沙丘人工差不嘎蒿植被建立后的微气候变化

运用文比热量平衡法和空气动力学梯度法初步分析了人工固定沙丘过程中的微气象变化。研究结果表明,随着流沙的固定,反射率减小;净辐射占太阳辐射的比例增大;热收支中,潜热通量所占的份额增多;近地表风速及其垂直切变减小。     

Exploring sustainability of aquifers based on predictive modeling of sorption characteristics of arsenic enriched Holocene sediments in Bangladesh

The importance of accessing safe aquifers in areas with high As is being increasingly recognized. The present study aims to investigate the sorption and mobility of As at the sediment-groundwater interface to identify a likely safe aquifer in the Holocene deposit in southwestern Bangladesh. The upper, shallow aquifer at around 18 m depth, which is composed mainly of very fine, grey, reduced sand and contains 24.3 μg/g As, was found to produce highly enriched groundwater (190 μg/L As). In contrast, deeper sediments are composed of partly oxidized, brownish, medium sand with natural adsorbents like Fe- and Al-oxides; they contain 0.76 μg/g As and impart low As concentrations to the water (4 μg/L). These observations were supported by spectroscopic studies with SEM, TEM, XRD and XRF, and by adsorption, leaching, column tests and sequential extraction. A relatively high in-situ dissolution rate (R_r) of 1.42 × 10⁻¹⁶ mol/m²/s was derived for the shallower aquifer from the inverse mass-balance model. The high R_r may enhance As release processes in the upper sediment. The field-based reaction rate (K_r) was extrapolated to be roughly 1.23 × 10⁻¹³ s⁻¹ and 6.24 × 10⁻¹⁴ s⁻¹ for the shallower and deeper aquifer, respectively, from the laboratory-obtained adsorption/desorption data. This implies that As is more reactive in the shallower aquifer. The partition coefficient for the distribution of As at the sediment-water interface (K_d-As) was found to range from 5 to 235 L/kg based on in-situ, batch adsorption, and flow-through column techniques. Additionally, a parametric equation for K_d-As (R² = 0.67) was obtained from the groundwater pH and the logarithm of the leachable Fe and Al concentrations in sediment. A one-dimensional finite-difference numerical model incorporating K_d and K_r showed that the shallow, leached As can be immobilized and prevented from reaching the deeper aquifer (∼150 m) after 100 year by a natural filter of oxidizing sand and adsorbent minerals like Fe and Al oxides; in this scenario, 99% of the As in groundwater is reduced. The deeper aquifer appears to be an adequate source of sustainable, safe water.     

Annual Variability of Sea Surface Height and Upper Layer Thickness in the Pacific Ocean

The annual variabilities of the sea surface height in the Pacific Ocean were investigated by analyzing the TOPEX/POSEIDON satellite data and by solving a reduced gravity model. We discuss how adequately the simple model can capture the variabilities of the sea surface height, and what the cause of the variabilities is. Three large amplitude peaks in the satellite data are found along the 12°N longitude line. Two elongated zones with a large amplitude are also found: one extends east-west along 6°N and the other extends northwestward from South America around 25°S. These features are adequately reproduced in the numerical simulation of the reduced gravity model. The propagation of the Rossby wave is analyzed by the use of the extended Eliassen-Palm flux to investigate the mechanism of these annual variabilities. The two east peaks around 12°N can be explained in terms of the interference between the local Ekman pumping and the free wave emitted near the western coast of North America, and the most western peak is affected by the Rossby wave formed by the local wind stress. The elongated zonal area around 6°N is mainly due to the local Ekman pumping. Another area around 25°S results from the convergence of the free Rossby wave emitted from the eastern boundary and the area with the strong wind stress curl off South America. A discrepancy between the satellite data and the model results suggests that the eastern equatorial Pacific Ocean is relatively calm in the model but not in the satellite data. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characteristics of the Cibaliung Gold Deposit: Miocene Low-Sulfidation-Type Epithermal Gold Deposit in Western Java, Indonesia

Middle Miocene (11.18–10.65 Ma) low sulfidation‐type epithermal gold mineralization occurred in the Cibaliung area, southwestern part of Java Island, Indonesia. It is hosted by andesitic to basaltic andesitic lavas of the Middle Miocene Honje Formation (11.4 Ma) and is covered by Pliocene Cibaliung tuff (4.9 Ma). The exploration estimates mineral resource of approximately 1.3 million tonnes at 10.42 g/t gold and 60.7 g/t silver at a 3 g/t Au cut‐off. This equates to approximately 435,000 ounces of gold and 2.54 million ounces of silver. That resource resulted from two ore shoots: Cibitung and Cikoneng. Studies on ore mineralogy, hydrothermal alteration, geology, fluid inclusion, stable isotopes and age dating were conducted in order to characterize the deposit and to understand a possible mechanism of preservation of the deposit. The ore mineral assemblage of the deposit consists of electrum, naumannite, Ag‐Se‐Te sulfide minerals, chalcopyrite, pyrite, sphalerite and galena. Those ore minerals occur in quartz veins showing colloform–crustiform texture. They are enveloped by mixed layer clay illite/smectite zone, which grades into smectite zone outward. The temperature of mineralization revealed by fluid inclusion study on quartz in the veins ranges from 170 and 220°C at shallow and deep level, respectively. The temperature range is in agreement with the temperature deduced from the hydrothermal alteration mineral assemblage including mixed layered illite/smectite and laumontite. The mineralizing fluid is dilute, with a salinity <1 wt% NaCl equivalent and has stable isotopes of oxygen and hydrogen composition indicating a meteoric water origin. Although the deposit is old enough that it would have been eroded in a tropical island arc setting, the coverage by younger volcanic deposits such as the Citeluk tuff and the Cibaliung tuff most probably prevented this erosion.     

Adsorption Characteristics of Reactive Black 5 from Aqueous Solution onto Chitosan

Adsorption of reactive black 5 (RB5) from aqueous solution onto chitosan was investigated in a batch system. The effects of solution pH, initial dye concentration, and temperature were studied. Adsorption data obtained from different batch experiments were modeled using both pseudo first‐ and second‐order kinetic equations. The equilibrium adsorption data were fitted to the Freundlich, Tempkin, and Langmuir isotherms over a dye concentration range of 45–100 µmol/L. The best results were achieved with the pseudo second‐order kinetic and Langmuir isotherm equilibrium models, respectively. The equilibrium adsorption capacity (q_e) was increased with increasing the initial dye concentration and solution temperature, and decreasing solution pH. The chitosan flakes for the adsorption of the dye was regenerated efficiently through the alkaline solution and was then reused for dye removal. The activation energy (E_a) of sorption kinetics was estimated to be 13.88 kJ/mol. Thermodynamic parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were evaluated by applying the van't Hoff equation. The thermodynamics of reactive dye adsorption by chitosan indicates its spontaneous and endothermic nature.     

Dependence of seafloor boundary layer thickness on the overlying flow direction: a large eddy simulation study

Using large eddy simulation (LES) incorporating the effect of the horizontal component of the earth’s rotation vector, we studied the seafloor turbulent boundary layer to investigate the dependence of the boundary layer thickness on the overlying geostrophic flow orientation. The thickest boundary layer appears for the westward geostrophic flow: it is almost twice that of the eastward flow. The turbulent disturbances in the boundary layer are elongated slightly leftward relative to the geostrophic flow. Linear stability analysis for the Ekman’s spiral flow showed that the growth rate is maximum for the westward geostrophic flow and the unstable roll-like mode appears, which points slightly leftward relative to the geostrophic flow. These properties correspond to the feature near the bottom of the developed turbulent layer.     

Climatic physical snowpack properties for large-scale modeling examined by observations and a physical model

Here we have conducted an integral study using site observations and a model with detailed snow dynamics, to examine the capability of the model for deriving a simple relationship between the density and thermal conductivity of the snowpack within different climatic zones used in large-scale climate modeling. Snow and meteorological observations were conducted at multiple sites in different climatic regions (two in Interior Alaska, two in Japan). A series of thermal conductivity measurements in snow pit observations done in Alaska provided useful information for constructing the relationship. The one-dimensional snow dynamics model, SNOWPACK, simulated the evolution of the snowpack and compared observations between all sites. Overall, model simulations tended to underestimate the density and overestimate the thermal conductivity, and failed to foster the relationship evident in the observations from the current and previous research. The causes for the deficiency were analyzed and discussed, regarding a low density of the new snow layer and a slow compaction rate. Our working relationships were compared to the equations derived by previous investigators. Discrepancy from the regression for the melting season observations in Alaska was found in common.     

奈曼沙漠化对草地微气象特性影响的研究

为探索沙漠化发生机制，在内蒙古奈曼的流动沙丘，干草地和湿草地进行了微气象观测，并用热量平衡法分析观测数据。观测结果表明，沙漠化发生后，反射率增加，净 辐射减少；而且热量平衡中土壤热通量所占份额增加，潜热通量所占份额减少。干、湿草地的风速廓线在白天和夜间都近于对数分布。而沙丘的风速廓线只在晚上近于对数分布。白天沙丘近地表风速垂直切变较大，从而对沙丘表面产生较强切应力。曳力系数白天低于夜里，沙丘低于干、湿草地。     

A Study on the Formation of Smectite in Silica Scales Precipitated from Geothermal Water: The Effect of Magnesium

Abstract. Silica scales containing large amounts of smectite were recently found in the pipelines for geothermal water at a geothermal power plant. To elucidate the mechanism of smectite formation, seven silica scale samples were characterized by powder X-ray diffraction, chemical analysis and ²⁷A1 MAS NMR. Smectite was present in samples with MgO levels above 10 wt% and Al₂O₃ levels below 10 wt%. In ²⁷A1 MAS NMR spectra, peaks assigned to both tetrahedrally and octahedrally coordinated aluminum (Al(4) and Al(6)) were observed for Mg-rich samples, whereas a peak due to Al(4) alone appeared in Mg-poor samples. From these observation and comparison between ²⁷A1 MAS NMR spectra for synthesized precipitates of Al₂O₃-SiO₂ containing MgO and not containing MgO, it is concluded that magnesium plays an important role in the stabilization of Al(6), and results in the formation of smectite     

Quasi-static slip on the plate boundary associated with the 2003 M8.0 Tokachi-oki and 2004 M7.1 off-Kushiro earthquakes, Japan

We analyzed small repeating earthquakes recorded over a 13-year period and GPS data recorded over an 8-month period to estimate interplate quasi-static slip associated with the 2003 Tokachi-oki earthquake (M8.0) and the 2004 off-Kushiro earthquake (M7.1). The repeating-earthquake analysis revealed that the slip rate near the source region of the Tokachi-oki earthquake was relatively low (< 5 cm/year) prior to the earthquake; however, in the last 3 years leading up to the event, a minor acceleration in slip occurred upon the deeper extension of the coseismic slip area of the earthquake. Repeating-earthquake and GPS data indicate that large amounts of afterslip occurred around the rupture area following the earthquake; the afterslip mainly propagated to the east of the coseismic slip area. We also infer that the occurrence of the 2004 off-Kushiro earthquake, located about 100 km northeast of the epicenter of the Tokachi-oki earthquake, was advanced by the afterslip associated with the Tokachi-oki earthquake.