辽东宽甸东北沟钼矿二长花岗岩年代学、地球化学及Hf同位素特征

东北沟钼矿是辽宁宽甸地区近些年发现的大型隐爆角砾岩型钼矿床。文章首次对东北沟钼矿床赋矿围岩二长花岗岩进行LA-MC-ICP-MS锆石U-Pb定年,主量元素、微量元素和Hf同位素地球化学研究,锆石U-Pb定年结果表明,二长花岗岩形成年龄为(129.4±0.3)Ma(MSWD=0.83),为燕山期构造岩浆活动产物。地球化学成分上,岩石具有富硅(SiO_2=62.21%~83.21%)、高钾(K_2O/Na_2O=3.35~20.27)和富碱(K_2O+Na_2O=5.82%~12.23%)的特点,属于钾玄岩系列。岩石富集轻稀土元素(LREE/HREE=10.26~24.21),亏损重稀土元素,具有弱负铕异常(δEu=0.63~1.07),富集大离子亲石元素(如K、Rb、Pb)和不相容元素(如Th、U)的特征,相对亏损高场强元素(如Nb、Ta、P、Ti)。锆石Hf同位素分析结果表明,东北沟钼矿二长花岗岩的ε_(Hf)(t)值为介于-12.4~-8.5,二阶段模式年龄(t_(DM2))介于442~1610 Ma,反映岩浆源区可能来源于中元古界古老地壳的再熔融。结合区域构造演化,成岩成矿构造背景为早白垩世古太平洋板块向欧亚之下俯冲,岩石圈减薄的构造环境。     

附着基粗糙度等因素与海藻密度的相关性研究

海藻附着基表面粗糙度与孢子附着密度有密切的相关性;已经由许多研究证实。但是海藻苗的密度是否仍然受到附着基粗糙度的影响;还缺乏明确的结论。本文以尼龙和亚克力两种材料作为海藻附着基;悬挂于自然海区中使海藻孢子附着并萌发生长;用以研究附着基表面粗糙度对4种海藻密度的影响。结果显示;多管藻、尾孢藻、点叶藻、硬毛藻这4种海藻;在不具沟槽的光滑面;密度显著低于任何有沟槽的粗糙面;但粗糙度不同的附着基之间比较;对海藻密度的影响并不显著。室内培育的海带苗;在尼龙上的密度与粗糙度成正相关;但是将海带苗移至海上培育后;不再与粗糙度有相关性;可能与其假根状固着器下海后的发育有关。本文还试验了海泥、灭活海泥和低栖硅藻3种沉积物与附着基粗糙度对海藻密度的影响;结果表明;沉积物和附着基粗糙度;以及它们的交互作用对海藻密度的影响;因附着基的材料和海藻种类而有差别。     

东海内陆架沉积物敏感粒级构成及其地质意义

沉积物粒级包含了大量的沉积环境信息,在古环境恢复和重建中被广泛应用。基于采自东海内陆架的三根沉积物岩芯,作者利用激光粒度分析方法研究了沉积物的粒度组成,确定了敏感性粒级,探讨了搬运机制及其环境意义。研究表明:东海内陆架现代沉积物含有大致相同的三个敏感性粒级,分别是粒级1(12μm)、粒级2(12—225μm)和粒级3(225μm)。从北到南敏感粒级具有逐渐细化的趋势,该趋势与长江入海沉积物向南搬运过程中发生的沉积分异作用有关。粒级1和粒级2分别由均匀悬浮次总体和递变悬浮次总体构成,而粒级3则由生物过程产生。结合该区的海洋动力特征,作者认为,粒级2可较好地用来指示冬季海洋动力强度,并具有揭示东亚冬季风强度的潜在意义。     

胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。     

Solar-, monsoon- and Kuroshio-influenced thermocline depth and sea surface salinity in the southern Okinawa Trough during the past 17,300 years

Factors influencing millennial-scale variability in the thermocline depth (vertical mixing) and sea surface salinity (SSS) of the southern Okinawa Trough (OT) during the past 17,300 years were investigated based on foraminifer oxygen isotope records of the surface dweller Globigerinoides ruber sensu stricto and the thermocline dweller Pulleniatina obliquiloculata in the AMS ¹⁴C dated OKT-3 core. The thermocline depth is influenced by surface thermal buoyancy (heat) flux, in turn controlled by the annual mean insolation at 30°N and the strength of the East Asian winter monsoon (EAWM). Strong insolation and weak EAWM tend to increase buoyancy gain (decrease buoyancy loss), corresponding to shallow thermocline depths, and vice versa. Regional SSS is influenced by the global ice volume, the Kuroshio Current (KC), and vertical mixing. A deep thermocline coincides with a high SSS because strong vertical mixing brings more, saltier subsurface KC water to the surface, and vice versa. Local SSS (excluding the global ice volume effect) became lower in the northern OT than in the southern OT after ~9.2 ka, implying that Changjiang diluted water had stronger influence in the northern sector. SSS show no major changes during the Bølling/Allerød and Younger Dryas events, probably because the KC disturbed the North Atlantic signals. This argues against earlier interpretations of sea surface temperature records of this core. Wavelet and spectral analyses of the Δδ¹⁸O_P-G (δ¹⁸O of P. obliquiloculata minus G. ruber s.s.) and δ¹⁸O_local records display 1,540-, 1,480-, 1,050-, 860-, 640-, and 630-year periods. These are consistent with published evidence of a pervasive periodicity of 1,500 years in global climate as well as EAWM and KC signatures, and a fundamental solar periodicity of 1,000 years and intermediary derived periodicity of 700 years.     

绿藻水溶性多糖的研究概况和进展

对近年来绿藻多糖的提纯方法、组成结构及应用的研究进展进行了综述。绿藻多糖的提纯需要经过样品的前处理、提取和精制三个步骤,提取方法包括酸提、酶提、加入钙螯合剂提取、微波及超声波辅助提取。绿藻多糖是水溶性的硫酸化杂多糖。从石莼(Ulva)、浒苔(Enteromorpha)、礁膜(Monostroma)、小球藻(Chlorella)、蕨菜(Bracken)及刚毛藻(Bristles)中提取的多糖的化学组成及结构特征各不相同,而且多糖的化学组成和结构特征受提取方式的影响。绿藻多糖的生物相容性、生物可降解性及抗氧化、抗肿瘤、抗凝血、抗炎、免疫调节等多种生物活性使其在食品、医药、化妆品及农业中具有广泛的应用。有关绿藻多糖的精确结构、提纯方法及化学修饰的进一步研究将使绿藻多糖的应用更加广泛。     

Early Mesozoic Southward Subduction of the Eastern Mongol–Okhotsk Oceanic Plate: Evidence from Zircon U–Pb–Hf Isotopes and Whole‐rock Geochemistry of Triassic Granitic Rocks in the Mohe Area,NE China

In this paper, we present new U–Pb zircon ages, Hf isotope data and major and trace elements for Early Mesozoic granitic rocks in Mohe area in the Erguna Massif of northeast China to elucidate the southward subduction of the eastern Mongol–Okhotsk Oceanic plate in Early Mesozoic. Zircons from two representative intrusions, syenogranites and monzogranites, in the Mohe area are euhedral–subhedral in shape, display oscillatory growth zoning in cathodoluminescence (CL) images, and have Th/U ratios of 0.10–0.72, and in combination these features indicating that the zircons are of igneous origin. U–Pb zircon dating results demonstrate that the syenogranites formed at 245.1 ± 1.4 Ma and monzogranites formed at 212.2 ± 1.7 Ma. These granitic rocks are characterized by high SiO₂, Al₂O₃ and (Na₂O + K₂O), low TFeO, MgO, TiO₂ and P₂O₅ concentrations, belonging to the high‐K calc‐alkaline series. They are enriched in LREE and large ion lithophile elements (e.g., Rb, K, and Sr), depleted in HREE and high field strength elements (e.g., Nb, Ta, Th, and Ti), as well as very weak negative Eu anomalies (Eu/Eu* = 0.48 ~ 1.01). Their zircon εHf(t) values range from −7.9 to −2.0 and range from 0.20 to 0.49, in response to their two‐stage Hf model ages (T_DM2) range from 1.40 Ga to 1.77 Ga range from 0.94 Ga to 1.24 Ga, respectively, indicating that primary magmas of syenogranites were derived from partial melting of newly accreted juvenile crustal material that formed from the enriched mantle during the Mesoproterozoic, monzogranites are generated by partial melting of newly accreted juvenile crustal material that formed from the depleted mantle during the Meso‐ to Neoproterozoic. We conclude, therefore, that the early Mesozoic granitic rocks of the Mohe area are associated with the continuous southward subduction of the Mongol–Okhotsk oceanic plate rather than the Paleo‐Asian and circum‐Pacific tectonic regimes.     

桂西地区二叠系合山组铝土岩的沉积环境*

桂西地区二叠系合山组铝土岩的沉积环境存在海相、陆相之争。通过对桂西二叠系铝土岩的区域调查及钻孔样品微量元素地球化学数据的分析,认为桂西二叠系铝土岩产出于陆相环境。从铝土岩分布情况看,桂西二叠纪各孤立碳酸盐岩台地上均广泛分布铝土岩沉积,该区域产出特征证明矿层是在碳酸盐岩台地全部暴露地表的环境下形成的。从铝土岩层与下伏茅口组灰岩的接触关系来看,铝土岩层底部存在茅口组灰岩砾石,在部分剖面尚见下伏茅口组灰岩中充填铝土岩等现象,说明铝土岩矿化过程直接于茅口组灰岩的古喀斯特面上完成。此外,在矿层中发现古植物根茎化石也是铝土岩形成于陆相环境的有力证据。从微量元素地球化学结果来看,来自铝土岩层样品的硼含量均小于10×10^-6,Sr/Ba值范围为0.29~1.61,平均值为0.92,Rb/K值范围为0.0011~0.0025,平均值为0.0017,以上指标结合V/Zr-Zr/Cu图解的判别,结果均指示铝土岩形成于陆相淡水环境。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

Open image in new window

Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

淤泥质潮滩地貌演变中的水动力及生物过程研究进展

淤泥质潮滩对于海岸防护、增加土地资源、保持生物多样性等具有重要作用。从淤泥质潮滩演变的主要驱动因子——潮流、波浪、生物作用及地下过程四个方面回顾和总结了潮滩演变动力地貌过程的相关研究进展,提出应关注潮滩短期演变规律、波浪与浮泥作用机理、生物生长与潮滩演变定量关系,以及地下过程作用机理等。