Geological and Geochemical Characteristics of the Hydrothermal Clay Alteration in South Korea

Abstract: Hydrothermally altered areas forming pyrophyllite‐kaolin‐sericite‐alunite deposits are distributed in Chonnam and Kyongsang areas, Cretaceous volcanic field of the Yuchon Group. The Chonnam alteration area is located within depression zone which is composed of volcanic and granitic rocks of late Cretaceous age. The clay deposits of this area show the genetic relationship with silicic lava domes. The Kyongsang alteration area is mainly distributed within Kyongsang Basin comprising volcanic, sedimentary and granitic rocks of Cretaceous and Tertiary age. Most of the clay deposits of this area are closely related to cauldrons. Paleozoic clay deposit occurs in the contact zone between Precambrian Hongjesa granite gneiss and Paleozoic Jangsan quartzite of Choson Supergroup. Cretaceous igneous rocks of the both alteration areas belong to high K calc‐alkaline series formed in the volcanic arc of continental margin by subduction‐related magmatism. Chonnam igneous rocks show more enrichment of crustal components such as K, La, Ce, Sm, Nd and Ba, higher (La/Yb)cn ratio, and higher initial ⁸⁷Sr/⁸⁶Sr ratio (0. 708 to 0. 712) than those of Kyongsang igneous rocks. This might be due to the difference of degree of crustal contamination during Cretaceous magmatism. The most characteristic alteration minerals of Chonnam clay deposits are alunite, kaolin, quartz, pyrophyllite and diaspore which were formed by acidic solution. Those of Kyongsang clay deposits are sericite, quartz and pyrophyllite which were formed by weak acid and neutral solution. The formation ages of the clay deposits of two alteration areas range from 70. 1 to 81. 4 Ma and 39. 7 to 79. 4 Ma, respectively. The Daehyun clay deposit in Ponghwa area of Kyongsang province shows the alteration age range from 290 to 336 Ma. This result shows the different alteration episode from the hydrothermal alteration of Cretaceous to early Tertiary in the Kyongsang and Chonnam alteration areas. These data indicate, at least, three hydrothermal activities of Tertiary (middle to late Eocene), late Cretaceous (Santonian to Maastrichtian) and Paleozoic Carboniferous Periods in South Korea.     

Petrogenesis of anhydrous clinopyroxenite xenoliths and clinopyroxene megacrysts in alkali basalts from the Ganseong area of South Korea

Late Cenozoic alkali basalts in the Ganseong area of South Korea contain abundant ultramafic xenoliths and clinopyroxene megacrysts. Anhydrous clinopyroxene‐rich wehrlite–clinopyroxenites make up the majority of the xenolith population and range from wehrlite through olivine clinopyroxenite to clinopyroxenite. This study investigates the petrogenesis of wehrlite–clinopyroxenite xenoliths and clinopyroxene megacrysts on the basis of petrography and mineral and whole‐rock chemistry. Observations such as an absence of carbonate or apatite, high Ti/Eu ratio, and clinopyroxene‐dominated mineralogy lead us to rule out peridotite–melt reactions as the origin of the Ganseong wehrlites– olivine clinopyroxenites. The whole‐rock compositions (e.g. high abundance of CaO at a given MgO content and low abundance of incompatible elements, such as U, K, P, and Ti compared with mafic melts) indicate that the pyroxenites do not represent crystallized magma itself, but are rather cumulates with a small amount of residual liquid. Anhydrous and orthopyroxene‐free mineral assemblages, crystallization sequence of olivine→clinopyroxene→plagioclase, and mineral chemistries (e.g. low Cr# and high TiO₂ abundances in spinels and high TiO₂ and Na₂O abundances in clinopyroxenes at a given Mg#) suggest that relatively anhydrous intraplate alkaline basalt is the most likely candidate for the parent magma. Texture and compositions of the clinopyroxene megacrysts preclude a cognate origin via high‐pressure crystallization of the host magma. The clinopyroxene megacrysts occupy the Fe‐rich end of the compositional trends defined by wehrlite–pyroxenite clinopyroxenes. Progressive decreases in Mg# and an absence of significant compositional gaps between pyroxenite xenoliths and clinopyroxene megacrysts indicate fractionation and differentiation of a similar parental magma. We suggest that the clinopyroxene megacrysts represent fragments of pegmatitic clinopyroxenites crystallized from more advanced fractionation stages of the evolution of a series of magmatic liquids formed Ganseong wehrlite–clinopyroxenites.     

朝鲜平南盆地泥盆纪化石的发现及其地质意义

平南盆地位于中朝地台东缘朝鲜半岛中部。平南盆地古生界比较发育,特别是盆地中南部地区发育寒武系、奥陶系和志留系,仅在盆地东南部谷山、法洞地区发现了晚奥陶世到志留纪的地层,其它地区末曾发现过晚奥陶世到早石炭世的地层。最近在平南盆地中部平壤之东原中奥陶统(晚达组)上部发现了Chaetetes cf. nantanensis, Calceola sp., Thamnopora sp., Cladopora sp. 等指示泥盆纪的化石;该含化石层的走向延续性比较好,延伸长度2~3 km。基于上述研究,认为原来的中奥陶统(晚达组)上部可能为泥盆系。在中朝地台,除了西缘和西南缘地区以外,大部分地区没有发现晚奥陶世-早石炭世的地层,只有辽东太子河流域本溪组的地质时代被认定为早石炭世晚期到晚石炭世早期。这些泥盆纪、早石炭世化石都发育在中朝地台东部,说明古生代时期中朝地台西部和东部沉积环境及构造演化有差别,因而对于中朝地台古生代古地理和构造演化需要重新认识。     

The role of United Nations Educational, Scientific and Cultural Organization–International Hydrological Programme in sustainable water resources management in East Asian countries

For over 30 years, IHP (International Hydrological Programme) has been actively operating as a UNESCO’s (United Nations Educational, Scientific and Cultural Organization) international scientific cooperative programme in water research, water resources management, education and capacity-building, and the only broadly-based science programme of the UN (United Nations) system in this region. By a number of initiatives and networks, the IHP has progressively carried out activities on the quantity and quality of global/regional water resources, transboundary water resources management, mitigation of water related hazards, and water education. While addressing comprehensive areas over water challenges, greater emphasis has been placed on the role of water resources management for sustainable development and with respect to the expected changes in climate and environmental conditions. WWAP (World Water Assessment Programme) and its major product WWDR (World Water Development Report) in East Asia are under the framework of IHP which supports field oriented activities on monitoring freshwater, developing case studies, enhancing national assessment capacity, and facilitating decision making processes. In light of transboundary waters in IHP, RSC (Regional Steering Committee) plays a focal role for facilitating regional cooperation in the Southeast and East Asia and Pacific States. Furthermore, ISI (International Sediment Initiative) and IFI (International Flood Initiative) have significant roles, respectively, for the management of erosion and sedimentation in line with river system or reservoir management, and for the flood management focusing on capacity building of each country in East Asia. There are other major areas of concern under UNESCO’s IHP programme in East Asia, specifically in aspects including, mitigating water conflicts on transboundary aquifers through ISARM (International Shared Aquifer Resources Management), water management of arid areas through Water and Development Information for Arid Lands- A Global Network (Asian G-WADI), and sustainable management of groundwater by UNESCO Water Chair, as well as water education through the programme of Sustainable Water Integrated Management- Educational Component.     

An englacial image and water pathways of the Fourcade glacier on King George Island, Antarctic Peninsula, inferred from ground-penetrating radar

The distribution of small fractures and water content of the Fourcade glacier on King George Island, Antarctica, was investigated in November 2006 and December 2007 by two ground-based (470-and 490-m-long profiles) and one helicopter-borne (470-m-long profile) ground-penetrating radar (GPR) surveys using 50-, 100-, and 500-MHz antennas. Radar images in the pre-migrated GPR sections are characterized by a smooth ice surface and irregular bed topography, numerous diffraction hyperbolas in the ice and at the g...     

Anthropogenic and biogenic winter sources of Arctic CO2—a model study

Long‐range transport of anthropogenic and biogenic CO₂ to a remote site in the Arctic is studied. A limited area, off‐line, Eulerian atmospheric transport model is used, and the results are compared to the observed CO₂ concentration at the "Ny‐Alesund International Arctic Research and Monitoring Facility". Inventories of anthropogenic CO₂ emissions and estimates of biogenic CO₂ emissions are used to investigate the respective impact of these emissions on Arctic CO₂ variations during 4 winter months. A direct comparison of the modelled and observed concentrations reveals remarkably good timing in the modelled variations as compared to the observed variations for most of the time. The correlation of observed versus modelled CO₂ concentration is significant at the 95% confidence level. The biogenic and the anthropogenic CO₂ emissions are shown to have approximately equal influence on Arctic CO₂ variations during winter. Europe is found to be the dominant source of anthropogenic CO₂ at the monitoring station, while Siberia and Northern America have little influence on Arctic CO₂, during the months studied. These results contradict Engardt and Holmén whose results indicate that the lower‐Ob region in western Siberia has a large impact on Arctic CO₂.     

CAN IMAGE ANALYSIS PROVIDE INFORMATION USEFUL IN CTTEMISTRY?

Images can contain chemical information and many chemical methods can generate image data. For anefficient extraction of chemical data from images, data analysis techniques are necessary, It is a greatadvantage to be able to work on multivariate images. Many imaging techniques allow the extraction ofchemical information. Inorganic analytical chemistry seems to have the longest tradition here, butorganic chemistry and biochemistry may soon be catching up. Also large data arrays from non-imagingtechniques can be combined with image analysis in a useful way, provided certain conditions are fulfilled.