Low‐frequency modulation and trend of the relationship between ENSO and precipitation along the northern to centre Peruvian Pacific coast

The relationship between El Niño Southern Oscillation (ENSO) and precipitation along the Peruvian Pacific coast is investigated over 1964–2011 on the basis of a variety of indices accounting for the different types of El Niño events and atmospheric and oceanographic manifestations of the interannual variability in the tropical Pacific. We show the existence of fluctuations in the ENSO/precipitation relationship at decadal timescales that are associated with the ENSO property changes over the recent decades. Several indices are considered in order to discriminate the influence of the two types of El Niño, namely, the eastern Pacific El Niño and the central Pacific El Niño, as well as the influence of large‐scale atmospheric variability associated to the Madden and Julian Oscillation, and of regional oceanic conditions. Three main periods are identified that correspond to the interleave periods between the main climatic transitions over 1964–2011, i.e. the shifts of the 1970s and the 2000s, over which ENSO experiences significant changes in its characteristics. We show that the relationship between ENSO and precipitation along the western coast of Peru has experienced significant decadal change. Whereas El Niño events before 2000 lead to increased precipitation, in the 2000s, ENSO is associated to drier conditions. This is due to the change in the main ENSO pattern after 2000 that is associated to cooler oceanic conditions off Peru during warm events (i.e. central Pacific El Niño). Our analysis also indicates that the two extreme El Niño events of 1982/1983 and 1997/1998 have overshadowed actual trends in the relationship between interannual variability in the tropical Pacific and precipitation along the coast of Peru. Overall, our study stresses on the complexity of the hydrological cycle on the western side of the Andes with regard to its relationship with the interannual to decadal variability in the tropical Pacific. Copyright © 2014 John Wiley & Sons, Ltd.     

High-frequency multi-solute calibration using an in situ UV–visible sensor

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.     

Up to 400‐year‐old Rhododendron shrubs on the southeastern Tibetan Plateau: prospects for shrub‐based dendrochronology

In harsh and treeless environments, shrubs constitute the dominant growth form of woody plants, thus offering the opportunity to extend dendrochronological networks beyond the uppermost and northernmost distribution limits of trees. However, shrub‐based dendrochronology has so far resulted in only a few long and climate‐responsive ring‐width chronologies at such stressful sites, particularly above the alpine tree line. A previous study on an alpine Rhododendron shrub species resulted in <80‐year‐long ring‐width chronologies. Here, we collected Rhododendron aganniphum var. schizopeplum stems from elevations between 4000 and 4500 m a.s.l. on the SE Tibetan Plateau and built six tree‐ring width chronologies. One of them is 401 years long and well replicated from AD 1670 to 2011 (EPS>0.85), thus representing the longest shrub chronology available to date. A principal component analysis (PCA) converted the total variability of all six site chronologies into PCs. Then, the six site chronologies and the PC1, accounting for 65.9% of the total variance of the tree‐ring width, were correlated with time series of monthly climate data. Based on this, the year‐to‐year variability of the ring‐width indices was positively correlated with July temperature, which thus turned out to be the dominant factor controlling growth. Accordingly, such long shrub‐ring chronologies may act as climatic and ecological proxies in treeless environments of the Tibetan Plateau.     

Assessment of phosphogypsum impact on the salt-marshes of the Tinto river (SW Spain): role of natural attenuation processes

About 120 Mton of phosphogypsum from the fertiliser industry were stack-piled on the salt-marshes of the Tinto river (Spain). This paper investigates the capacity of salt-marshes to attenuate contamination due to downward leaching from phosphogypsum. Solids and pore-waters were characterized at different depths of the pile to reach the marsh-ground. In superficial zones, metals were highly mobile, and no reduced sulphur was found. However, pollutant concentration decreased in the pore-water in deeper oxygen-restricted zones. Metal removal occurred by precipitation of newly formed sulphides, being this process main responsible for the contamination attenuation. Pyrite-S was the main sulphide component (up to 2528 mg/kg) and occurred as framboids, leading to high degrees of pyritization (up to 97%). The sulphidization reaction is Fe-limited; however, excess of acid-volatile sulphide over other metals cause precipitation of other sulphides, mainly of Cu and As. This decrease in metal mobility significantly minimises the impact of phosphogypsums on the salt-marshes.     

Multidisciplinary approach of the hyperarid desert of Pampas de La Joya in southern Peru as a new Mars-like soil analog

The distribution of living organisms, organic matter, and chemical properties in Mars-like environments on Earth can be used as a model to guide the investigation of possible habitable environments on Mars. This work aims to demonstrate that the place known informally as the “Mar de Cuarzo” (Sea of Quartz) in the Pampas de La Joya desert southern Peru (between 16°S and 17°S latitude), contains soils with characteristics similar to those found on the Martian surface. Using a multidisciplinary approach, we studied the environmental data, geology, organic matter content, oxidant activity, and microbiology of this area. Our data show that (1) Mar de Cuarzo is a hyper arid area with a lower concentration of organic matter than those found in the Mars-like soils from Yungay area (Atacama Desert in Chile), while at the same time having, comparable extreme environmental conditions, and very low levels of microorganisms. (2) The detrital components of the soils come essentially from the Andean volcanic chain and local outcrops of Precambrian gneisses and Cretaceous granitic batholiths. (3) The presence of microclimates, geomorphological features, and the high influence of the “El Niño Southern Oscillation (ENSO)” allowed the formation of exotic and heterogeneous chemical deposits in these soils, including iron oxides, sulfates, and other evaporites. (4) Thermal volatilization in these soils (using methods similar to the Viking and Phoenix instruments) shows high oxidant activity. (5) Labeled release experiment (similar to the Viking instrument) shows high degradation of nutrients added in these soils.Altogether, the Mar de Cuarzo area in the Pampas de La Joya is an interesting place for astrobiological studies as a new analog to Mars, and for comparative analyses with other hyperarid analogs as Yungay.     

Modeling aquifer�Criver interactions under the influence of groundwater abstraction in the Mancha Oriental System (SE Spain)

The Mancha Oriental System (MOS, 7,260?km²) is one of the largest aquifers within Spain, and is encompassed by the Jucar River Basin. Over the past 30?years, socioeconomic development within the region has been largely due to intensive use of groundwater resources for irrigating crops (1,000?km²). Groundwater pumping (406 million m³/year) has provoked a steady drop in the groundwater level and a reduction of MOS discharge to the Jucar River. The study aims to characterize the river?Caquifer relationship, to determine the influence that groundwater abstraction has on the river discharge. This research has advanced a three-dimensional large-scale numerical groundwater-flow model (MODFLOW 2000) in order to spatially and temporally evaluate, quantify and predict the river?Caquifer interactions that are influenced by groundwater abstraction in MOS. It is demonstrated that although groundwater abstraction increased considerably from the early 1980s to 2000, the depletion of water stored in the aquifer was lower than might be expected. This is mainly due to aquifer recharge from the Jucar River, induced by groundwater abstraction. The area of disconnection between the river and the water table (i.e. where groundwater head is lower than the riverbed) is found to have spread 20?km downstream from its position before pumping started.     

Origin of rare earth element anomalies in mangrove sediments,Sepetiba Bay,SE Brazil: used as geochemical tracers of sediment sources

Elemental contents were determined in two mangrove habitats along Sepetiba Bay, SE Brazil, an area impacted by local industrial activities, as well as hinterland water diversion networks. This study demonstrates how specific REEs (La, Ce, Nd, Sm, Eu, Tb, Yb and Lu) may be used as a sediment source tracer to mangrove-dominated coastlines. From the two stations studied, a pair of cores was collected, one in the mangrove forest and the other in the tidal flat. Station 1 results show a general enrichment in most of the fractioned patterns of the REEs normalised by Post-Archean Australian Shale. The relatively light rare earth elements are similarly enriched in the generally more polluted Station 1. Despite the probable difference in background sediment characteristics, a common sharp increase in mud contents patterns in the upper part of the mangrove sediment core was related to a lower REE content as well as Eu anomalies. With existing knowledge of clockwise water circulation in the bay, these patterns can be explained by man-made water diversion from the São Francisco and Guandu rivers, initiated more than 30 years ago, whereby suspended matter with relatively large contents of REEs and material originating from industrial sources accumulate in the eastern sector of the bay. This is the first comprehensive assessment of REEs as sedimentary tracers in a mangrove ecosystem in Brazil.