的裂隙中或呈他形粒状分布在这些矿物中;铅锌矿石中黄铜矿主要呈浸染状分布于闪锌矿之中。两类矿石金属矿物的组构特征,显示铜矿物与铅锌矿物具有密切的共生、穿插和包裹关系,应属同期成矿。同位素地球化学数据显示,铜矿石中黄铜矿的δ34SCDT值为3.9‰~4.2‰(均值为4.1‰,n=3),铅锌矿石闪锌矿的δ34SCDT值为3.3‰~3.9‰(均值为3.5‰,n=3),十分相近,暗示它们具有相似的S源,应均属赋矿地层海相蒸发岩中硫酸盐热化学还原作用的产物。铜矿石中黄铜矿的~(206)Pb/~(204)Pb=18.441~18.476(均值为18.461,n=3),~(207)Pb/~(204)Pb=15.731~15.751(均值为15.741,n=3),~(208)Pb/~(204)Pb=38.809~38.873(均值为38.849,n=3),μ=9.72~9.76;铅锌矿石中方铅矿的~(206)Pb/~(204)Pb=18.442~18.480(均值为18.455,n=3),~(207)Pb/~(204)Pb=15.746~15.763(均值为15.752,n=3),~(208)Pb/~(204)Pb=38.793~38.892(均值为38.840,n=3),μ=9.75~9.78。两者具有相近的Pb同位素组成且其壳源特征明显,表明它们的成矿金属来源相似,均来自上地壳,与赋矿沉积岩有关。综上,矿物学和同位素地球化学证据表明,天宝山矿床深部新发现铜矿与铅锌矿具有明显的同期共生关系和相似的成矿物质来源,是同一成矿热液体系不同阶段演化的产物。天宝山铜铅锌矿床与MVT矿床的成矿特征不同,暗示其成矿作用(环境)特殊,可能与矿床所处的地质背景有关,其成因认识对川滇黔接壤区同类型矿床深部找铜矿具有重要的指导意义。     

胶东-朝鲜半岛中生代金成矿作用

华北克拉通东部与朝鲜半岛相接,是中朝克拉通的重要组成部分。在华北克拉通东部的胶东半岛和朝鲜半岛内皆产出有不同规模的金矿床,并具有显著的地域特色。胶东半岛已发现金矿床(点)近200处,其中三山岛、焦家、新城、玲珑等为世界级金矿,它们为石英脉型和受构造控制的蚀变岩型,成矿时间主要集中在~120Ma,说明金成矿作用是在相当短的时间内,在同一成矿背景下和同一构造-岩浆-流体成矿系统下完成的。成矿流体主要来自幔源岩浆以及幔源岩浆与地壳相互作用产生的地质流体,就位环境与地壳/岩石圈在早白垩世强烈伸展构造变形有关,为克拉通破坏型金矿;与我国辽东相邻的朝鲜半岛北部平安北道等地金矿储量较大,成矿类型与特征辽东五龙金矿类似,为石英脉型矿化,也可能为早白垩世与华北克拉通岩石圈减薄、破坏相关的金矿床;朝鲜半岛南部的韩国金(银)矿床分成侏罗纪中温热液型和白垩纪浅成低温热液型两类,其中侏罗纪热液脉状金矿成矿特征虽与胶东金矿类似,但成矿时代(峰期~160Ma)有显著差异。而白垩纪浅成低温热液型金-银矿化主要发生在100~70Ma,与太平洋板块俯冲作用相关,为典型的环太平洋斑岩-次火山活动有关的浅成低温贱金属成矿系列。胶东和朝鲜半岛金矿床类型、特征及成矿时间的异同,与区域中生代地质演化及地球动力学背景密切相关。     

Underwater Navigation Based on Real-Time Simultaneous Sound Speed Profile Correction

Precise sound speed profile (SSP) information is critical when using sonar for underwater terrain navigation. Nevertheless, acquiring SSP information in real-time is difficult, especially in underwater navigation environment. To account for this problem, this paper presents an underwater navigation method that applies real-time SSP correction to the terrain measurements. The method uses a probe to measure the surface sound speed simultaneously. Meanwhile, redundancy of topographic measurement data is exploited to derive the equivalent SSP information. The acquired equivalent SSP is updated continuously with particle filter algorithm. The terrain measurements can be corrected in real-time with the equivalent SSP to improve the performance of underwater terrain navigation. By removing the impact of inaccurate SSP from the terrain measurements, the proposed method can achieve precise and robust underwater navigation result without using an underway-profiling instrument. Simulated results confirm the good performance of the proposed method.     

Iron Reduction Along an Inundation Gradient in a Tidal Sedge (<Emphasis Type="Italic">Cyperus malaccensis</Emphasis>) Marsh: the Rates,Pathways, and Contributions to Anaerobic Organic Matter Mineralization

Incubation experiments were adopted to characterize the rates and pathways of iron reduction and the contributions to anaerobic organic matter mineralization in the upper 0–5 cm of sediments along a landscape-scale inundation gradient in tidal marsh sediments in the Min River Estuary, Southeast China. Similar sediment characteristics, single-species vegetation, varied biomass and bioturbation, distinct porewater pH, redox potential, and electrical conductivity values have resulted in a unique ecogeochemical zonation along the inundation gradient. Decreases in solid-phase Fe(III) and increases in nonsulfidic Fe(II) and iron sulfide were observed in a seaward direction. Porewater Fe²⁺ was only detected in the upland area. High rates of iron reduction were observed in incubation jars, with significant accumulations of nonsulfidic Fe(II), moderate accumulations of iron sulfides, and negligible accumulations of porewater Fe²⁺. Most of the iron reduction was microbially mediated rather than coupled to reduced sulfides. Microbial iron reduction accounted for 20–89 % of the anaerobic organic matter mineralization along the inundation gradient. The rate and dominance of microbial iron reduction generally decreased in a seaward direction. The contributions of microbial iron reduction to anaerobic organic matter mineralization depended on the concentrations of bioavailable Fe(III), the spatial distribution of which was significantly related to tidal inundation. Our results clearly showed that microbial iron reduction in the upper sediments along the gradient is highly dependent on spatial scales controlled primarily by tidal inundation.     

南海西南部海盆附近中尺度涡及其水文特征

根据"东方红2"于2011年9月在南海西南部11°N~15°N、111°E~114°E海域测得的CTD资料及据此的地转流计算结果,结合南海的海流数值计算结果的对比分析,得出南海西南部海盆附近水域中尺度涡的基本分布规律及其水文特征:(1)以12°N~13°N附近宽约100km的条带作为分界,其北部是气旋式运动,南部是反气旋式运动。(2)气旋涡中心产生上升流,底层水上升,中心密度大。表层表现为低温高盐高密特征;200m层表现为低温低盐高密特征;1 000m层则表现为低温高盐高密特征。(3)在反气旋涡中心产生下降流,海水密度小。表层表现为高温低盐低密特征;200m层表现为高温高盐低密特征;1 000m层则表现为高温低盐低密特征。(4)在8~9月,上述北气旋、南反气旋的分布流态基本不变;(5)季风的影响是因素之一,而地形影响更是调查区域双涡旋流动结构的重要动力机制。     

Glacier changes in the eastern Nyainqêntanglha Range of Tibetan Plateau from 1975 to 2013

Maritime-type glaciers in the eastern Nyainqêntanglha Range, located in the southeastern part of the Tibetan Plateau, are an important water source for downstream residents and ecological systems. To better understand the variability of glaciers in this region, we used the band ratio threshold(TM3/TM5 for the Landsat TM /ETM+ and TM4/TM6 for Landsat OLI) to extract glacier outlines in ~1999 and ~2013. After that, we also generated a series of glacier boundaries and monitored glacier variations in the past 40 years with the help of the Chinese Glacier Inventory data(1975) and Landsat TM, ETM+ and OLI data. The total glacier area decreased by 37.69 ± 2.84% from 1975 to 2013. The annual percentage area change(APAC) was ~1.32% a-1 and ~1.29% a-1 in the periods 1975-1999 and 1999-2013, respectively. According to the lag theory, the reaction time is probably about 10 years and we discuss the variations of temperature and precipitation between 1965 and 2011. Temperature and precipitation increased between 1965 and 2011 at a rate of 0.34°C /10 a and 15.4 mm/10 a, respectively. Extensive meteorological data show that the glacier shrinkage rate over the period may be mainly due to increasing air temperature, while the increasing precipitation partly made up for the mass loss of glacier ice resulting from increasing temperature may also lead to the low APAC between 1999 and 2013. The lag theory suggests that glacier shrinkage may accelerate in the next 10 years. Small glaciers were more sensitive to climate change, and there was a normal distribution between glacier area and elevation. Glaciers shrank in all aspects, and south aspects diminished faster than others.     

Characteristics of deuterium excess parameters for geothermal water in Beijing

This study investigates the characteristics of geothermal water in 10 geothermal fields in Beijing. The relationships between the deuterium excess parameter (d) and temperature, depth, age of geothermal groundwater, groundwater flow field, and Eh were investigated using geothermal groundwater samples. Results showed that (1) the average d value of geothermal water is 5.4, whereas that of the groundwater in normal temperature is 6.04. The differences are induced by the oxygen isotope exchange during the water–rock interaction, which may be more easily completed in geothermal water than in cold groundwater. (2) The d value increases remarkably with the age of the geothermal groundwater. The d value increases from 11.2 to 14.6 when the age of the geothermal water is 12,760 ± 130 a and 38,960 ± 630 a, respectively. Moreover, the isotope heat exchange for composition of the hydrogen and oxygen isotopes in the geothermal groundwater proceeds sufficiently with time. (3) The d value decreases from 5.72 to 3.03 when the depth increases from 125.13 to 3221 m. Generally, in the same area, the d value decreases with depth because the temperature is increasing. (4) The d value of the groundwater gradually reduces from the northern recharge area to the southern discharge area. The average d value is 7.31 in the northern recharge area and 5.68 in the middle Beijing Depression, whereas the d value in the southern area of Fengheying is ?9.20. The larger difference in d values between the recharge and discharge areas is due to the slower velocity of underwater flow, which induces longer time for oxygen exchange. (5) The relationship between the d and Eh is complex. When Eh is <200 mV, the d value of the geothermal water decreases with the decrease in Eh. When Eh is higher than 200 mV, the d value increases slightly with the decrease in Eh. The study of the characteristics of deuterium excess parameters for geothermal water could provide a scientific isotopic evidence for assessment and exploitation measures in geothermal groundwater systems.     

Study on Longitudinal Deformation Profile of Rock Mass in a Subsea Tunnel

During tunnel excavation, the deformation of surrounding rock due to the unloading of rock mass will vary with time. However, the measured displacement of surrounding rock is only a part of the actual longitudinal deformation profile. There is a need to analyze the longitudinal deformation profile to identify the deformation state and evaluate the stability of surrounding rock mass. In the present article, the variation of pre-deformation of surrounding rock due to excavation was analyzed, and the release coefficient was obtained from the measured results. For the Qingdao subsea tunnel, the measured crown settlement of surrounding rock was analyzed using the regression analysis method, and the longitudinal deformation profile of rock mass was simulated using the numerical calculation method. Moreover, based on the conditions of the subsea tunnel, a solid-fluid coupling model test was carried out to check the reliability of the numerical calculation results. The results of the model test were consistent with the numerical calculation results.     

Soil phosphorus composition and phosphatase activities along altitudes of alpine tundra in Changbai Mountains,China

Alpine tundra ecosystems have specific vegetation and environmental conditions that may affect soil phosphorus(P) composition and phosphatase activities. However, these effects are poorly understood. This study used Na OH-EDTA extraction and solution31 P nuclear magnetic resonance(NMR) spectroscopy to determine soil P composition and phosphatase activities, including acid phosphomonoesterase(Ac P), phosphodiesterase(PD) and inorganic pyrophosphatase(IPP), in the alpine tundra of the Changbai Mountains at seven different altitudinal gradients(i.e., 2000 m, 2100 m, 2200 m, 2300 m, 2400 m, 2500 m, and 2600 m). The results show that total P(TP), organic P(OP), OP/TP, Na OH-EDTA extracted P and AcP, PD, and IPP activities over the altitude range of 2500–2600 m are significantly lower than those below 2400 m. The dominant extracted form of P is OP(73%–83%) with a large proportion of monoesters(65%–72%), whereas inorganic P is present in lower proportions(17%–27%). The activity of Ac P is significantly positively correlated with the contents of soil OP, total carbon(TC), total nitrogen(TN), and TP(P 0.05), indicating that the Ac P is a more sensitive index for responding P nutrient storage than PD and IPP. Soil properties, P composition, and phosphatase activities decrease with increased altitude and soil p H. Our results indicate that the distribution of soil P composition and phosphatase activities along altitude and Ac P may play an important role in P hydrolysis as well as have the potential to be an indicator of soil quality.