Study of the Interaction Mechanism in the Biosorption of Copper(II) Ions onto Posidonia oceanica and Peat

A systematic approach was used to characterize the biosorption of copper(II) onto two biosorbents, Posidonia oceanica and peat, focusing on the interaction mechanisms, the copper(II) sorption–desorption process and the thermal behavior of the biosorbents. Sorption isotherms at pH 4–6 were obtained and the experimental data were fitted to the Langmuir model with a maximum uptake (q_max) at pH 6 of 85.78 and 49.69 mg g^?1, for P. oceanica and peat, respectively. A sequential desorption (SD) with water, Ca(NO₃)₂, and EDTA was applied to copper‐saturated biosorbents. Around 65–70% copper(II) were desorbed with EDTA, indicating that this heavy metal was strongly bound. The reversibility of copper(II) sorption was obtained by desorption with HCl and SD. Fourier transform IR spectroscopy (FTIR) analysis detected the presence of peaks associated with OH groups in aromatic and aliphatic structures, CH, CH₂, and CH₃ in aliphatic structures, COO^? and COOH groups and unsaturated aromatic structures on the surface of both biosorbents, as well as peaks corresponding to Si? O groups on the surface of peat. The results of SEM‐EDX and FTIR analysis of copper‐saturated samples demonstrated that ion exchange was one of the mechanisms involved in copper(II) retention. Thermal analysis of biosorbent samples showed that copper(II) sorption–desorption processes affected the thermal stability of the biosorbents.     

Floodplain hydrology of the Mekong Delta,Vietnam

The Mekong Delta is one of the largest and most intensively used estuaries in the world. Each year it witnesses widespread flooding which is both the basis of the livelihood for more than 17 million people but also the major hazard. Therefore, a thorough understanding of the hydrologic and hydraulic features is urgently required for various planning purposes. While the general causes and characteristics of the annual floods are understood, the inundation dynamics in the floodplains in Vietnam which are highly controlled by dikes and other control structures have not been investigated in depth. Especially, quantitative analyses are lacking, mainly due to scarce data about the inundation processes in the floodplains. Therefore, a comprehensive monitoring scheme for channel and floodplain inundation was established in a study area in the Plain of Reeds in the northeastern part of the Vietnamese Delta. This in situ data collection was complemented by a series of high‐resolution inundation maps derived from the TerraSAR‐X satellite for the flood seasons 2008 and 2009. Hence, the inundation dynamics in the channels and floodplains, and the interaction between channels and floodplains, could be quantified for the first time. The study identifies the strong human interference which is governed by flood protection levels, cropping patterns and communal water management. In addition, we examine the tidal influence on the inundation in various parts of the Delta, since it is expected that climate change‐induced sea level rise will increase the tidal contribution to floodplain inundation. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial scale effect on the upper soil effective parameters of a distributed hydrological model

Nonlinear dynamics and spatial variability in hydrological systems make the formulation of scaling theories difficult. Therefore, the development of knowledge related to scale effects, scaling techniques, parameterization and linkages of parameters across scales is highly relevant. The main purpose of this work is to analyse the spatial effect of the static storage capacity parameter H_u and the saturated hydraulic conductivity parameter k_s from microscale (sub‐grid level) to mesoscale (grid level) and its implication to the definition of an optimum cell size. These two parameters describe the upper soil water characteristics in the infiltration process conceptualization of the TETIS hydrological model. At microscale, the spatial heterogeneity of H_u and k_s was obtained generating random parameter fields through probability distribution functions and a spatial dependence model with pre‐established correlation lengths. The effective parameters at mesoscale were calculated by solving the inverse problem for each parameter field. Results indicate that the adopted inverse formulation allows transferring the nonlinearity of the system from microscale to the mesoscale via non‐stationary effective parameters. Their values at each cell and time step are in the range of zero to the mean value of the parameter at microscale. The stochastic simulations showed that the variance of the estimated effective parameters decreases when the ratio between mesoscale cell size and correlation length at microscale increases. For a ratio greater than 1, we found cell sizes having the characteristics of a representative elementary area (REA); in such case, the microscale variability pattern did not affect the system response at mesoscale. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of spatial resolution on regionalization of hydrological model parameters

Lack of availability of historical data series is one of the major hindrances in hydrological modelling. Regionalization of hydrological model parameters is one of the solutions to obtain the parameters for ungauged basins. Recently, lots of methodologies have been developed. They can be categorized as model calibration then fitting regression between model parameters and catchments characteristics, using some kind of transfer function. The aim of this study was to compare different regionalization methods as well as to look how the spatial resolution affects regionalization. In this study, a modified Lipschitz and monotony condition was used for regionalization. To identify the effect of the model resolution, the parameters of a distributed and semi‐distributed version of the Hydrologiska Byråns Vattenbalansavdelning (HBV) model were regionalized. The study was conducted at the upper Neckar catchment of southwest Germany. It has been found that the combination of Lipschitz and monotony condition has performed reasonably. It has been seen that the distributed model structure has outperformed the semi‐distributed model structure. It shows under present data conditions that higher model resolution can describe processes of ungauged basins reasonably. Copyright © 2011 John Wiley & Sons, Ltd.     

Thomsen's parameters from p‐wave measurements in a spherical sample‡

The aim of this paper is to understand the seismic anisotropy of the overburden shale in an oilfield in the North West Shelf of Western Australia. To this end, we first find the orientation of the symmetry axis of a spherical shale sample from measurements of ultrasonic P‐wave velocities in 132 directions at the reservoir pressure. After transforming the data to the symmetry axis coordinates, we find Thomsen's anisotropy parameters δ and ? using these measurements and measurements of the shear‐wave velocity along the symmetry axis from a well log. To find these anisotropy parameters, we use a very fast simulated re‐annealing algorithm with an objective function that contains only the measured ray velocities, their numerical derivatives and the unknown elasticity parameters. The results show strong elliptical anisotropy in the overburden shale. This approach produces smaller uncertainty of Thomsen parameter δ than more direct approaches.     

JCZ-1T超宽频带地震计LP垂直通道记录的固体潮特征

JCZ-1T超宽频带地震计具有全频带覆盖特性,其低频端输出延伸到固体潮汐,利用地震计LP通道的垂直分向观测数据,经过处理获得有关的固体潮资料,通过对记录信号的频谱分析对其有了初步的认知。JCZ-1T超宽频地震计LP加速度垂直通道记录的观测信号以固体潮汐信息为主,用该仪器观测可以获取与地震相关的综合观测数据,分析JCZ-1T记录波形叠加的的固体潮信息有着重要的实际意义,通过对资料处理运用,可以与传统前兆仪器结合观测,拓展其研究应用领域,更好的服务于地震科学研究。     

西宁地震台地磁数字化与模拟记录对比分析

西宁地震台FHD数字化核旋仪从2006年10月安装以来,一直与模拟仪器并行工作。二者采样率不同,所测的量也不相同。在对西宁地震台磁变仪的记录图纸进行数字化转换、生成分钟值的基础上,对FHD仪和磁变仪的观测结果进行对比分析。结果表明:数字FHD仪比三分量磁变仪更加准确地记录了当地地磁场的变化,数字仪器的观测资料明显优于模拟仪器。     

Analysis of the contribution of natural sources of radiation to the total dose received by workers

People working with ionising radiation are receiving radiation coming from artificial and natural sources. In Spain, as in many other countries, there is a serious control by the national authorities, Spanish Nuclear Safety Council, of the dose the workers receive from artificial sources. However, until the publication of the European Basic Safety Standards Directive, 96/29/EURATOM, the old criteria referring to the “above natural background” were widely used. This directive was incorporated to the Spanish legislation in July 2001 (BOE 178); in its Title VII it recommends to evaluate the dose coming from natural sources and take it into account for establishing the safety criteria. It is noteworthy to assess the natural doses received at homes and the dose received by workers of radioactive installations subject to regulations, and to compare the two results. The social and economical implications of the results derived can be important in the practical application of the recommendations included in the above-mentioned BOE 178 Directive.     

关中地区地磁比值Rq的变化与地震关系的分析

应用小波分析空间差分法分析了泾阳台、乾陵台、周至台和郑州台的Z分量的地磁磁静日Rg值的变化规律，结果显示，各台的磁静日Rg值有较一致的年变规律。分析泾阳台与其它各台的磁静日R。差值分析和小波变换，发现1998年1月5日泾阳4．8级地震前4个月内存在较明显的异常变化。可能反映了泾阳地震的震磁效应。对远离泾阳台、乾陵台的青海昆仑山口西8．1级地震，震前也有明显异常变化。     

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.