The effect of copper-treated net pens on farmed salmon (Salmo salar) and other marine organisms and sediments

Samples of Atlantic salmon (Salmo salar), saithe (Pollacius virens), blue mussel (Mytilus edulis), brown seaweed (Ascophyllum nodosum) and sediment were collected from six different fish farms. Five of the farms used net pens treated with copper-containing coatings, whereas one farm did not use copper-containing coating (this was used as a reference location). Samples of muscle, liver and gills of Atlantic salmon and saithe, blue mussel and brown seaweed were freeze dried, homogenised, wet digested and analysed for copper by flame atomic absorption spectrometry. The results showed no significant differences in copper concentrations among the samples from the different locations. The copper contents of some of the samples appeared to be in the upper part of the normal concentration range. From a nutritional point of view, the use of copper-coatings on net pens did not affect the quality of the seafood products either within, or around the net pen.     

Mutual phenomena of Jupiter's Galilean satellites 1973–74

Two series of predictions have been published for the 1973–1974 mutual phenomena of Jupiter's satellites, one (June–October, 1973) by Milbourn and Carey, and the other (February 1973–May 1974) by Brinkmann and Millis. The main purpose of this paper is to investigate some significant discrepancies between these two sets of predictions. New predictions are calculated for the period June 1973–May 1974. They agree very nearly with the predictions by Milbourn and Carey, but frequently differ by several minutes (up to 30 min when Jupiter III and IV are involved) from those by Brinkmann and Millis. Unlike the previous predictions, the new ones also give the estimated light decreases during the phenomena. The method of prediction is documented for future applications to Jupiter's and Saturn's satellites. The paper concludes with a brief discussion of the problems involved in extracting information about the positions, radii, and albedos of the satellites from observed light curves.     

Submarine debris flow impact on pipelines — Part II: Numerical analysis

Computational Fluid Dynamics (CFD) numerical analysis was employed to analyze the situations tested experimentally, as described in Part I. The methodology and results of the CFD analyses are discussed and compared with the observations made from the experiments. The numerical model performed satisfactorily with regard to obtaining the impact forces exerted on the model pipe as well as simulating the hydroplaning phenomenon and estimating slurry flow heights. The experimental results were combined with the results of the CFD analyses to develop a practical method to compute the drag force caused by a submarine debris flow impact on a pipeline. The CFD analyses provided some insight to the separated region characterization, but the attempt to analyze the vortex shedding phenomenon as observed in the experiments was unsuccessful. Additional studies are required for better understanding of both the separated region characteristics and vortex shedding.     

Caprock interaction with CO2: A laboratory study of reactivity of shale with supercritical CO2 and brine

Crushed rock from two caprock samples, a carbonate-rich shale and a clay-rich shale, were reacted with a mixture of brine and supercritical CO₂ (CO₂–brine) in a laboratory batch reactor, at different temperature and pressure conditions. The samples were cored from a proposed underground CO₂ storage site near the town of Longyearbyen in Svalbard. The reacting fluid was a mixture of 1 M NaCl solution and CO₂ (110 bar) and the water/rock ratio was 20:1. Carbon dioxide was injected into the reactors after the solution had been bubbled with N₂, in order to mimic O₂-depleted natural storage conditions. A control reaction was also run on the clay-rich shale sample, where the crushed rock was reacted with brine (CO₂-free brine) at the same experimental conditions. A total of 8 batch reaction experiments were run at temperatures ranging from 80 to 250 °C and total pressures of 110 bar (∼40 bar for the control experiment). The experiments lasted 1–5 weeks.Fluid analysis showed that the aqueous concentration of major elements (i.e. Ca, Mg, Fe, K, Al) and SiO₂ increased in all experiments. Release rates of Fe and SiO₂ were more pronounced in solutions reacted with CO₂–brine as compared to those reacted with CO₂-free brine. For samples reacted with the CO₂–brine, lower temperature reactions (80 °C) released much more Fe and SiO₂ than higher temperature reactions (150–250 °C). Analysis by SEM and XRD of reacted solids also revealed changes in mineralogical compositions. The carbonate-rich shale was more reactive at 250 °C, as revealed by the dissolution of plagioclase and clay minerals (illite and chlorite), dissolution and re-precipitation of carbonates, and the formation of smectite. Carbon dioxide was also permanently sequestered as calcite in the same sample. The clay-rich shale reacted with CO₂–brine did not show major mineralogical alteration. However, a significant amount of analcime was formed in the clay-rich shale reacted with CO₂-free brine; while no trace of analcime was observed in either of the samples reacted with CO₂–brine.     

On the potential for CO2 mineral storage in continental flood basalts – PHREEQC batch- and 1D diffusion–reaction simulations

Continental flood basalts (CFB) are considered as potential CO₂ storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO₂ point emission sources. Based on the mineral and glass composition of the Columbia River Basalt (CRB) we estimated the potential of CFB to store CO₂ in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass) and the local equilibrium assumption for secondary phases (weathering products). The simulations were divided into closed-system batch simulations at a constant CO₂ pressure of 100?bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H₂O in scCO₂, and finally 1D reactive diffusion simulations giving reactivity at CO₂ pressures varying from 0 to 100?bar. Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO₂ mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40?C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 ?C 100?C), magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO₂ stored as solid carbonates, if CO₂ is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO₂ phase with limited amount of water, the total carbonation potential is limited by the amount of water present for hydration of basalt.     

Observations of beach cusps

Aagaard. Troels: Observations of beach cusps. Geografisk Tidsskrift 85: 27–31 Copenhagen, October 1985.

Observations of beach cusps have been conducted under low-energy conditions on the northern coast of Zealand, Denmark. The distance between cusps showed consistently good correlation with values calculated from a hypothetical occurrence of synchronous or subharmonic edge waves. A relationship is implied between the edge wave frequency and the value of the surf scaling parameter. Supplementary observations from the southern coast of England indicate that the edge wave theory may not be adequate in explaining the distance between cusps on pocket beaches.     

Glimpses of Arctic Ocean shelf–basin interaction from submarine-borne radium sampling

Evidence of shelf-water transfer from temperature, salinity, and ²²⁸Ra/²²⁶Ra sampling from the nuclear submarine USS L. Mendel Rivers SCICEX cruise in October, 2000 demonstrates the heterogeneity of the Arctic Ocean with respect to halocline ventilation. This likely reflects both time-dependent events on the shelves and the variety of dispersal mechanisms within the ocean, including boundary currents and eddies, at least one of which was sampled in this work. Halocline waters at the 132 m sampling depth in the interior Eurasian Basin are generally not well connected to the shelves, consonant with their ventilation within the deep basins, rather than on the shelves. In the western Arctic, steep gradients in ²²⁸Ra/²²⁶Ra ratio and age since shelf contact are consistent with very slow exchange between the Chukchi shelf and the interior Beaufort Gyre. These are the first radium measurements from a nuclear submarine.