Petroleum and aqueous inclusions from deeply buried reservoirs: Experimental simulations and consequences for overpressure estimates

Synthetic hydrocarbon and aqueous inclusions have been created in the laboratory batch reactors in order to mimic inclusion formation or re-equilibration in deeply buried reservoirs. Inclusions were synthesized in quartz and calcite using pure water and Mexican dead oil, or n-tetradecane (C₁₄H₃₀), at a temperature and pressure of 150 °C and 1 kbar. One-phase hydrocarbon inclusions are frequently observed at standard laboratory conditions leading to homogenization temperatures between 0 and 60 °C. UV epifluorescence of Mexican oil inclusions is not uniform; blue and green-yellow colored inclusions coexist; however, no clear evidence of variations in fluid chemistry were observed. Homogenization temperatures were recorded and the maxima of T_h plotted on histograms are in good agreement with expected T_h in a range of 6 °C. Broad histograms were reconstructed showing non-symmetrical T_h distributions over a 20 °C temperature range centered on the expected T_h. This histogram broadening is due to the fragility of the fluid inclusions that were created by re-filling of pre-existing microcavities. Such T_h histograms are similar to T_h histograms recorded on natural samples from deeply buried carbonate reservoirs. T_h values lower than those expected were measured for hydrocarbon inclusions in quartz and calcite, and for aqueous inclusions in calcite. However, the results confirm the ability of fluid inclusions containing two immiscible fluids to lead to PT reconstructions, even in overpressured environments.     

On the Limitation of the H/V Spectral Ratio Using Seismic Noise as an Exploration Tool: Application to the Grenoble Valley (France), a Small Apex Ratio Basin

The H/V spectral ratio method based on seismic noise (HVSRN) was used in the Grenoble Basin (France), an Alpine valley characterized by a small apex ratio. The resonance frequencies obtained in the experiments were compared to the thickness of the sediments deduced from a microgravimetric survey and to the 1-D theoretical assessment of site responses. Given the abundance of data on the sediments and depth of the basin, the values of the theoretical resonance frequency f_o can be determined quite accurately. However, it has been observed that the effects of basin geometry can disturb f_o measurements using the HVSR method, in particular for a case like the Grenoble Basin, which has a small apex ratio (w/H) and strong suspected 2-D and/or 3-D effects. Interpretation of f_o values in terms of bedrock depth gives rise to estimation errors of about 10% in certain cases, with the most significant errors (>50%) occurring on the edges of the basin, where subsurface layers are characterised by larger heterogeneities and where the basin topography is accentuated. This study suggests that great care must be taken when using the HVSRN method as an exploration tool, at least in valleys with a small apex ratio.     

A quasi-spherical inner accretion flow in Seyfert galaxies?

We study a phenomenological model for the continuum emission of Seyfert galaxies. In this quasi-spherical accretion scenario, the central X-ray source is constituted of a hot spherical plasma region surrounded by spherically distributed cold dense clouds. The cold material is radiatively coupled with the hot thermal plasma. Assuming energy balance, we compute the hard X-ray spectral slope Γ and the reflection amplitude R . This simple model enables us to reproduce both the range of observed hard X-ray spectral slopes and the reflection amplitude R . It also predicts a correlation between R and Γ that is very close to what is observed. Most of the observed spectral variations from source to source would be caused by differences in the cloud covering fraction. If some internal dissipation process is active in the cold clouds, darkening effects may provide a simple explanation for the observed distributions of reflection amplitudes, spectral slopes and ultraviolet to X-ray flux ratios.     

Conditioning of Multiple-Point Statistics Facies Simulations to Tomographic Images

Geophysical tomography captures the spatial distribution of the underlying geophysical property at a relatively high resolution, but the tomographic images tend to be blurred representations of reality and generally fail to reproduce sharp interfaces. Such models may cause significant bias when taken as a basis for predictive flow and transport modeling and are unsuitable for uncertainty assessment. We present a methodology in which tomograms are used to condition multiple-point statistics (MPS) simulations. A large set of geologically reasonable facies realizations and their corresponding synthetically calculated cross-hole radar tomograms are used as a training image. The training image is scanned with a direct sampling algorithm for patterns in the conditioning tomogram, while accounting for the spatially varying resolution of the tomograms. In a post-processing step, only those conditional simulations that predicted the radar traveltimes within the expected data error levels are accepted. The methodology is demonstrated on a two-facies example featuring channels and an aquifer analog of alluvial sedimentary structures with five facies. For both cases, MPS simulations exhibit the sharp interfaces and the geological patterns found in the training image. Compared to unconditioned MPS simulations, the uncertainty in transport predictions is markedly decreased for simulations conditioned to tomograms. As an improvement to other approaches relying on classical smoothness-constrained geophysical tomography, the proposed method allows for: (1) reproduction of sharp interfaces, (2) incorporation of realistic geological constraints and (3) generation of multiple realizations that enables uncertainty assessment.     

Hydrogeochemical and multi-tracer investigations of arsenic-affected aquifers in semi-arid West Africa

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.     

Vulnerability conditions and risk representations in Latin-America: Framing the territorializing urban risk

In risk studies, a large scope of approaches has already been defined, from hazard-centered to socially rooted analysis; being social scientists’ focus on vulnerability more obvious from the late 1960s on. The present epistemological article locates risk causes in society and states that the production of risks is two fold: these are both material and discursive. The conceptual proposal of the article consists of setting an integrative framework that accounts for material aspects of risk as well as for the performative dimensions of its discourses, representations and conceptions. By performativity we mean that discourses and representations do not only reflect what people see or have in mind, but that they also operate the world and make things exist, having concrete consequences in society and its relations with the environment. The proposed framework is called the territorialization-of-risk framework and requires contextualizing and politicizing risk. We state that such framework lays epistemological and methodological groundwork for such a perspective. Territories are viewed as social constructions that are more than bounded pieces of space where an authority takes place. They are spaces where competing social meanings and identification are ascribed, and their making accounts for both material and ideal social drivers that also do intervene in the production of risk. Drawing on different Latin-American cities’ case studies, and mainly on the case of Caracas as former PhD fieldwork, the territorialization-of-risk allows asking critical questions related with power relations, social status, identity and discourses. Actually, risk appears to be the result of a social (both material and ideal) production as it contributes to the shaping of society. It is an outcome and a driver of society at the same time. The territorialization-of-risk framework sheds the light on the importance of non-material aspects in framing risk, as well as on the factual and discursive consequences of its management and policy.     

Morphology and structure of a landslide complex in an active margin setting: The Waitawhiti complex, North Island, New Zealand

Multi-scale gravitational instabilities are widespread in the Coastal Ranges of the North Island of New Zealand. We document here a detailed analysis of the Waitawhiti landslide complex, located in the core of the Tawhero syncline, and investigate the potential landslides triggering factors in the area. Four contiguous large slides form the Waitawhiti complex. These slides involve fine-grained Miocene sandstones and massive fractured siltstones. Sliding occurs mostly along nearly horizontal strata. All slides are bounded laterally and/or distally by deep-incised valleys. Three gas seeps evidencing thermogenic gas release have been discovered in the vicinity of the slides. We propose that river incision, continuously removing distal buttresses, is the main destabilizing factor in the area. However, additional factors, such as tectonic activity and intense rainfall, cannot be excluded. We also propose that fluid overpressure, reducing the effective shear strength at the base of low-permeability layers, may have influenced the triggering of landslides in the Waitawhiti area.     

Cosmogenic Be dating of a sackung and its faulted rock glaciers, in the Alps of Savoy (France)

Sackungs are the largest gravitational deformation observed in mountains. They are characterized by the long-term slowness of the movements, but their mechanism is still not well understood. Nowadays cosmic ray exposure (CRE) dating methods allow dating the morphologic structures involved in sackung and can contribute at the understanding of their origin. In the Alps, the 5.3 km long Arcs sackung initiated during the activity of rock glaciers. Three samples from these faulted rock glaciers provide their first CRE ages and show that at 2000 m elevation these block accumulations moved during the Younger Dryas and stopped in early Holocene. Six ¹⁰Be ages of fault scarps show that the Arcs sackung lasted only a few thousand years and stopped at about 8462 ± 432 ¹⁰Be yr. They also reveal that deformation migrated upslope in agreement with a mechanism of flexural toppling of vertical layers. This unique and long gravitational event, characterized by migration of the deformation, does not support earthquake shaking as triggering mechanism for individual faults. It shows that, in the upper Isère valley, slope deformation was delayed of several thousand years after glacial debuttressing, and is not anymore active despite its fresh morphology.     

Tidal and wind-induced circulation within the Southeastern limit of the Bay of Biscay: Pasaia Bay,Basque Coast

The Basque coastal area, in the southeastern Bay of Biscay, can be characterised as being more influenced by land climate and inputs, than other typically ‘open sea’ areas. The influence of coastal processes, together with the presence of irregular and steep topography, complicate greatly the water circulation patterns. Water movement along the Basque coastal area is not well understood; observations are scarce and long-term current records are lacking. The knowledge available is confined to the surface currents: the surface water circulation is controlled mainly by wind forcing, with tidal and density currents being weak. However, there is a lack of knowledge available on currents within the lower levels of the water column; likewise, on the main time-scales involved in the water circulation. This study quantifies the contribution of the tidal and wind-induced currents, to the overall water circulation; it identifies the main time-scales involved within the tidal and wind-induced flows, investigating difference in such currents, throughout the water column, within Pasaia Bay (Basque coast). Within this context, extensive oceanographic and meteorological data have been obtained, in order to describe the circulation. The present investigation reveals that the circulation, within the surface and the sub-surface waters, is controlled mainly by wind forcing fluctuations, over a wide range of meteorological frequencies: third-diurnal, semidiurnal and diurnal land–sea breezes; synoptic variability; frequencies, near fortnightly periods; and seasonal. At the lower levels of the water column, the main contribution to the water circulation arises from residual currents, followed by wind-induced currents on synoptic time-scales. In contrast, tidal currents contribute minimally to the overall circulation throughout the water column.