TiN PRODUCTION IN A GLOW DISCHARGE

We have been studying direct current glow discharges aiming at the production of different paint of coatings on steel substrates. In a set of preliminary experiments, long lasting (hours) discharges performed in a Nitrogen atmosphere between a stell anode (holding the substrates) and a titanium cathode separated by a small gap (few mm) produced very thin coatings of the substrates whose colour depend on the parameter of (interelectrodes gap, gas pressure, discharge current and time duration). In some conditions, the coatings showed a golden colour, typical of the Nti compound. A discussion of the results is given.     

Dark matter influence on velocity dispersion profiles of clusters of galaxies

We have performed a series ofN-body experiments including the effects of a massive dominant background which follows Schuster's density law in order to simulate clusters of galaxies in which a smoothly distributed dark component is present. The existence of this background is inferred from the weak luminosity segregation observed in clusters which, however, show several characteristics of well-relaxed systems. The comparison of the velocity dispersion profiles of three clusters of galaxies (Coma, Perseus, and Virgo) with those obtained in the numerical experiments allows us to place some constraints on both the distribution and amount of distributed dark material in these clusters. The profiles are rather insensitive to variations in the ratio of the background mass to the mass attached to galaxies (M _b/M_g), but exhibit a strong dependence on their relative concentration. We conclude that highly concentrated background models are not consistent with observations. We find a maximum value for the ratio of the gravitational radius of the galaxies and the background (R _g/R_b) (approximately 0.6) and using previous results (Navarroet al., 1986) we conclude that virial theorem masses underestimate the total mass (M _b+M _g) of the clusters. As a final result, we derive a minimum value for theM _b/M_g ratio. All these conclusions could apply in general if Coma, Perseus, and Virgo constitute a fair sample of the rich clusters of galaxies in the Universe.     

Modelling and Remote Sensing of Land Surface Temperature in Turkey

This study introduces artificial neural networks (ANNs) for the estimation of land surface temperature (LST) using meteorological and geographical data in Turkey (26?C45°E and 36?C42°N). A generalized regression neural network (GRNN) was used in the network. In order to train the neural network, meteorological and geographical data for the period from January 2002 to December 2002 for 10 stations (Adana, Afyon, Ankara, Eski?ehir, ?stanbul, ?zmir, Konya, Malatya, Rize, Sivas) spread over Turkey were used as training (six stations) and testing (four stations) data. Latitude, longitude, elevation and mean air temperature are used in the input layer of the network. Land surface temperature is the output. However, land surface temperature has been estimated as monthly mean by using NOAA-AVHRR satellite data in the thermal range over 10 stations in Turkey. The RMSE between the estimated and ground values for monthly mean with ANN temperature(LST_ANN) and Becker and Li temperature(LST_B-L) method values have been found as 0.077?K and 0.091?K (training stations), 0.045?K and 0.003?K (testing stations), respectively.     

Rainfall trends in the Brazilian Amazon Basin in the past eight decades

Rainfall series at 18 stations along the major rivers of the Brazilian Amazon Basin, having data since 1920s or 1930s, are analyzed to verify if there are appreciable long-term trends. Annual, rainy-season, and dry-season rainfalls are individually analyzed for each station and for the region as a whole. Some stations showed positive trends and some negative trends. The trends in the annual rainfall are significant at only six stations, five of which reporting increasing trends (Barcelos, Belem, Manaus, Rio Branco, and Soure stations) and just one (Itaituba station) reporting decreasing trend. The climatological values of rainfall before and after 1970 show significant differences at six stations (Barcelos, Belem, Benjamin Constant, Iaurete, Itaituba, and Soure). The region as a whole shows an insignificant and weak downward trend; therefore, we cannot affirm that the rainfall in the Brazilian Amazon basin is experiencing a significant change, except at a few individual stations. Subregions with upward and downward trends are interspersed in space from the far eastern Amazon to western Amazon. Most of the seasonal trends follow the annual trends, thus, indicating a certain consistency in the datasets and analysis.     

Relationship between climate change and vegetation distribution in the Mediterranean mountains: Manzanares Head valley, Sierra De Guadarrama (Central Spain)

This work analyzes the consequences of climate change in the distribution of the Mediterranean high-mountain vegetation. A study area was chosen at the Sierra de Guadarrama, in the center of the Iberian Peninsula (1,795 to 2,374 m asl). Climate change was analyzed from the record of 18 variables regarding temperature, rainfall and snowfall over the period 1951–2000. The permanence of snow cover (1996–2004), landforms stability and vegetation distribution in 5 years (1956, 1972, 1984, 1991 and 1998) were all analyzed. The Nival Correlation Level of the different vegetation classes was determined through their spatial and/or temporal relationship with several climatologic variables, snow cover duration and landforms. In order to quantify trends and major change processes, areas and percent changes were calculated, as well as Mean Annual Transformation Indices and Transition Matrices. The findings reveal that in the first part of the study period (up to the first half of the 1970s) the temperature rise in the mid-winter months caused the reduction of some classes of nival vegetation, while others expanded, favored by high rainfall, decrease in both maximum temperatures and summer aridity, and longer snow cover duration. The second part of the study period was characterized by the consolidation of the increase in all thermal variables, along with an important reduction in rainfall volume and snow cover duration. As a result, herbaceous plants, which are highly correlated with a long snow permanence and abundance of melting water, have been replaced by leguminous shrubs which grow away from the influence of snow, and which are steadily becoming denser.     

Late Quaternary (Marine Isotope Stage 3 to Recent) sedimentary evolution of the Basque shelf (southern Bay of Biscay)

Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ¹⁸O_bull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From ～56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.     

Carbon pricing in practice: a review of existing emissions trading systems

This article analyses the implementation of emissions trading systems (ETSs) in eight jurisdictions: the EU, Switzerland, the Regional Greenhouse Gas Initiative (RGGI) and California in the US, Québec in Canada, New Zealand, the Republic of Korea and pilot schemes in China. The article clarifies what is working, what isn’t and why, when it comes to the practice of implementing an ETS. The eight ETSs are evaluated against five main criteria: environmental effectiveness, economic efficiency, market management, revenue management and stakeholder engagement. Within each of these categories, ETS attributes ? including abatement cost, stringency of the cap, improved allocation practices over time and the trajectory of price stability ? are assessed for each system. Institutional learning, administrative prudence, appropriate carbon revenue management and stakeholder engagement are identified as key ingredients for successful ETS regimes. Recent implementation of ETSs in regions including California, Québec and South Korea indicates significant institutional learning from prior systems, especially the EU ETS, with these regions implementing more robust administrative and regulatory structures suitable for handling unique national and sub-national opportunities and constraints. The analysis also shows that there is potential for a ‘double dividend’ in emissions reductions even with a modest carbon price, provided the cap tightens over time and a portion of the auctioned revenues are reinvested in other emissions-reduction activities. Knowledge gaps exist in understanding the interaction of pricing instruments with other climate policy instruments and how governments manage these policies to achieve optimum emissions reductions with lower administrative costs.

Key policy insights

• Countries are learning from each other on ETS implementation.

• Administrative and regulatory structures of ETS jurisdictions appear to evolve and become more robust in every ETS analysed.

• A ‘double dividend’ for emissions reductions may also exist in cases where mitigation occurs as a result of the ETS policy and when auction revenues are reinvested in other emissions-reduction activities.

     

Modelling regional effects of artificial groundwater recharge in a multilayer aquifer characterized by perched water tables

This paper presents an approach to estimate the effects of a managed recharge experiment in a multilayer aquifer characterized by the presence of perched water tables in the Medina del Campo groundwater body, Douro basin, central Spain. A numerical model was developed to evaluate the effect of artificial recharge on the shallow sector of a regional-scale aquifer and on formerly active wetlands. The model was developed in the Visual MODFLOW Pro v.2011.1 environment in order to represent and analyse the regional impact of this artificial recharge event. Results suggest that the assumption of a single perched system may prove useful in regional contexts where data is limited. From a study site perspective, managed recharge is observed to increase shallow storage along the riverbanks, which is considered valuable for environmental purposes. However, downstream wetlands are unlikely to experience a significant recovery. Furthermore, only a small percentage of artificial recharge is expected to reach the deep regional aquifer. This method can be exported to settings characterized by the presence of perched aquifers and associated groundwater dependent ecosystems.     

Dynamic compaction evaluation using in situ tests in Sagunto’s Harbor,Valencia (Spain)

This paper presents an assessment on the use of dynamic compaction as a ground improvement technique in a port’s hydraulic fill in the new southern dock of Sagunto’s Harbor near Valencia (Spain). Soil behavior improvement was monitored by several in situ techniques such as boreholes with SPTs, DPSH, CPTU and CSWS geophysical tests. A total energy between 2188 and 3125 kN/m² (depending the area) was applied to the hydraulic fill by the dynamic compaction procedure. In situ techniques led to evaluate dynamic compaction efficiency, as well as controlling ground modifications that might cause potential damages to adjacent buildings. The dynamic compaction carried out was capable of fulfilling requirements established to use the area, that is, an average deformability modulus (E′) of 30 MPa with a minimum of 20 MPa, in a depth of 10 m. Moreover, dynamic compaction increased hydraulic fill relative density by about 75%.