Deciphering late Quaternary land snail shell δO and δC from Franchthi Cave (Argolid,Greece)

This paper investigates the stable isotopic composition from late Pleistocene–Holocene (~ 13 to ~ 10.5 cal ka BP) shells of the land snail Helix figulina, from Franchthi Cave (Greece). It explores the palaeoclimatic and palaeoenvironmental implications of the isotope palaeoecology of archaeological shells at the time of human occupation of the cave. Modern shells from around the cave were also analysed and their isotopic signatures compared with those of the archaeological shells. The carbon isotope composition of modern shells depicts the consumption of C₃ vegetation. Shell oxygen isotopic values are consistent with other Mediterranean snail shells from coastal areas. Combining empirical linear regression and an evaporative model, the δ¹⁸Os suggest that modern snails in the study area are active during periods of higher relative humidity and lower rainfall δ¹⁸O, probably at night. Late glacial and early Holocene δ¹⁸Os show lower values compared to modern ones. Early Holocene δ¹⁸Os values likely track enhanced moisture and isotopic changes in the precipitation source. By contrast, lower late glacial δ¹⁸O could reflect lower temperatures and δ¹⁸Op, compared to the present day. Shell carbon isotope values indicate the presence of C₃ vegetation as main source of carbon to late glacial and early Holocene snails.     

Assessing the benthic quality status of the Bohai Bay (China) with proposed modifications of M-AMBI

Multivariate AZTI's Marine Biotic Index (M-AMBI) was designed to indicate the ecological status of European coastal areas. Based upon samples collected from 2009 to 2012 in the Bohai Bay, we have tested the response of variations of M-AMBI, using biomass (M-BAMBI) in the calculations, with different transformations of the raw data. The results showed that the ecological quality of most areas in the study indicated by M-AMBI was from moderate to bad status with the worse status in the coastal areas, especially around the estuaries, harbors and outfalls, and better status in the offshore areas except the area close to oil platforms or disposal sites. Despite large variations in nature of the input data, all variations of M-AMBI gave similar spatial and temporal distribution patterns of the ecological status within the bay, and showed high correlation between them. The agreement of new ecological status obtained from all M-AMBI variations, which were calculated according to linear regression, was almost perfect. The benthic quality, assessed using different input data, could be related to human pressures in the bay, such as water discharges, land reclamation, dredged sediment and drilling cuts disposal sites. It seems that M-BAMBI were more effective than M-NABMI (M-AMBI calculated using abundance data) in indicating human pressures of the Bay. Finally, indices calculated with more severe transformations, such as presence/absence data, could not indicate the higher density of human pressures in the coastal areas of the north part of our study area, but those calculated using mild transformation (i.e., square root) did.     

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.     

Atlas of susceptibility to pollution in marinas. Application to the Spanish coast

An atlas of susceptibility to pollution of 320 Spanish marinas is provided. Susceptibility is assessed through a simple, fast and low cost empirical method estimating the flushing capacity of marinas. The Complexity Tidal Range Index (CTRI) was selected among eleven empirical methods. The CTRI method was selected by means of statistical analyses because: it contributes to explain the system's variance; it is highly correlated to numerical model results; and, it is sensitive to marinas' location and typology. The process of implementation to the Spanish coast confirmed its usefulness, versatility and adaptability as a tool for the environmental management of marinas worldwide. The atlas of susceptibility, assessed through CTRI values, is an appropriate instrument to prioritize environmental and planning strategies at a regional scale.     

Geomorphic monitoring and response to two dam removals: rivers Urumea and Leitzaran (Basque Country,Spain)

Dam removal has been demonstrated to be one of the most frequent and effective fluvial restoration actions but at most dam removals, especially of small dams, there has been little geomorphological monitoring. The results of the geomorphological monitoring implemented in two dams in the rivers Urumea and Leitzaran (northern Spain) are presented. The one from the River Urumea, originally 3.5 m high and impounding 500 m of river course, was removed instantaneously whereas that in the River Leitzaran, 12.5 m high, and impounding 1500 m of river course, is in its second phase of a four‐stage removal process. Changes in channel morphology, sediment size and mobility and river bed morphologies were assessed. The monitoring included several different techniques: topographical measurements of the channel, terrestrial laser scanner measurements of river bed and bars, sediment grain size and transport; all of them repeated in four (May, August, November 2011 and May 2012) and five (July and September 2013, April and August 2014 and June 2015) fieldwork campaigns in the River Urumea and River Leitzaran, respectively. Geomorphic responses of both dam removals are presented, and compared. Morphological channel adjustments occurred mainly shortly after dam removals, but with differences among the one removed instantaneously, that was immediate, whereas that conducted by stages took longer. Degradational processes were observed upstream of both dams (up to 1.2 m and 4 m in the River Urumea and River Leitzaran, respectively), but also aggradational processes (pool filling), upstream of Inturia Dam (2.85 m at least). Less evident aggradational processes were observed downstream of the dams (up to 0.37 m and 0.50 m in the River Urumea and River Leitzaran, respectively). Flood events, especially a 100 year flood registered during the monitoring period of Mendaraz Dam removal, reactivated geomorphological processes as incision and bank erosion, whereas longitudinal profile recovery, grain‐size sorting and upstream erosion took longer. Copyright © 2016 John Wiley & Sons, Ltd.     

水污染物总量综合权重系数分配方法研究

区域污染物排放总量分配是水污染总量控制的重要内容,分配合理与否将直接影响总量控制工作成效。以陆域排污-水体水质响应空间单元为基础,构建了综合考虑水环境质量、排污及污染治理水平、区域经济实力等因素的总量分配指标体系,提出一套单元的水污染物总量分配综合权重系数计算方法。并将该方法应用于北京市,结果表明本方法较好地解决了目前分配方法中总量目标与水质改善需求衔接不足、分配指标体系过于单一的问题。     

Crustal segments in the North Patagonian Massif,Patagonia: An integrated perspective based on Sm–Nd isotope systematics

New insights on the Paleozoic evolution of the continental crust in the North Patagonian Massif are presented based on the analysis of Sm–Nd systematics. New evidence is presented to constrain tectonic models for the origin of Patagonia and its relations with the South American crustal blocks. Geologic, isotopic and tectonic characterization of the North Patagonian Massif and comparison of the Nd parameters lead us to conclude that: (1) The North Patagonian Massif is a crustal block with bulk crustal average ages between 2.1 and 1.6 Ga T_DM (Nd) and (2) At least three metamorphic episodes could be identified in the Paleozoic rocks of the North Patagonian Massif. In the northeastern corner, Famatinian metamorphism is widely identified. However field and petrographic evidence indicate a Middle to Late Cambrian metamorphism pre-dating the emplacement of the ca. 475 Ma granitoids. In the southwestern area, are apparent 425–420 Ma (?) and 380–360 Ma metamorphic peaks. The latter episode might have resulted from the collision of the Antonia terrane; and (3) Early Paleozoic magmatism in the northeastern area is coeval with the Famatinian arc. Nd isotopic compositions reveal that Ordovician magmatism was associated with attenuated crust. On the southwestern border, the first magmatic recycling record is Devonian. Nd data shows a step by step melting of different levels of the continental crust in the Late Palaeozoic. Between 330 and 295 Ma magmatism was likely the product of a crustal source with an average 1.5 Ga T_DM (Nd). Widespread magmatism represented by the 295–260 Ma granitoids involved a lower crustal mafic source, and continued with massive shallower-acid plutono volcanic complexes which might have recycled an upper crustal segment of the Proterozoic continental basement, resulting in a more felsic crust until the Triassic. (4) Sm–Nd parameters and detrital zircon age patterns of Early Paleozoic (meta)-sedimentary rocks from the North Patagonian Massif and those from the neighboring blocks, suggest crustal continuity between Eastern Sierras Pampeanas, southern Arequipa-Antofalla and the northeastern sector of the North Patagonian Massif by the Early Paleozoic. This evidence suggests that, at least, this corner of the North Patagonian Massif is not allochthonous to Gondwana. A Late Paleozoic frontal collision with the southwestern margin of Gondwana can be reconcilied in a para-autochthonous model including a rifting event from a similar or neighbouring position to its post-collision location. Possible Proterozoic or Early Paleozoic connections of the NPM with the Kalahari craton or the western Antartic blocks should be investigated.     

LES of turbulent surface shear stress and pressure-gradient-driven flow on shallow continental shelves

Turbulent shear flows on shallow continental shelves (here shallow means that the interaction with the solid, no-slip bottom is important) are of great importance because tide- and wind-driven flows on the shelf are drivers of the transfer of momentum, heat, and mass (gas) across the air–sea interface. These turbulent flows play an important role because vertical mixing and current are vectors for the transport of sediment and bioactive material on continental shelves. Understanding the dynamics of this class of flows presents complications because of the presence of a free surface and also because the flow can be driven by a pressure gradient (a tidal current), a stress at the free surface (a wind-driven current), or a combination of both. In addition, the flow can be modified by the presence of a wave field that can induce Langmuir circulation (Langmuir, Science 87:119–123, 1938). Large eddy simulation is used to quantify the effects of pressure gradient and wind shear on the distinctive structures of the turbulent flow. From these computations, an understanding of the physics governing the turbulence of pressure-driven and wind-driven flows, how they can interact in a normal or a tangential direction, and the effect of wave forcing on these flows is obtained.     

浅循环泉简析

泉按照出露原因通常可以分为侵蚀泉、接触泉、溢流泉（溢出泉）和断层泉等。根据泉眼和地下水循环深度（或径流位置）的相对关系,泉可以分为表层泉、浅循环泉和深循环泉。地下水在地下流动(循环)的最深处仍然高于泉口,这类泉称为浅循环泉。浅循环泉出露的位置并不在地形最低处,其补给来源主要是大气降水入渗,地下水受到重力作用自高处往低处流动,在地下径流的途径短、时间短,流量一般不大。浅循环泉通常是常温泉、淡水泉（也有咸泉和盐泉）,多是常年性泉,也有部分是季节性泉或暂时性泉。广西北竂岭北坡泉和云南顺荡井盐泉是典型的浅循环泉。