安徽铜陵矿集区海底喷流沉积体系的流体包裹体微量元素对比

铜陵矿集区与铜-金(多金属)矿床有关的热液活动主要有两大体系。即与海西期海底喷流沉积有关的热液体系和与矽卡岩矿化有关的燕山期岩浆热液体系。查明这两类热液体系的流体包裹体特征对区域找矿和矿床成因研究都有实际意义。在包裹体岩相学研究基础上，应用ICP-MS技术和热爆提取方法，研究了新桥、冬瓜山、峙门口、铜官山、朝山等矿床具代表性的热液石英中流体包裹体的微量元素、稀土元素特征。结果表明，两类热液体系在流体包裹体特征上有较大的区别，在流体的微量元素和稀土元素特征方面也很不相同。海底喷流沉积体系的热液石英中流体包裹体与岩浆热液体系的相比。稀土总量较高，LREE／HREE比值较大，δEu不明显。且Mo／(W Sn)比值较高，反映流体中成矿物质的深源特征；Ga／T1、Rb／Cs大。Zr／Hf低，也不同于岩浆热液体系。     

铜陵地区老鸦岭层状钼矿床铅同位素组成研究

安徽铜陵老鸦岭矿床中二叠系大隆组(P2d)顶部的含矿(钼矿化)黑色页岩以及附近(立新煤矿)同一层位不含矿黑色页岩的实测铅同位素组成分别为：^206Pb/^204Pb20.20～22.37,^207Pb/^204Pb15.67～15.82,^208Pb/^204Pb38.47～38.60和^206Pb/204Pb18.83～20.80,^207Pb/^204Pb15.65～15.76,^208Pb/^204Pb38．84～39．22。对137Ma的放射成因Pb进行校正后的铅同位素组成表明，含矿黑色页岩和不含矿黑色页岩均与燕山晚期火成岩无关，老鸦岭含矿黑色页岩可能具沉积成因。对沉积(约250Ma)以来的放射成因Pb进行校正后的铅同位素组成表明：不含矿黑色页岩的Pb源自上地壳，而含矿黑色页岩的Pb(因而推测其他成矿金属)可能源于上地壳物质(与不含矿黑色页岩的Pb源相似)与下地壳物质的混合。     

南秦岭十里坪锑矿床成矿时代及成因的初步研究

十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%～11.3%,均一温度为109～232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

沙坡头没蒿和柠条叶片δ13C 和 N 含量的季节变化特征

通过对腾格里沙漠东南缘沙坡头人工固沙区油蒿和柠条叶片稳定碳同位素分辨率（△）和N 含量的测定，研究了不同种植方式下油蒿和柠条叶片△ 和 N 含量的季节变化及其关系。结果表明：在不同种植方式下，两种植物的△ 与 N 含量在不同月份之间均存在显著差异。油蒿叶片 △ 极显著高于柠条的：在不同种植方式下，油蒿单种下 △ 显著高于混种，柠条则反之。 油蒿叶片 N 含量极显著低于柠条的：不同种植方式下柠条叶片 N 含量无显著差异，而单种油蒿叶片 N 含量则显著低于混种。在 △ 与 N 含量的关系中，柠条叶片 △ 与 N 在两种生境、单种和混种下均极显著正相关，雨明柠条叶片 N 含量可以作为其 △ 与 N 含量的季节变化及其关系在不同微生境有所差异。     

Effect of the Initial Vortex Structure on Intensity Change During Eyewall Replacement Cycle of Tropical Cyclones: A Numerical Study

This study investigates the effect of the initial tropical cyclone (TC) vortex structure on the intensity change during the eyewall replacement cycle (ERC) of TCs based on two idealized simulations using the Weather Research and Forecasting (WRF) model. Results show that an initially smaller TC with weaker outer winds experienced a much more drastic intensity change during the ERC than an initially larger TC with stronger outer winds. It is found that an initially larger TC vortex with stronger outer winds favored the development of more active spiral rainbands outside the outer eyewall, which slowed down the contraction and intensification of the outer eyewall and thus prolonged the duration of the concentric eyewall and slow intensity evolution. In contrast, the initially smaller TC with weaker outer winds corresponded to higher inertial stability in the inner core and weaker inertial stability but stronger filamentation outside the outer eyewall. These led to stronger boundary layer inflow, stronger updraft and convection in the outer eyewall, and suppressed convective activity outside the outer eyewall. These resulted in the rapid weakening during the formation of the outer eyewall, followed by a rapid re-intensification of the TC during the ERC. Our study demonstrates that accurate in- itialization of the TC structure in numerical models is crucial for predicting changes in TC intensity during the ERC. Additionally, monitoring the activity of spiral rainbands outside the outer eyewall can help to improve short-term intensity forecasts for TCs experiencing ERCs.     

Characterization and Application of S-Band Polarimetric Radar and X-Band Phased Array Radar for a Tornadic Storm Event on June 16,2022

The X-band phased array radar offers faster scanning speed and higher spatial resolution compared to the S-band radar, making it capable of enhancing tornado monitoring and early warning capabilities. This study analyzed the char- acteristics and nowcasting signals of a tornado case that occurred on June 16, 2022 in the Guangzhou region. Our findings indicate that the violent contraction of rotation radius and the dramatic increase in rotation speed were important signal characteristics associated with tornado formation. The X-band phased array radar, with its high temporal and spatial resolution, provided an opportunity to capture early warning signals from polarimetric characteristics. The X-band phased array radar demonstrated noteworthy ability to identify apparent tornado vortex signature (TVS) features in a 10-minute lead time, surpassing the capabilities of the CINRAD/SA radar. Additionally, due to its higher scanning frequency, the X- band phased-array radar was capable of consistently identifying TVS with shorter intervals, enabling a more precise tracking of the tornado’s path. The application of professional radars, in this case, provides valuable insights for the monitoring of evolutions of severe local storms and even tornadoes and the issuance of early warning signals.     

近1800年以来内蒙古达里湖浮游植物群落演变及驱动因素

湖泊是地质历史上区域生态环境演变的重要载体,其沉积物中包含了丰富的环境演变信息。达里湖是典型的草原内陆封闭型湖泊,位于东亚夏季风的北部边缘,地理位置关键。本研究基于在达里湖采集的约238 cm沉积物岩芯 (GDL-1),通过²¹⁰Pb和¹³⁷Cs (岩芯上部20 cm)、AMS¹⁴C测年,以及沉积物样品中甾醇等生物标志物含量分析,重建了近1800年以来达里湖硅藻、蓝藻等典型藻类含量的演化历史,并结合总氮(TN)、总磷(TP)、盐度(Sr/Ba)和温度(T)等环境代用指标,分析藻类群落的主要影响因素。结果显示达里湖典型藻类总量平均为2.03 ng/g(最高6.69 ng/g,最小0.53 ng/g),其中蓝藻占比平均为60%,绿藻和硅藻占比平均为20%;环境因子对硅藻、蓝藻和典型藻类生物量的解释率分别为47.7%、55.20%和48.10%,T、TN和Sr/Ba是影响浮游植物群落的主要影响因素;硅藻占比与温度呈显著负相关,小冰期硅藻占比最高,中世纪暖期占比最低;在达里湖的高盐环境下,湖泊营养盐浓度对藻类的影响受到限制,成为藻类等生长的限制因素;Sr/Ba小于0.9时,硅藻含量与典型藻类总量随着Sr/Ba值的升高而增加,Sr/Ba大于0.9时,典型藻类总量与Sr/Ba值呈负相关关系,而硅藻则表现出对盐度具有一定的耐受性;整体上,近1800年以来,区域或全球性气候事件通过改变达里湖盐度、营养元素浓度和温度来影响典型藻类群落结构。在暖期阶段,蒸发作用增强等导致的湖泊盐度增加成为达里湖典型藻类群落结构演变的主要影响因素;在冷期,营养元素浓度和温度的降低成为湖泊水体浮游植物生物量的主要影响因素。