基于GIS的北京城市形态研究

经典的城市形态理论包括同心圆理论、扇形理论和多核心理论.利用2002年北京市土地利用图,采用GIS缓冲区分析的方法,分析了北京市各功能用地的方向特征和圈层特征.结果表明:北京市的土地利用体现了明显的圈层特征,同时各类功能用地在各方向的分布又明显受到了河流、交通干道和工业区等地理要素的影响.北京没有形成城市总体规划的多中心布局,第一道绿化隔离地区中绿地面积没有明显高出其他地区,基本上已经失去了中心城区和边缘集团隔离开的功能.总体上,北京城市空间形态主要是同心圆和扇形的结合,更接近同心圆理论和扇形理论的混合形式.     

水泥粉煤灰加固有机质土的试验研究

对于高有机质含量的泻湖相软土,单纯采用水泥不能有效提高该软土的力学性能,因此提出了采用水泥和粉煤灰作为固化剂的加固方法。通过不同水泥掺入量、粉煤灰掺入量和龄期下水泥土的无侧限抗压强度试验,分析了水泥粉煤灰固化土的强度规律和变形规律,探讨了水泥和粉煤灰加固高有机质含量软土的机理。结果表明,粉煤灰对于水泥试块的早期强度影响较小,对后期强度影响较大;粉煤灰最佳掺入量为12％,超过此掺入量水泥土强度反而会降低,粉煤灰水泥土的破坏应变、E50也在粉煤灰掺量为12％时分别达到最低值和最大值。水泥掺加粉煤灰可有效地提高高有机质含量软土的强度。     

Cross-scale analysis of cluster correspondence using different operational neighborhoods

Cluster correspondence analysis examines the spatial autocorrelation of multi-location events at the local scale. This paper argues that patterns of cluster correspondence are highly sensitive to the definition of operational neighborhoods that form the spatial units of analysis. A subset of multi-location events is examined for cluster correspondence if they are associated with the same operational neighborhood. This paper discusses the construction of operational neighborhoods for cluster correspondence analysis based on the spatial properties of the underlying zoning system and the scales at which the zones are aggregated into neighborhoods. Impacts of this construction on the degree of cluster correspondence are also analyzed. Empirical analyses of cluster correspondence between paired vehicle theft and recovery locations are conducted on different zoning methods and across a series of geographic scales and the dynamics of cluster correspondence patterns are discussed.      

Income distribution dynamics and cross-region convergence in Europe

This paper presents a continuous version of the model of distribution dynamics to analyse the transition dynamics and implied long-run behaviour of the EU-27 NUTS-2 regions over the period 1995–2003. It departs from previous research in two respects: first, by introducing kernel estimation and three-dimensional stacked conditional density plots as well as highest density regions plots for the visualisation of the transition function, based on Hyndman et al. (J Comput Graph Stat 5(4):315–336, 1996), and second, by combining Getis’ spatial filtering view with kernel estimation to explicitly account for the spatial dimension of the growth process. The results of the analysis indicate a very slow catching-up of the poorest regions with the richer ones, a process of shifting away of a small group of very rich regions, and highlight the importance of geography in understanding regional income distribution dynamics.

太湖入湖河道沉积物中生物利用磷和营养水平分析

为了解太湖入湖河道的营养状况,研究了太湖西部河流沉积物生物利用磷的组成与分布。研究结果显示,北部沉积物中营养元素较高,南部较低;沉积物中生物利用磷的含量次序为藻类可利用磷(AAP)>NaHCO3提取磷(OLP)>水溶性磷(WSP)>易解吸磷(RDP),其中AAP是重要的生物利用磷,AAP的比例越高,富营养化程度越高。AAP与营养元素的相关性在不同区域河道有所不同,北部河道与总氮(TN)、总磷(TP)相关性较好,中部和南部河道与沉积物有机质总量(TOM)相关性较好。沉积物的生物利用磷受不同污染源影响较大。对比河道沉积物与湖泊沉积物的特征,发现湖泊沉积物中生物利用磷(BAP)/总磷(TP)、藻类可利用磷(AAP)/总磷(TP)都高于河道沉积物,表明湖泊沉积物中的磷更容易被植物吸收。     

Mirdita Zone ophiolites and associated sediments in Albania reveal Neotethys Ocean origin

The Mirdita Ophiolite Zone in Albania is associated with widespread mélanges containing components of up to nappe-size. We dated matrix and components of the mélange by radiolarians, conodonts, and other taxa. The components consist of radiolarites, pelagic limestones and shallow-water limestones, all of Triassic age, as well as ophiolites. Triassic radiolarite as a primary cover of ophiolite material proves Middle Triassic onset of Mirdita ocean-floor formation. The mélange contains a turbiditic radiolarite-rich matrix (“radiolaritic flysch”), dated as Late Bajocian to Early Oxfordian. It formed as a synorogenic sediment during west-directed thrusting of ophiolite and sediment-cover nappes representing ocean floor and underplated fragments of the western continental margin. The tectonic structures formed during these orogenic events (“Younger Kimmeridian or Eohellenic Orogeny”) are sealed by Late Jurassic platform carbonates. The geological history conforms with that of the Inner Dinarides and adjoining areas; we therefore correlate the Mirdita-Pindos Ophiolite Zone with the Vardar Zone and explain its present position by far-distance west-directed thrusting.     

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.